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公开(公告)号:US10539870B2
公开(公告)日:2020-01-21
申请号:US13907789
申请日:2013-05-31
Applicant: Rohm and Haas Electronic Materials, LLC
Inventor: William Williams, III , Cong Liu , Cheng-Bai Xu
IPC: G03F7/004 , C07C269/04 , C07C271/24 , G03F7/039
Abstract: New photoresist compositions are provided that comprise a carbamate compound that comprises 1) a carbamate group and 2) an ester group. Preferred photoresists of the invention may comprise a resin with acid-labile groups; an acid generator compound; and a carbamate compound that can function to decrease undesired photogenerated-acid diffusion out of unexposed regions of a photoresist coating layer.
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公开(公告)号:US10527934B2
公开(公告)日:2020-01-07
申请号:US13665232
申请日:2012-10-31
Applicant: Rohm and Haas Electronic Materials LLC
Inventor: Gerhard Pohlers , Cong Liu , Cheng-Bai Xu , Chunyi Wu
IPC: G03F7/004 , C07C211/63 , C07C211/64 , G03F7/20 , G03F7/039
Abstract: New photoresist compositions are provided that comprise a component that comprises a radiation-insensitive ionic compound. Preferred photoresists of the invention may comprise a resin with photoacid-labile groups; a photoacid generator compound; and a radiation-insensitive ionic compound that can function to decrease undesired photogenerated-acid diffusion out of unexposed regions of a photoresist coating layer.
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公开(公告)号:US10042259B2
公开(公告)日:2018-08-07
申请号:US15730876
申请日:2017-10-12
Applicant: Rohm and Haas Electronic Materials LLC
Inventor: Irvinder Kaur , Cong Liu , Doris Kang , Mingqi Li , Deyan Wang , Huaxing Zhou
IPC: G03F7/11 , C08F20/34 , C08F222/40 , C08L33/16 , C09D133/08 , C09D133/10 , C09D133/16 , G03F7/00 , G03F7/038 , G03F7/039 , G03F7/32 , H01L21/027
Abstract: Topcoat compositions comprise: a matrix polymer; a surface active polymer comprising a polymerized unit formed from a monomer of the following general formula (I): wherein: R1 represents H, F, methyl or fluorinated methyl; R2 represents optionally substituted C1 to C8 alkylene or optionally substituted C1 to C8 fluoroalkylene, optionally comprising one or more heteroatom; R3 represents H, F, optionally substituted C1 to C10 alkyl or optionally substituted C5 to C15 aryl, optionally comprising one or more heteroatom; R4 represents optionally substituted C1 to C8 alkyl, optionally substituted C1 to C8 fluoroalkyl or optionally substituted C5 to C15 aryl, optionally comprising one or more heteroatom; X represents O, S or NR5, wherein R5 is chosen from hydrogen and optionally substituted C1 to C5 alkyl; and a is 0 or 1; and a solvent. Also provided are coated substrates and pattern-forming methods which make use of the topcoat compositions. The invention has particular applicability in photolithographic processes as a photoresist topcoat layer in the manufacture of semiconductor devices.
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公开(公告)号:US20180188654A1
公开(公告)日:2018-07-05
申请号:US15846658
申请日:2017-12-19
Applicant: Rohm and Haas Electronic Materials LLC
Inventor: Kevin Rowell , Cong Liu , Cheng Bai Xu , Irvinder Kaur , Xisen Hou , Mingqi Li
IPC: G03F7/40
Abstract: Pattern-formation methods comprise: (a) providing a substrate; (b) forming a photoresist pattern over the substrate; (c) applying a pattern treatment composition to the photoresist pattern, the pattern treatment composition comprising a solvent mixture comprising a first organic solvent and a second organic solvent, wherein the first organic solvent has a boiling point that is greater than a boiling point of the second organic solvent, and wherein the first organic solvent has a boiling point of 210° C. or more; and (d) thereafter heating the photoresist pattern. The methods find particular applicability in the manufacture of semiconductor devices.
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公开(公告)号:US09921475B1
公开(公告)日:2018-03-20
申请号:US15252522
申请日:2016-08-31
Applicant: Rohm and Haas Electronic Materials LLC
Inventor: Emad Aqad , William Williams, III , Cong Liu
IPC: G03F7/004 , G03F7/38 , C07C69/753 , C07C303/32 , C07C309/00 , C07C309/12 , C08F218/14 , G03F7/039 , G03F7/20 , G03F7/32 , C07C321/30 , G03F7/30 , C08F232/08
CPC classification number: G03F7/0045 , C07C69/753 , C07C303/32 , C07C309/00 , C07C309/12 , C07C381/12 , C07C2102/42 , C07C2103/74 , C07C2602/42 , C07C2603/74 , C07D303/40 , C07D317/34 , C07D317/72 , C07D327/08 , C07D333/76 , C07D335/16 , C07D339/08 , C07D409/12 , C07D493/18 , C08F232/08 , G03F7/0046 , G03F7/0397 , G03F7/30 , G03F7/38
Abstract: A photoacid-generating compound has the structure where R1, R2, R3, R4, Q, and X are defined herein. The photoacid-generating compound can be used as a component of a photoresist composition, or as a monomer incorporated into a polymer useful in a photoresist composition. The photoacid-generating compound provides a desired balance of solubility and line width roughness.
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公开(公告)号:US09869933B2
公开(公告)日:2018-01-16
申请号:US15062695
申请日:2016-03-07
Applicant: Rohm and Haas Electronic Materials LLC
Inventor: Kevin Rowell , Cong Liu , Cheng Bai Xu , Irvinder Kaur , Jong Keun Park
CPC classification number: G03F7/425 , G03F7/0392 , G03F7/16 , G03F7/2004 , G03F7/36 , G03F7/405 , H01L21/02057 , H01L21/0273 , H01L21/0274
Abstract: Methods of trimming a photoresist pattern comprise: (a) providing a semiconductor substrate; (b) forming a photoresist pattern over the semiconductor substrate, wherein the photoresist pattern is formed from a photoresist composition comprising: a first polymer comprising acid labile groups; and a photoacid generator; (c) coating a pattern trimming composition over the photoresist pattern, wherein the pattern trimming composition comprises a second polymer and a solvent system, wherein the solvent system comprises one or more monoether solvents in a combined amount of 50 wt % or more based on the solvent system; (d) heating the coated semiconductor substrate, thereby causing a change in solubility of a surface region of the photoresist pattern in a rinsing agent to be applied; and (e) contacting the photoresist pattern with a rinsing agent to remove the surface region of the photoresist pattern, thereby forming a trimmed photoresist pattern. The methods find particular applicability in the manufacture of semiconductor devices.
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公开(公告)号:US09760011B1
公开(公告)日:2017-09-12
申请号:US15062701
申请日:2016-03-07
Applicant: Rohm and Haas Electronic Materials LLC
Inventor: Kevin Rowell , Cong Liu , Cheng Bai Xu , Irvinder Kaur , Jong Keun Park
CPC classification number: G03F7/405 , G03F1/40 , G03F7/11 , G03F7/30 , G03F7/325 , H01L21/0273 , H01L21/0274
Abstract: Photoresist pattern trimming compositions comprise: a polymer that is soluble in a 0.26 normality aqueous tetramethylammonium hydroxide solution; and a solvent system, wherein the solvent system comprises one or more monoether solvents in a combined amount of from 50 to 98 wt % based on the solvent system. The compositions find particular applicability in the manufacture of semiconductor devices.
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公开(公告)号:US20170153542A1
公开(公告)日:2017-06-01
申请号:US15332340
申请日:2016-10-24
Applicant: Rohm and Haas Electronic Materials LLC
Inventor: Cong Liu , Cheng-Bai Xu
IPC: G03F7/004 , C07C321/28 , G03F7/039 , G03F7/16 , G03F7/20 , G03F7/32 , C07C313/04 , G03F7/038
Abstract: New bis(sulfonyl)imide and tri(sulfonyl)methide photoacid generator compounds (“PAGs”) are provided as well as photoresist compositions that comprise such PAG compounds.
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公开(公告)号:US09581904B2
公开(公告)日:2017-02-28
申请号:US14927357
申请日:2015-10-29
Applicant: Rohm and Haas Electronic Materials LLC
Inventor: Choong-Bong Lee , Stefan J. Caporale , Jason A. DeSisto , Jong Keun Park , Cong Liu , Cheng-Bai Xu , Cecily Andes
IPC: G03F7/039 , G03F7/38 , G03F7/11 , G03F7/004 , G03F7/075 , G03F7/09 , G03F7/20 , C09D4/06 , C09D133/06
CPC classification number: G03F7/11 , C09D4/06 , C09D133/06 , G03F7/0046 , G03F7/0752 , G03F7/091 , G03F7/2041 , C08F220/18
Abstract: Photoresist overcoat compositions are provided. The compositions comprise: a matrix polymer, an additive polymer a basic quencher and an organic solvent. The additive polymer has a lower surface energy than a surface energy of the matrix polymer, and the additive polymer is present in the overcoat composition in an amount of from 1 to 20 wt % based on total solids of the overcoat composition. The compositions have particular applicability in the semiconductor manufacturing industry for use in negative tone development processes.
Abstract translation: 提供光刻胶外涂层组合物。 组合物包括:基质聚合物,添加剂聚合物,碱性猝灭剂和有机溶剂。 添加剂聚合物具有比基体聚合物的表面能更低的表面能,并且添加剂聚合物以基于外涂层组合物的总固体的1至20重量%的量存在于外涂层组合物中。 该组合物在用于负色调发展方法的半导体制造业中具有特别的适用性。
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公开(公告)号:US09541834B2
公开(公告)日:2017-01-10
申请号:US13691689
申请日:2012-11-30
Applicant: Rohm and Haas Electronic Materials LLC
Inventor: Gerhard Pohlers , Cong Liu , Cheng-Bai Xu , Kevin Rowell , Irvinder Kaur
IPC: G03F7/40 , G03F7/30 , G03F7/09 , G03F7/11 , G03F7/039 , C07D239/26 , C07D241/12 , C07D263/32 , C07D277/22 , C07C309/03 , C07C309/06 , C07D333/48
CPC classification number: G03F7/40 , C07C309/03 , C07C309/06 , C07D239/26 , C07D241/12 , C07D263/32 , C07D277/22 , C07D333/48 , G03F7/0397 , G03F7/09 , G03F7/091 , G03F7/11 , G03F7/30 , G03F7/405
Abstract: New ionic thermal acid generator compounds are provided. Also provided are photoresist compositions, antireflective coating compositions, and chemical trim overcoat compositions, and methods of using the compositions.
Abstract translation: 提供新的离子热酸发生剂化合物。 还提供了光致抗蚀剂组合物,抗反射涂料组合物和化学修饰外涂层组合物,以及使用该组合物的方法。
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