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    BIOMASS CONVERSION SYSTEMS PROVIDING INTEGRATED STABILIZATION OF A HYDROLYSATE USING A SLURRY CATALYST FOLLOWING BIOMASS PRETREATMENT AND METHODS FOR USE THEREOF
    32.
    发明申请
    BIOMASS CONVERSION SYSTEMS PROVIDING INTEGRATED STABILIZATION OF A HYDROLYSATE USING A SLURRY CATALYST FOLLOWING BIOMASS PRETREATMENT AND METHODS FOR USE THEREOF 审中-公开
    生物质转化系统提供使用生物质预处理的浆状催化剂的水解产物的综合稳定性及其使用方法

    公开(公告)号：US20160237360A1

    公开(公告)日：2016-08-18

    申请号：US15138841

    申请日：2016-04-26

    Applicant: SHELL OIL COMPANY

    Inventor： Joseph Broun Powell

    IPC: C10L1/04 ,  C10G3/00

    CPC classification number: C10L1/04 ,  C10G1/002 ,  C10G1/006 ,  C10G1/065 ,  C10G1/08 ,  C10G1/083 ,  C10G3/00 ,  C10G3/42 ,  C10G3/50 ,  C10G3/56 ,  C10G3/62 ,  C10G2300/1011 ,  C10G2300/1014 ,  C10L2200/0469 ,  C10L2290/06 ,  C10L2290/10 ,  C10L2290/12 ,  Y02E50/343 ,  Y02P30/20 ,  Y02T50/678

    Abstract: Digestion of cellulosic biomass solids to form a hydrolysate may be conducted with integrated catalytic reduction during digestion to transform soluble carbohydrates in the hydrolysate into a more stable reaction product. Such integrated catalytic reduction may be conducted using a slurry catalyst. Biomass conversion systems for performing integrated catalytic reduction can comprise: a hydrothermal digestion unit that contains a slurry catalyst capable of activating molecular hydrogen; an optional hydrogen feed line that is operatively connected to the hydrothermal digestion unit; a fluid circulation loop comprising the hydrothermal digestion unit and a catalytic reduction reactor unit, the catalytic reduction reactor unit also containing the slurry catalyst; a pretreatment digestion unit that is not part of the fluid circulation loop and does not contain the slurry catalyst; and a solids transport mechanism operatively connecting the pretreatment digestion unit to the hydrothermal digestion unit.

    Abstract translation: 消化纤维素生物质固体以形成水解产物可以在消化过程中进行一体化催化还原，以将水解产物中的可溶性碳水化合物转化为更稳定的反应产物。 这种一体化催化还原可以使用浆料催化剂进行。 用于进行一体化催化还原的生物质转化系统可以包括：含有能够活化分子氢的浆料催化剂的水热消解装置; 可操作地连接到水热消解单元的氢供给管线; 包括所述水热消解单元和催化还原反应器单元的流体循环回路，所述催化还原反应器单元还含有所述浆料催化剂; 预处理消化单元，其不是流体循环回路的一部分并且不含有浆料催化剂; 以及将预处理消化单元可操作地连接到水热消解单元的固体输送机构。

    Biomass conversion systems having a fluid circulation loop containing a centripetal force-based separation mechanism for control of cellulosic fines and methods for use thereof
    33.
    发明授权
    Biomass conversion systems having a fluid circulation loop containing a centripetal force-based separation mechanism for control of cellulosic fines and methods for use thereof 有权
    具有包含用于控制纤维素细粒的向心力分离机构的流体循环回路的生物质转化系统及其使用方法

    公开(公告)号：US09415367B2

    公开(公告)日：2016-08-16

    申请号：US14242934

    申请日：2014-04-02

    Applicant: SHELL OIL COMPANY

    Inventor： Joseph Broun Powell

    IPC: C07C1/00 ,  B01J19/00 ,  C10G3/00 ,  C10L1/02 ,  C10G1/00 ,  C10G1/06

    CPC classification number: B01J19/0046 ,  C10G1/002 ,  C10G1/065 ,  C10G3/00 ,  C10G3/42 ,  C10G2300/1014 ,  C10L1/02 ,  Y02P30/20

    Abstract: Digestion of cellulosic biomass to produce a hydrolysate may be accompanied by the formation of cellulosic fines which may be damaging to system components. Biomass conversion systems that may address the issue of cellulosic fines may comprise a fluid circulation loop comprising: a hydrothermal digestion unit; a solids separation unit that is in fluid communication with an outlet of the hydrothermal digestion unit; where the solids separation unit comprises a centripetal force-based separation mechanism that comprises a fluid outlet and a solids outlet; and a catalytic reduction reactor unit that is in fluid communication with the fluid outlet of the centripetal force-based separation mechanism and an inlet of the hydrothermal digestion unit.

    Abstract translation: 消化纤维素生物质以产生水解产物可伴随着可能损害系统组分的纤维素细粉的形成。 可能解决纤维素细粒问题的生物质转化系统可以包括流体循环回路，包括：水热消解单元; 固体分离单元，其与所述水热消解单元的出口流体连通; 其中固体分离单元包括向心力分离机构，其包括流体出口和固体出口; 以及催化还原反应器单元，其与向心力分离机构的流体出口和水热消解单元的入口流体连通。

    METHODS AND SYSTEMS FOR PROCESSING CELLULOSIC BIOMASS
    35.
    发明申请
    METHODS AND SYSTEMS FOR PROCESSING CELLULOSIC BIOMASS 审中-公开

    公开(公告)号：US20160184734A1

    公开(公告)日：2016-06-30

    申请号：US14980589

    申请日：2015-12-28

    Applicant: SHELL OIL COMPANY

    Inventor： Joseph Broun Powell ,  Glenn Charles Komplin ,  Juben Nemchand Chheda

    IPC: B01D11/04 ,  B01J19/24 ,  B01D3/06 ,  B01J8/18

    CPC classification number: B01D11/04 ,  B01D3/06 ,  B01J8/18 ,  B01J19/24 ,  B01J2219/24 ,  C10G1/002 ,  C10G1/065 ,  C10G1/083 ,  C10G3/50 ,  Y02P30/20

    Abstract: Separation of a product of digestion of cellulosic biomass solids may be challenging due to the various components contained therein. Methods and systems for processing cellulosic biomass, particularly a reaction product of a hydrothermal reaction containing lignin-derived products, such as phenolics, comprise providing the reaction product to a separation zone comprising a liquid-liquid extraction unit. The liquid-liquid extraction unit can provide an aqueous portion and a non-aqueous portion, where these portions can be separated into various fractions individually. For example, desirable compounds in the aqueous portion and non-aqueous portion can be recovered from the portions individually and optionally combined to be further processed into a fuels product. Heavier components in the aqueous portion and non-aqueous portion can be recovered from the portions individually and used in the process, such as phenolics that can be used as a digestion solvent.

    Biomass conversion process to hydrocarbons
    38.
    发明授权
    Biomass conversion process to hydrocarbons 有权

    公开(公告)号：US10221362B2

    公开(公告)日：2019-03-05

    申请号：US15194633

    申请日：2016-06-28

    Applicant: SHELL OIL COMPANY

    Inventor： Kimberly Ann Johnson ,  Joseph Broun Powell

    IPC: C10G1/06 ,  C10G3/00 ,  C10L1/04 ,  C07C29/132 ,  C07C45/41

    Abstract: A process for the production of a higher hydrocarbon useful as gasoline component from solid biomass is provided. The process provides for longer ZSM-5 condensation catalyst life by contacting the stable oxygenated hydrocarbon intermediate containing diols produced from digestion and hydrodoxygenation of the solid biomass to an amorphous silica alumina catalyst to reduce the diols content, and optionally removing water, prior to contacting with the ZSM-5 condensation catalyst.

    Biomass conversion process to hydrocarbons
    39.
    发明授权
    Biomass conversion process to hydrocarbons 有权

    公开(公告)号：US10167243B2

    公开(公告)日：2019-01-01

    申请号：US15194650

    申请日：2016-06-28

    Applicant: SHELL OIL COMPANY

    Inventor： Joseph Broun Powell ,  Kimberly Ann Johnson

    IPC: C10G1/06 ,  C10G3/00 ,  C10L1/04 ,  C07C29/60

    Abstract: An improved process for the production of a higher hydrocarbon from solid biomass is provided. Solid biomass that has been digested and hydrodeoxygenated in a liquid digestive solvent in the presence of a hydrothermal hydrocatalytic catalyst is separated to an organic rich phase and an aqueous rich phase containing diols. At least a portion of the aqueous rich phase is contacted with an acidic amorphous silica alumina catalyst producing monooxygenate-containing stream comprising water, organic monooxygenates, and unsaturated aliphatic hydrocarbons. At least a portion of the monooxygenate-containing stream is contacted with a solid acid condensation catalyst to produce a higher hydrocarbons stream. At least a portion of the organic rich phase is also contacted with a solid acid condensation catalyst to produce a higher hydrocarbons stream.

    Methods and systems for supplying hydrogen to a hydrocatalytic reaction
    40.
    发明授权
    Methods and systems for supplying hydrogen to a hydrocatalytic reaction 有权

    公开(公告)号：US10106746B2

    公开(公告)日：2018-10-23

    申请号：US15832805

    申请日：2017-12-06

    Applicant: SHELL OIL COMPANY

    Inventor： Andries Quirin Maria Boon ,  Joseph Broun Powell

    IPC: C10G1/06 ,  C01B3/38 ,  C10G3/00 ,  C12P5/02 ,  G06Q30/00 ,  C12M1/00

    Abstract: Systems and methods involving hydrocatalytic reactions that use molecular hydrogen obtained from a biogas generated from at least a portion of the hydrocatalytic reaction product. Hydrocatalytic reactions can require significant quantities of molecular hydrogen, particularly if the molecular hydrogen is being introduced under dynamic flow conditions. The present disclosure provides systems and methods that can allow for reducing the carbon footprint of the fuels formed from the hydrocatalytic reaction because at least a portion of the hydrogen used in the hydrocatalytic reaction has low carbon footprint. A fuel with low carbon footprint can qualify for certain governmental status that provides certain benefits.

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