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公开(公告)号:US20190060879A1
公开(公告)日:2019-02-28
申请号:US16110237
申请日:2018-08-23
Applicant: UOP LLC
Inventor: Stuart R. Miller , Susan C. Koster
IPC: B01J23/888 , C10G47/36 , C10G45/72 , G05B15/02
Abstract: A hydroprocessing catalyst has been developed. The catalyst is a crystalline transition metal tungstate material or metal sulfides derived therefrom, or both. The hydroprocessing using the crystalline transition metal tungstate material may include hydrodenitrification, hydrodesulfurization, hydrodemetallation, hydrodesilication, hydrodearomatization, hydroisomerization, hydrotreating, hydrofining, and hydrocracking. A data system comprising at least one processor; at least one memory storing computer-executable instructions; and at least one receiver configured to receive data of at least one unit or stream in fluid communication with and downstream from or upstream to a conversion process comprising at least one reaction catalyzed by the catalyst or a metal sulfide decomposition product of the catalyst has been developed.
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公开(公告)号:US20190060873A1
公开(公告)日:2019-02-28
申请号:US16106400
申请日:2018-08-21
Applicant: UOP LLC
Inventor: Stuart R. Miller , Susan C. Koster
IPC: B01J23/00 , B01J23/885 , B01J21/04 , B01J21/08 , B01J21/12 , B01J37/00 , B01J37/03 , B01J37/04 , B01J37/08 , B01J37/20 , C10G11/04 , C10G29/16
Abstract: A hydroprocessing catalyst has been developed. The catalyst is a crystalline transition metal molybdotungstate material or metal sulfides derived therefrom, or both. The hydroprocessing using the crystalline transition metal molybdotungstate material may include hydrodenitrification, hydrodesulfurization, hydrodemetallation, hydrodesilication, hydrodearomatization, hydroisomerization, hydrotreating, hydrofining, and hydrocracking.
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公开(公告)号:US11804615B2
公开(公告)日:2023-10-31
申请号:US17451217
申请日:2021-10-18
Applicant: UOP LLC
Inventor: Chunqing Liu , Xueliang Dong , Jinfeng Wu , Stuart R. Miller
IPC: H01M8/1004 , H01M8/18 , H01M8/1062 , H01M8/10 , H01M8/04119
CPC classification number: H01M8/1004 , H01M8/04171 , H01M8/1062 , H01M8/188 , H01M2008/1095
Abstract: Low cost membrane electrode assemblies (MEA) with improved coulombic efficiency (CE), reduced maintenance cost, and improved deliverable capacity have been developed for redox flow batteries and other electrochemical reaction applications. The MEA comprises: a microporous substrate membrane, first and second hydrophilic ionomeric polymer coating layers on surfaces of the microporous substrate membrane, and an electrode adhered to a second surface of the second hydrophilic ionomeric polymer coating layer. Methods of preparing the MEA and a redox flow battery system incorporating the MEA are also described.
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公开(公告)号:US20230198053A1
公开(公告)日:2023-06-22
申请号:US17559837
申请日:2021-12-22
Applicant: UOP LLC
Inventor: David E. Gray , William T. Kender , Stuart R. Miller
IPC: H01M16/00 , H01M8/18 , H01M8/04276 , H01M8/04746 , H01M8/04313
CPC classification number: H01M16/006 , H01M8/188 , H01M8/04283 , H01M8/04746 , H01M8/04313
Abstract: Devices and methods for managing the state of health of an electrolyte in redox flow batteries (RFB) efficiently are described. A diffusion cell is added to the RFB which controls one or more properties of the electrolytes using the diffusion of protons through a proton exchange membrane. The diffusion cell can resemble an electrochemical cell in that there are two fluid chambers divided by a proton conducting membrane. Anolyte flows through one side of the device where it contacts the proton conducting membrane, and catholyte flows through the second side of the device where it contacts the other face of the proton conducting membrane. The concentration gradient of protons from high concentration in the catholyte to low concentration in the anolyte is the driving force for proton diffusion, rather than electromotive force, which greatly simplifies the design and operation.
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公开(公告)号:US20230187652A1
公开(公告)日:2023-06-15
申请号:US17821723
申请日:2022-08-23
Applicant: UOP LLC
Inventor: Michael G. Baddeloo , Stuart R. Miller , Russell D. Schumaker
Abstract: Various current collectors for redox flow batteries are described. The current collectors include at least one metal plate encapsulated in a conductive polymer end plate, the metal plate to the back of a stack end plate with a conductive adhesive, and a flat metal plate having deformable tabs. Battery flow systems incorporating the current collectors are also described. Battery flow systems with easily replaceable current collectors are also described.
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公开(公告)号:US20230163337A1
公开(公告)日:2023-05-25
申请号:US17820273
申请日:2022-08-17
Applicant: UOP LLC
Inventor: Jinfeng Wu , Stuart R. Miller
IPC: H01M8/18 , H01M8/04186 , H01M8/04082
CPC classification number: H01M8/188 , H01M8/04186 , H01M8/04201
Abstract: A protective layer for an electrolyte in a flow battery and an electrolyte tank having a protective layer. The protective layer includes a light oil that includes hydrophobic hydrocarbons. The light oil having a density lower than a density of the electrolyte, the hydrophobic hydrocarbons being non-reactive to the electrolyte. The protective layer may be a liquid layer or may include a substrate impregnated with the light oil. An inert gas may also be utilized in the electrolyte tank.
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公开(公告)号:US20230097875A1
公开(公告)日:2023-03-30
申请号:US17820272
申请日:2022-08-17
Applicant: UOP LLC
Inventor: Stuart R. Miller , Christopher D. DiGiulio , William T. Kender
IPC: H01M8/18 , H01M50/46 , H01M50/673 , H01M8/04313
Abstract: A flow battery system with a cathode cell including a first electrode, an anode cell includes a second electrode, and a membrane between the two cells. A first electrolyte tank includes a catholyte. A second electrolyte tank includes an anolyte. The system includes two rebalancing cells. A first rebalancing cell is in fluid communication between the cathode cell and the first electrolyte tank and is configured to reduce active species from the catholyte. The second rebalancing cell is in fluid communication with the first electrolyte tank and the second electrolyte tank such that the first electrolyte tank and the second electrolyte tank are in direct fluid communication. The second rebalancing cell is configured to reduce active species from the catholyte and the reduced catholyte may be combined directly with the anolyte. The second rebalancing cell may be a chemical reactor, a catalytic reactor, or an electrochemical reactor.
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公开(公告)号:US11090636B2
公开(公告)日:2021-08-17
申请号:US16110182
申请日:2018-08-23
Applicant: UOP LLC
Inventor: Stuart R. Miller , Susan C. Koster
IPC: B01J23/888 , G05B15/02 , C10G45/72 , C10G47/36 , C01G53/00 , B01J37/08 , B01J37/03 , B01J37/06 , C01G41/00 , G16C20/90 , B01J27/049 , B01J37/00 , B01J37/04 , B01J37/20 , G16C20/70 , C01G41/02 , G16C20/10 , C10G45/50
Abstract: A hydroprocessing catalyst has been developed. The catalyst is a crystalline transition metal tungstate material or metal sulfides derived therefrom, or both. The hydroprocessing using the crystalline transition metal tungstate material may include hydrodenitrification, hydrodesulfurization, hydrodemetallation, hydrodesilication, hydrodearomatization, hydroisomerization, hydrotreating, hydrofining, and hydrocracking. A data system comprising at least one processor; at least one memory storing computer-executable instructions; and at least one receiver configured to receive data of a conversion process comprising at least one reaction catalyzed by the catalyst or a metal sulfide decomposition product of the catalyst has been developed.
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公开(公告)号:US10981151B2
公开(公告)日:2021-04-20
申请号:US16388357
申请日:2019-04-18
Applicant: UOP LLC
Inventor: Stuart R. Miller , Susan C. Koster
Abstract: A hydroprocessing catalyst or catalyst precursor has been developed. The catalyst is a poorly crystalline transition metal molybdotungstate material or a metal sulfide decomposition product thereof. The hydroprocessing using the crystalline ammonia transition metal molybdotungstate material may include hydrodenitrification, hydrodesulfurization, hydrodemetallation, hydrodesilication, hydrodearomatization, hydroisomerization, hydrotreating, hydrofining, and hydrocracking.
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公开(公告)号:US10882030B2
公开(公告)日:2021-01-05
申请号:US16106714
申请日:2018-08-21
Applicant: UOP LLC
Inventor: Stuart R. Miller , Susan C. Koster
IPC: B01J23/888 , G05B15/02 , C10G45/72 , C10G47/36 , C10G53/00 , B01J37/08 , B01J37/03 , B01J37/06 , C01G41/00 , G16C20/90 , B01J27/049 , B01J37/00 , B01J37/04 , B01J37/20 , G16C20/70 , C01G41/02 , G16C20/10 , C10G45/50 , C01G53/00
Abstract: A hydroprocessing catalyst has been developed. The catalyst is a crystalline transition metal tungstate material or metal sulfides derived therefrom, or both. The hydroprocessing using the crystalline transition metal tungstate material may include hydrodenitrification, hydrodesulfurization, hydrodemetallation, hydrodesilication, hydrodearomatization, hydroisomerization, hydrotreating, hydrofining, and hydrocracking.
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