公开(公告)号：US09502711B2

公开(公告)日：2016-11-22

申请号：US14967940

申请日：2015-12-14

Applicant: Board of Regents, The University of Texas System

Inventor： Shaoli Fang ,  Marcio Dias Lima ,  Xavier N. Lepro-Chavez ,  Javier Carretero-Gonzalez ,  Elizabeth Castillo-Martinez ,  Raquel Ovalle-Robles ,  Carter Sebastian Haines ,  David Michael Novitski ,  Mohammad H. Haque ,  Chihye Lewis-Azad ,  Mikhail Kozlov ,  Anvar A. Zakhidov ,  Ray H. Baughman

IPC: A01N25/34 ,  H01M4/04 ,  D01F9/12 ,  B01J21/18 ,  B01J21/06 ,  B01J35/00 ,  B01J35/06 ,  B01J37/02 ,  A61K9/70 ,  B05D3/12 ,  H01B12/06 ,  C23C16/04 ,  C23C14/58 ,  C23C14/04 ,  B05D5/00 ,  C23C16/56 ,  H01M4/131 ,  H01M4/133 ,  H01M4/1391 ,  H01M4/1393 ,  H01M4/58 ,  H01M4/587 ,  H01M4/96 ,  D02G3/16 ,  A61L15/18 ,  A61L17/04 ,  A61L31/02 ,  A61L31/16 ,  B01J23/42 ,  H01G11/86 ,  H01M8/00 ,  H01M10/0525

CPC classification number: H01M4/04 ,  A61K9/7007 ,  A61L15/18 ,  A61L17/04 ,  A61L31/024 ,  A61L31/16 ,  A61L2300/108 ,  A61L2300/414 ,  A61L2300/418 ,  A61L2400/12 ,  B01J21/063 ,  B01J21/18 ,  B01J21/185 ,  B01J23/42 ,  B01J35/0006 ,  B01J35/004 ,  B01J35/06 ,  B01J37/0215 ,  B01J37/0238 ,  B05D3/12 ,  B05D5/00 ,  C23C14/04 ,  C23C14/58 ,  C23C16/04 ,  C23C16/56 ,  D01F9/12 ,  D02G3/16 ,  D10B2101/122 ,  H01B12/06 ,  H01G11/86 ,  H01M4/0402 ,  H01M4/131 ,  H01M4/133 ,  H01M4/1391 ,  H01M4/1393 ,  H01M4/5825 ,  H01M4/587 ,  H01M4/96 ,  H01M8/00 ,  H01M10/0525 ,  Y02E60/122 ,  Y02E60/50 ,  Y10T428/2918 ,  Y10T428/2929

Abstract: Fabrication of yarns or other shaped articles from materials in powder form (or nanoparticles or nanofibers) using carbon nanotube/nanofiber sheet as a platform (template). This includes methods for fabricating biscrolled yarns using carbon nanotube/nanofiber sheets and biscrolled fibers fabricated thereby.

公开(公告)号：US20160297681A1

公开(公告)日：2016-10-13

申请号：US15183282

申请日：2016-06-15

Applicant: Korea Institute of Science and Technology

Inventor： Han-Ik JOH ,  Su Young SON ,  Sung Ho LEE ,  Tae-Wook KIM

IPC: C01B31/04 ,  C23C14/06 ,  C08J9/26 ,  C23C16/26 ,  H01B1/04 ,  C09D5/24

CPC classification number: C01B31/0446 ,  B01J23/40 ,  B01J23/70 ,  B01J35/0013 ,  B01J35/06 ,  B01J35/065 ,  B01J37/0215 ,  B01J37/0232 ,  B32B18/00 ,  B82Y30/00 ,  B82Y40/00 ,  C01B32/184 ,  C01B32/186 ,  C01B2204/04 ,  C01B2204/32 ,  C04B35/524 ,  C04B35/62222 ,  C04B38/0032 ,  C04B2111/00844 ,  C04B2237/363 ,  C08J9/26 ,  C08J2201/046 ,  C08J2333/12 ,  C08J2333/20 ,  C09D5/24 ,  C23C14/0605 ,  C23C16/26 ,  H01B1/04 ,  Y10S977/734 ,  Y10S977/842 ,  Y10S977/932 ,  C04B35/52

Abstract: The present disclosure relates to a polymer-based large-area carbon nanomesh and a method for preparing the same. More particularly, the present disclosure provides a method for preparing a carbon nanomesh such as graphene nanomesh, including: preparing a polymer nanofilm by coating a solution of a block copolymer or a polymer mixture thereof on a substrate; stabilizing the polymer nanofilm by annealing such that the polymer nanofilm is phase-separated, a hole-forming polymer is removed and, at the same time, a nanomesh-forming polymer is cyclized and forms a stabilized polymer nanomesh; and carbonizing the stabilized polymer nanomesh by annealing at high temperature to prepare a carbon nanomesh. Using the phase separation and cyclization, a large-area carbon nanomesh with superior activity can be prepared simply with high reproducibility in large scale.

Abstract translation: 本发明涉及基于聚合物的大面积碳纳米体及其制备方法。 更具体地说，本公开内容提供了制备碳纳米材料如石墨烯纳米薄膜的方法，包括：通过将嵌段共聚物或其聚合物混合物的溶液涂布在基材上来制备聚合物纳米薄膜; 通过退火来稳定聚合物纳米薄膜，使得聚合物纳米薄膜相分离，除去空穴形成聚合物，同时使形成纳米成型聚合物的环状化并形成稳定的聚合物纳米薄膜; 并通过在高温下退火将稳定的聚合物纳米颗粒碳化以制备碳纳米体。 使用相分离和环化，可以简单地以大规模的高再现性制备具有优异活性的大面积碳纳米体。

公开(公告)号：US09463442B2

公开(公告)日：2016-10-11

申请号：US13818456

申请日：2011-08-12

Applicant: Zhonjie Lin ,  Jonathan Keith Bartley ,  Stuart Hamilton Taylor ,  Graham John Hutchings ,  Nicholas Francois Dummer

Inventor： Zhonjie Lin ,  Jonathan Keith Bartley ,  Stuart Hamilton Taylor ,  Graham John Hutchings ,  Nicholas Francois Dummer

IPC: B01J23/32 ,  B01J23/16 ,  B01J23/881 ,  B01J23/882 ,  B01J23/888 ,  B01J35/00 ,  B01J35/02 ,  B01J35/06 ,  B01J35/10 ,  B01J37/02 ,  C07C45/27 ,  B01J23/28 ,  B01J23/30 ,  B01J23/34 ,  B01J23/68 ,  C07C45/38

CPC classification number: B01J23/881 ,  B01J23/28 ,  B01J23/30 ,  B01J23/34 ,  B01J23/686 ,  B01J23/882 ,  B01J23/888 ,  B01J35/006 ,  B01J35/008 ,  B01J35/023 ,  B01J35/026 ,  B01J35/06 ,  B01J35/1009 ,  B01J35/1014 ,  B01J37/02 ,  B01J37/0207 ,  B01J2523/69 ,  C07C45/27 ,  C07C45/38 ,  C07C47/04

Abstract: A catalyst is provided, the catalyst comprising rods having mean length of 100 microns or less, the rods comprising a metal molybdate or tungstate, the metal being selected from the group consisting of iron, manganese, nickel, chromium, vanadium, aluminum, silver, titanium, copper, bismuth, and cobalt. A method of making such a catalyst is also provided.

Abstract translation: 提供催化剂，催化剂包含平均长度为100微米或更小的棒，该棒包括钼酸金属或钨酸盐，该金属选自铁，锰，镍，铬，钒，铝，银， 钛，铜，铋和钴。 还提供了制备这种催化剂的方法。

公开(公告)号：US09446386B2

公开(公告)日：2016-09-20

申请号：US13649622

申请日：2012-10-11

Applicant: ALLOY SURFACES COMPANY, INC.

Inventor： Vincent A. Durante ,  Rajinder Gill ,  Andrew Davis ,  Elaine C. Soltani

IPC: B01J23/755 ,  B01J21/02 ,  B01J32/00 ,  B01J23/89 ,  B01J37/02 ,  B01J37/06 ,  B01J37/18 ,  B01J23/847 ,  B01J23/44 ,  B01J23/63 ,  B01J23/80 ,  B01J23/86 ,  B01J25/02 ,  B01J35/10 ,  C01B3/40

CPC classification number: B01J23/894 ,  B01J21/02 ,  B01J23/44 ,  B01J23/63 ,  B01J23/755 ,  B01J23/80 ,  B01J23/8472 ,  B01J23/8476 ,  B01J23/866 ,  B01J23/8906 ,  B01J25/02 ,  B01J32/00 ,  B01J35/06 ,  B01J35/1019 ,  B01J37/0225 ,  B01J37/0228 ,  B01J37/06 ,  B01J37/14 ,  B01J37/18 ,  C01B3/40 ,  C01B2203/0233 ,  C01B2203/1041 ,  C01B2203/1058 ,  C01B2203/1064 ,  C01B2203/107 ,  C01B2203/1076 ,  C01B2203/1082 ,  C01B2203/1235 ,  C01B2203/1241 ,  C07C5/03 ,  C07C2521/02 ,  C07C2521/06 ,  C07C2523/44 ,  C07C2523/63 ,  C07C2523/755 ,  C07C2523/89 ,  C10G2/332 ,  C10G2/333 ,  C10G3/45 ,  C10G3/47 ,  Y02P20/52 ,  Y02P30/20

Abstract: The present invention relates to methods for producing metal-supported thin layer skeletal catalyst structures, to methods for producing catalyst support structures without separately applying an intermediate washcoat layer, and to novel catalyst compositions produced by these methods. Catalyst precursors may be interdiffused with the underlying metal support then activated to create catalytically active skeletal alloy surfaces. The resulting metal-anchored skeletal layers provide increased conversion per geometric area compared to conversions from other types of supported alloy catalysts of similar bulk compositions, and provide resistance to activity loss when used under severe on-stream conditions. Particular compositions of the metal-supported skeletal catalyst alloy structures can be used for conventional steam methane reforming to produce syngas from natural gas and steam, for hydrodeoxygenation of pyrolysis bio-oils, and for other metal-catalyzed reactions inter alia.

Abstract translation: 本发明涉及金属负载型薄层骨架催化剂结构体的制造方法，以及不分别涂布中间涂层的催化剂载体结构体的制造方法，以及由这些方法制造的新型催化剂组合物。 催化剂前体可以与下面的金属载体相互扩散，然后被活化以产生催化活性的骨架合金表面。 与来自其他类型的类似体积组合物的支撑合金催化剂的转化相比，所得到的金属锚定骨架层提供每几何面积的增加的转化率，并且当在严格的流动条件下使用时提供对活性损失的抵抗力。 金属支撑的骨架催化剂合金结构的特定组成可用于常规蒸汽甲烷重整，以从天然气和蒸汽产生合成气，用于热解生物油的加氢脱氧，以及其它金属催化反应。

公开(公告)号：US20160176756A1

公开(公告)日：2016-06-23

申请号：US15057601

申请日：2016-03-01

Applicant: Corning Incorporated

Inventor： Archit Lal ,  Windsor Pipes Thomas, III

IPC: C03C23/00 ,  C01B31/02 ,  C01B33/12

CPC classification number: C03C23/0025 ,  B01J21/08 ,  B01J35/002 ,  B01J35/0026 ,  B01J35/023 ,  B01J35/06 ,  B01J35/10 ,  B01J35/1004 ,  B01J37/349 ,  C01B32/16 ,  C01B32/162 ,  C01B33/12 ,  C03B19/1453 ,  C03C3/06 ,  C03C17/22 ,  C03C17/36 ,  C03C17/3605 ,  C03C17/3634 ,  C03C23/0095 ,  C03C2201/3488

Abstract: An assembly, such as for growing carbon nanotubes, includes a substrate including SiO2 and has a thickness of less than 500 μm. Further, the substrate is bendable and has a surface with non-flat or non-polished texture such that surface comprises raised and recessed features for receiving a coating, such as a catalyst. Carbon nanotubes may be anchored to and grow from the recessed features of the substrate.

Abstract translation: 诸如用于生长碳纳米管的组件包括包含SiO 2的衬底并且具有小于500μm的厚度。 此外，基底是可弯曲的并且具有非平坦或非抛光纹理的表面，使得表面包括用于接收诸如催化剂的涂层的凸起和凹陷特征。 碳纳米管可以锚定并从基底的凹陷特征生长。

公开(公告)号：US20160160362A1

公开(公告)日：2016-06-09

申请号：US14966356

申请日：2015-12-11

Applicant: Washington University

Inventor： Elijah James Thimsen ,  Pratim Biswas

IPC: C25B9/06 ,  C25B1/00 ,  H01L31/0352 ,  H01G9/20 ,  H01L31/032 ,  H01L31/068 ,  C25B11/02 ,  C25B1/04

CPC classification number: C25B9/06 ,  B01J21/063 ,  B01J35/06 ,  B01J37/349 ,  B82Y30/00 ,  C25B1/003 ,  C25B1/04 ,  C25B11/02 ,  H01G9/2031 ,  H01L31/032 ,  H01L31/0324 ,  H01L31/035281 ,  H01L31/03529 ,  H01L31/068 ,  Y02E10/542 ,  Y02E60/366 ,  Y02E70/10

Abstract: An improved process for the preparation of nanostructured metal species-based films in a flame aerosol reactor is provided. The present invention also further provides improved nanostructured photo-watersplitting cells, improved dye sensitized solar cells and improved nanostructured p/n junction solar cells.

Abstract translation: 提供了一种用于在火焰气溶胶反应器中制备纳米结构金属物质基膜的改进方法。 本发明还进一步提供改进的纳米结构光水分裂细胞，改进的染料敏化太阳能电池和改进的纳米结构的p / n结太阳能电池。

公开(公告)号：US20160061157A1

公开(公告)日：2016-03-03

申请号：US14698056

申请日：2015-04-28

Applicant: EDMOND POL JEAN LEPOUTRE

Inventor： EDMOND POL JEAN LEPOUTRE

IPC: F02M35/02 ,  F02M35/12 ,  B01D53/04 ,  F02M35/024 ,  B01D46/00 ,  B01D46/42

CPC classification number: F02M35/0216 ,  B01D46/0036 ,  B01D46/4236 ,  B01D53/0462 ,  B01D2253/102 ,  B01D2257/702 ,  B01D2259/4516 ,  B01J21/18 ,  B01J35/06 ,  F02M33/043 ,  F02M35/0218 ,  F02M35/02441 ,  F02M35/10137 ,  F02M35/10281 ,  F02M35/10334 ,  F02M35/12 ,  F02M35/1272 ,  F02M35/1277 ,  F16L11/118 ,  F16L55/0336

Abstract: ANTI-POLLUTION POROUS FLEX PIPE, refers to ananti-pollution porous flex pipe with its walls essentially comprised by tapes formed by interlaced textile fibers, to which activated charcoal is added (6), in agglomerate, powder or granulated form, and the textile tapes being wound over it and glued among it in the helical direction, forming an air conducting acoustic flexible helical pipe which is a part of the combustion engines intake system used by the automotive industry, adding the activated charcoal (6) in the walls or in the pipe's external (1) or internal (3) lining.

Abstract translation: 防污多孔挠性管是指一种抗污染的多孔柔性管，其壁基本上由隔行织物纤维形成的带组成，活性炭（6）以附聚物，粉末或颗粒形式加入到其中，纺织带 缠绕在其上并沿螺旋方向粘合在其中，形成导气弹性螺旋管，其是汽车工业使用的内燃机进气系统的一部分，将活性炭（6）添加到壁或在 管子的外部（1）或内部（3）内衬。

公开(公告)号：US09180438B2

公开(公告)日：2015-11-10

申请号：US14202978

申请日：2014-03-10

Applicant: NIPPON SEISEN CO., LTD. ,  Masaru Ichikawa

Inventor： Masaru Ichikawa ,  Yoshinori Tanimoto ,  Tsuneo Akiura

IPC: B01J37/12 ,  B01J35/10 ,  B01J23/89 ,  B01J21/04 ,  B01J21/06 ,  B01J23/42 ,  B01J23/652 ,  B01J23/656 ,  B01J23/755 ,  B01J23/86 ,  B01J35/00 ,  B01J35/02 ,  B01J35/06 ,  B01J37/02 ,  B01J37/34

CPC classification number: B01J23/8993 ,  B01J21/04 ,  B01J21/063 ,  B01J21/066 ,  B01J23/42 ,  B01J23/6525 ,  B01J23/6527 ,  B01J23/6567 ,  B01J23/755 ,  B01J23/866 ,  B01J23/892 ,  B01J35/0006 ,  B01J35/026 ,  B01J35/06 ,  B01J37/0215 ,  B01J37/0225 ,  B01J37/342 ,  Y10T29/49986

Abstract: A wire catalyst for hydrogenation reaction and/or dehydrogenation reaction comprises a metallic core and an oxide surface layer covering at least part of the surface thereof. The metallic core is electrically conductive so that the metallic core itself can generate heat by directly passing an electric current therethrough or electromagnetic induction. The oxide surface layer is made of an oxide of a metallic element constituting the metallic core. The oxide surface layer is provided with a porous structure having pores opening at the surface of the oxide surface layer. The catalytic material is supported in the pores of the oxide surface layer. When a shaped wire catalyst is manufactured, the shaping into a specific shape is made before the oxide surface layer having the porous structure is formed and the catalytic material is supported thereon.

Abstract translation: 用于氢化反应和/或脱氢反应的线催化剂包括覆盖其表面的至少一部分的金属芯和氧化物表面层。 金属芯是导电的，使得金属芯本身可以通过直接通过电流或电磁感应来产生热量。 氧化物表面层由构成金属芯的金属元素的氧化物构成。 氧化物表面层设置有在氧化物表面层的表面开口的多孔结构。 催化材料负载在氧化物表面层的孔中。 当制造成形网状催化剂时，在形成具有多孔结构的氧化物表面层之前进行成形为特定形状，并且催化材料被支撑在其上。

公开(公告)号：US09162935B2

公开(公告)日：2015-10-20

申请号：US13772080

申请日：2013-02-20

Applicant: Ceramatec, Inc.

Inventor： Joseph J. Hartvigsen ,  S. Elangovan ,  Lyman Joseph Frost

IPC: B01J19/24 ,  B01J8/06 ,  B01J35/00 ,  B01J35/06 ,  C07C1/04 ,  C10G2/00 ,  F28F7/02 ,  F28F13/00 ,  F28D7/00 ,  F28F1/12 ,  B01J8/00 ,  B01J8/02 ,  B01J35/02 ,  C07C1/00 ,  C07C1/02

CPC classification number: C07C1/041 ,  B01J8/067 ,  B01J35/0013 ,  B01J35/06 ,  B01J2208/00194 ,  B01J2208/026 ,  B01J2219/0002 ,  C10G2/33 ,  C10G2/341 ,  F28D7/0025 ,  F28F1/12 ,  F28F7/02 ,  F28F13/003

Abstract: A Fischer Tropsch (“FT”) unit includes at least one FT reactor tube. The FT reactor tube is configured to convert syngas into one or more hydrocarbon products. Inside the tube is a nano-sized catalyst particles dispersed in a micro-fibrous substrate. The FT reactor tube may be positioned within a cooling block that may be made of aluminum or another metal. The cooling block includes an aperture, wherein the FT reactor tube is housed within the aperture. At least one cooling channel is located on the cooling block. The cooling channel houses at least one cooling tube that is designed to dissipate the heat produced by the FT reaction.

Abstract translation: Fischer Tropsch（“FT”）单元包括至少一个FT反应器管。 FT反应器管被配置成将合成气转化为一种或多种烃产物。 管内部是分散在微纤维基质中的纳米级催化剂颗粒。 FT反应器管可以定位在可以由铝或另一种金属制成的冷却块内。 冷却块包括孔，其中FT反应器管容纳在孔内。 至少一个冷却通道位于冷却块上。 冷却通道容纳至少一个设计用于消散由FT反应产生的热量的冷却管。

公开(公告)号：US09162214B2

公开(公告)日：2015-10-20

申请号：US14463155

申请日：2014-08-19

Applicant: UOP LLC

Inventor： Paula L. Bogdan ,  Valeria J. Nemeth ,  Simon R. Bare

IPC: C07C5/02 ,  C07C5/03 ,  C07C5/10 ,  B01J21/00 ,  B01J23/00 ,  B01J23/40 ,  B01J23/42 ,  B01J23/44 ,  B01J23/58 ,  B01J23/02 ,  B01J21/04 ,  B01J23/63 ,  B01J37/18 ,  B01J35/06 ,  B01J35/10 ,  B01J37/02

CPC classification number: B01J23/63 ,  B01J23/44 ,  B01J35/06 ,  B01J35/1009 ,  B01J37/0207 ,  B01J37/18 ,  C07C5/03 ,  C07C2523/10 ,  C07C2523/44 ,  C07C2529/068 ,  C07C2601/14 ,  C07C13/18 ,  C07C9/15

Abstract: Aspects of the invention relate to hydrogenation catalysts, and hydrogenation processes using these catalysts, having particular characteristics, in terms of the amount and type of metal hydrogenation component (or catalytic constituent), as well as the support or substrate. The catalyst compositions, comprising both a noble metal and a lanthanide element on a substantially non-porous substrate, provide advantageous performance characteristics, including conversion, selectivity, and activity stability, as demanded in industrial hydrogenation and selective hydrogenation applications.

Abstract translation: 本发明的方面涉及使用这些催化剂的氢化催化剂以及在金属氢化组分（或催化组分）的量和类型以及载体或底物方面具有特定特征的氢化方法。 包含基本无孔基材上的贵金属和镧系元素的催化剂组合物提供了有利的性能特征，包括转化率，选择性和活性稳定性，如在工业氢化和选择性氢化应用中所要求的。