公开(公告)号：US20070099803A1

公开(公告)日：2007-05-03

申请号：US11626502

申请日：2007-01-24

Applicant: Duong Nguyen

Inventor： Duong Nguyen

IPC: C07C205/22

CPC classification number: C07C201/08 ,  C07C205/03 ,  C10M133/32 ,  C10M159/12 ,  C10M177/00 ,  C10M2205/026 ,  C10M2215/202 ,  C10M2215/24 ,  C10M2217/06 ,  C10N2230/06 ,  C10N2240/40 ,  C10N2260/09

Abstract: This invention relates to processes for making nitro compounds derived from C2-C30 unsaturated fatty acids; C2-C30 unsaturated fatty oils; esters derived from the reaction of C1-C20 alcohols with unsaturated C2-C30 fatty acids; C2-C20 polyolefins; C4-C20 polydiolefins; C8-C20 copolymers derived from polyolefins and vinyl aromatics; and C4-C30 alkylated phenols using nitric acid or gaseous nitrogen dioxide. This class of extreme-pressure additives was found extremely effective in processing steel, stainless steel and special titanium and nickel or low-iron alloys.

Abstract translation: 本发明涉及制备衍生自C 2 -C 30不饱和脂肪酸的硝基化合物的方法; C 2 -C 30不饱和脂肪油; 衍生自C 1 -C 20 -C 20醇与不饱和C 2 -C 30脂肪酸的反应的酯; C 2 -C 20聚烯烃; C 4 -C 20二聚烯烃; 衍生自聚烯烃和乙烯基芳族化合物的C 8 -C 20 -C 20共聚物; 和C 4 -C 30烷基化的酚，使用硝酸或二氧化氮气体。 发现这类极压添加剂在加工钢，不锈钢和特殊的钛和镍或低铁合金方面非常有效。

公开(公告)号：US07041858B1

公开(公告)日：2006-05-09

申请号：US11054012

申请日：2005-02-09

Applicant: Juergen Muennig ,  Bernd Pennemann ,  Dietmar Wastian ,  Volker Michele ,  Jesse Caravaggio ,  John F. Gisch, Jr.

Inventor： Juergen Muennig ,  Bernd Pennemann ,  Dietmar Wastian ,  Volker Michele ,  Jesse Caravaggio ,  John F. Gisch, Jr.

IPC: C07C205/00

CPC classification number: C07C201/08 ,  C07C205/06

Abstract: The present invention is directed to a process for the isothermal nitration of aromatic organic compounds, wherein an aromatic organic compound is brought into contact and reacted with a mixture of sulfuric acid and nitric acid. The mixture of sulfuric acid and nitric acid, and the aromatic organic compound are brought into contact with each other through a mixing nozzle which comprises a substantially cylindrical tubular reactor and an annular gap which surrounds the tubular reactor. The aromatic organic compound flows through the tubular reactor, and the mixture of sulfuric acid and nitric acid flows through the annular gap, and they are mixed together upon emerging from the tubular reactor and the annular gap, wherein the ratio of the average rates of flow of the aromatic organic compound in the tubular reactor, and of the mixture of sulphuric acid and nitric acid in the annular gap ranges from 0.5:1 to 10:1.

Abstract translation: 本发明涉及芳族有机化合物的等温硝化方法，其中使芳族有机化合物与硫酸和硝酸的混合物接触并反应。 硫酸和硝酸的混合物和芳香族有机化合物通过混合喷嘴相互接触，所述混合喷嘴包括基本上圆柱形的管式反应器和围绕管状反应器的环形间隙。 芳族有机化合物流过管状反应器，硫酸和硝酸的混合物流过环形间隙，并且在从管式反应器和环形间隙出现时将它们混合在一起，其中平均流速 的管状反应器中的芳族有机化合物，以及环状间隙中的硫酸和硝酸的混合物的范围为0.5:1至10:1。

公开(公告)号：US20060036100A1

公开(公告)日：2006-02-16

申请号：US11242779

申请日：2005-10-05

Applicant: Yasutaka Ishii ,  Tatsuya Nakano ,  Shinya Nagano ,  Naoto Okuyama

Inventor： Yasutaka Ishii ,  Tatsuya Nakano ,  Shinya Nagano ,  Naoto Okuyama

IPC: C07F15/00

CPC classification number: C07C51/313 ,  B01J31/006 ,  B01J31/0209 ,  B01J31/0247 ,  B01J31/0271 ,  B01J31/2208 ,  B01J2231/70 ,  B01J2531/845 ,  C07C29/50 ,  C07C45/33 ,  C07C45/39 ,  C07C51/265 ,  C07C201/02 ,  C07C201/08 ,  C07C2601/14 ,  C07D209/48 ,  C07C49/403 ,  C07C49/04 ,  C07C63/06 ,  C07C55/12 ,  C07C55/14 ,  C07C203/08 ,  C07C205/05 ,  C07C31/125 ,  C07C35/08

Abstract: A catalyst includes a cyclic imide compound having an N-substituted cyclic imide skeleton represented by following Formula (I): wherein X is an oxygen atom or a hydroxyl group, and having a solubility parameter of less than or equal to 26 [(MPa) 1/2] as determined by Fedors method. The catalyst may further comprise a metallic compound. By allowing (A) a compound capable of forming a radical to react with (B) a radical scavenging compound in the presence of the catalyst, an addition or substitution reaction product between the compound (A) and the compound (B) or a derivative thereof can be obtained.

Abstract translation: 催化剂包括具有由下式（I）表示的N-取代的环状酰亚胺骨架的环状酰亚胺化合物：其中X是氧原子或羟基，溶解度参数小于或等于26 [（MPa） 通过Fedors方法测定的 ^{1/2。 催化剂还可以包含金属化合物。 通过使（A）能够形成自由基的化合物与（B）自由基清除化合物在催化剂存在下反应的化合物（A）和化合物（B）之间的加成或取代反应产物或衍生物 可以得到。}

公开(公告)号：US06930214B2

公开(公告)日：2005-08-16

申请号：US10883820

申请日：2004-07-06

Applicant: Tamaki Shimizu

Inventor： Tamaki Shimizu

IPC: C07C201/08 ,  C07C205/11 ,  C07J73/00 ,  C07J75/00 ,  C07C205/00 ,  C07D221/18

CPC classification number: C07J75/00 ,  C07C201/08 ,  C07J73/00 ,  C07C205/11

Abstract: A process to produce 2,5-bis(trifluoromethyl)nitrobenzene in a high yield from an industrially easily available material by using a substance with which the reaction operation is simple and handling is easy, with a small number of steps under moderate reaction conditions, is provided. 1,4-bis(trifluoromethyl)benzene is nitrated by means of nitric acid in a solvent comprising as an essential component an acid selected from sulfuric acid having a sulfuric acid concentration of from 91 to 100 mass % and fuming sulfuric acid having a sulfur trioxide concentration of higher than 0 mass % and at most 20 mass %.

Abstract translation: 通过使用反应操作简单并且处理容易的物质，在中等反应条件下以少量的步骤从工业上容易获得的材料中以高产率制备2,5-双（三氟甲基）硝基苯的方法， 被提供。 1,4-二（三氟甲基）苯通过硝酸在含有选自硫酸浓度为91〜100质量％的硫酸和三氧化硫的发烟硫酸作为必需成分的溶剂中进行硝化 浓度高于0质量％，最多为20质量％。

公开(公告)号：US06825388B2

公开(公告)日：2004-11-30

申请号：US10396102

申请日：2003-03-25

Applicant: Mohan Keraba Dongare ,  Pratap Tukaram Patil ,  Kusum Madhukar Malshe

Inventor： Mohan Keraba Dongare ,  Pratap Tukaram Patil ,  Kusum Madhukar Malshe

IPC: C07C20500

CPC classification number: C07C201/08 ,  C07C205/06

Abstract: The present invention relates to the process for vapor phase nitration of o-xylene using dilute nitric acid over H-beta zeolite. More particularly it relates to the selective formation of 4-nitro o-xylene by vapor phase nitration of 0-xylene using dilute nitric acid over commercially available H-beta catalyst. The continuous process of nitration of o-xylene comprises of a reaction carried out in a downflow reactor using o-xylene and dilute nitric acid with mole ratio of 2:1 to 1:2 and WHSV of 0.1-0.5 at 100-250° C. at atmospheric pressure.

公开(公告)号：US06809218B2

公开(公告)日：2004-10-26

申请号：US10680337

申请日：2003-10-07

Applicant: Mark Andrew Harmer ,  Qun Sun

Inventor： Mark Andrew Harmer ,  Qun Sun

IPC: C07C6704

CPC classification number: B01J21/08 ,  B01J31/10 ,  B01J31/165 ,  B01J31/2419 ,  B01J31/4007 ,  B01J35/10 ,  B01J35/1019 ,  B01J35/1023 ,  B01J35/1038 ,  B01J35/1042 ,  B01J35/1047 ,  B01J35/1057 ,  B01J35/1061 ,  B01J35/1066 ,  B01J35/1071 ,  B01J35/109 ,  B01J2231/10 ,  B01J2231/323 ,  B01J2231/4205 ,  B01J2231/52 ,  B01J2231/54 ,  B01J2531/38 ,  B01J2531/821 ,  B01J2531/825 ,  B01J2531/842 ,  B01J2531/847 ,  C07C2/02 ,  C07C2/66 ,  C07C5/2266 ,  C07C5/2273 ,  C07C5/2562 ,  C07C41/30 ,  C07C45/46 ,  C07C67/04 ,  C07C201/08 ,  C07C2521/04 ,  C07C2521/06 ,  C07C2521/08 ,  C07C2521/12 ,  C07C2523/10 ,  C07C2523/14 ,  C07C2523/26 ,  C07C2523/28 ,  C07C2523/745 ,  C07C2531/08 ,  C07C2531/10 ,  C07C2531/20 ,  C07C2531/26 ,  C07C2531/34 ,  Y02P20/584 ,  C07C11/02 ,  C07C49/784 ,  C07C69/013 ,  C07C69/14 ,  C07C205/06 ,  C07C43/263

Abstract: Porous microcomposites have been prepared from perfluorinated ion-exchange polymer and metal oxides such as silica using the sol-gel process. Such microcomposites possess high surface area and exhibit extremely high catalytic activity.

Abstract translation: 使用溶胶 - 凝胶法从全氟化离子交换聚合物和金属氧化物如二氧化硅制备多孔微复合材料。 这样的微复合材料具有高的表面积并且表现出极高的催化活性。

公开(公告)号：US20040068146A1

公开(公告)日：2004-04-08

申请号：US10680838

申请日：2003-10-07

Inventor： Mark Andrew Harmer ,  Qun Sun

IPC: C07C049/00 ,  B01J020/26

CPC classification number: B01J21/08 ,  B01J31/10 ,  B01J31/165 ,  B01J31/2419 ,  B01J31/4007 ,  B01J35/10 ,  B01J35/1019 ,  B01J35/1023 ,  B01J35/1038 ,  B01J35/1042 ,  B01J35/1047 ,  B01J35/1057 ,  B01J35/1061 ,  B01J35/1066 ,  B01J35/1071 ,  B01J35/109 ,  B01J2231/10 ,  B01J2231/323 ,  B01J2231/4205 ,  B01J2231/52 ,  B01J2231/54 ,  B01J2531/38 ,  B01J2531/821 ,  B01J2531/825 ,  B01J2531/842 ,  B01J2531/847 ,  C07C2/02 ,  C07C2/66 ,  C07C5/2266 ,  C07C5/2273 ,  C07C5/2562 ,  C07C41/30 ,  C07C45/46 ,  C07C67/04 ,  C07C201/08 ,  C07C2521/04 ,  C07C2521/06 ,  C07C2521/08 ,  C07C2521/12 ,  C07C2523/10 ,  C07C2523/14 ,  C07C2523/26 ,  C07C2523/28 ,  C07C2523/745 ,  C07C2531/08 ,  C07C2531/10 ,  C07C2531/20 ,  C07C2531/26 ,  C07C2531/34 ,  Y02P20/584 ,  C07C11/02 ,  C07C49/784 ,  C07C69/013 ,  C07C69/14 ,  C07C205/06 ,  C07C43/263

Abstract: Porous microcomposites have been prepared from perfluorinated ion-exchange polymer and metal oxides such as silica using the sol-gel process. Such microcomposites possess high surface area and exhibit extremely high catalytic activity.

公开(公告)号：US06703532B2

公开(公告)日：2004-03-09

申请号：US10032380

申请日：2001-12-21

Applicant: Boyapati Manoranjan Choudary ,  Mannepalli Lakshmi Kantam ,  Nadakuditi Sailendra Kumar ,  Kompella Vishweshwara Ram Prasad ,  Kondapuram Vijaya Raghavan

Inventor： Boyapati Manoranjan Choudary ,  Mannepalli Lakshmi Kantam ,  Nadakuditi Sailendra Kumar ,  Kompella Vishweshwara Ram Prasad ,  Kondapuram Vijaya Raghavan

IPC: C07C20500

CPC classification number: C07C201/08 ,  C07C205/06

Abstract: This invention relates to a process for the nitration of xylene isomers by using zeolite-beta as a catalyst. This invention particularly relates to a process for the nitration of xylenes using solid acid catalyst, thus totally eliminating the disposal of spent acid and salts. Herein we describe the nitration of disubstituted benzenes, all the isomers of xylene, by employing nitric acid and beta zeolite catalyst dispensing the use of acetic anhydride. The reactions were performed at temperatures ranging from room temperature to reflux temperature of the solvent

Abstract translation: 本发明涉及通过使用沸石-β作为催化剂硝化二甲苯异构体的方法。 本发明特别涉及使用固体酸催化剂硝化二甲苯的方法，从而完全消除废酸和盐的处理。 在这里，我们描述了二取代苯的硝化，二甲苯的所有异构体，通过使用硝酸和β沸石催化剂分配使用乙酸酐。 反应在溶剂的室温至回流温度的温度下进行

公开(公告)号：US20040006248A1

公开(公告)日：2004-01-08

申请号：US10311319

申请日：2002-12-30

Applicant: ZAMBON GROUP S.P.A

Inventor： Maurizio Paiocchi ,  Aldo Belli ,  Francesco Ponzini ,  Marco Villa

IPC: C07C027/00

CPC classification number: C07C201/08 ,  C07C2602/28 ,  C07D311/58 ,  C07C205/05

Abstract: A process for the nitration of conjugated alkenes of formula (I) wherein R, R1, R2, R3 and R4 have the meanings reported in the description, which allows to obtain the corresponding null-nitro-alkenes, characterised in that the nitrating agent is a mixture of an inorganic nitrite and iodine in the presence of an oxidising agent is described. 1

Abstract translation: 用于硝化式（I）的共轭烯的方法，其中R，R 1，R 2，R 3和R 4具有在说明书中报道的含义，其允许获得相应的β-硝基 - 烯烃，其特征在于硝化剂是 描述了在氧化剂存在下无机亚硝酸盐和碘的混合物。

公开(公告)号：US20030181771A1

公开(公告)日：2003-09-25

申请号：US10360192

申请日：2003-02-06

Inventor： Ralf Demuth ,  Matthias Gotta ,  Thomas Linn ,  Hans-Martin Weber ,  Eberhard Zirngiebl

IPC: C07C21/08

CPC classification number: C07C201/08 ,  C07C205/12

Abstract: The present invention relates to a continuous adiabatic process for preparing nitrochlorobenzene in the presence of phosphoric acid. The waste acid produced during the practice of the process is reconcentrated and recycled into the nitration reaction.

Abstract translation: 本发明涉及在磷酸存在下制备硝基氯苯的连续绝热方法。 在该过程的实践过程中产生的废酸被再浓缩并再循环到硝化反应中。