Active energy curable resin composition, hard coat laminated film, and film for application to glass

    公开(公告)号:US11248141B2

    公开(公告)日:2022-02-15

    申请号:US16618651

    申请日:2018-04-23

    Inventor: Motohiro Shimizu

    Abstract: Embodiments provide an active energy curable resin composition containing (A) 100 parts by mass of a UV-absorbing polymer and (B) 20-600 parts by mass of a polyfunctional (meth)acrylate. The UV-absorbing polymer (A) contains: (a1) 10-60 mol % of a structural unit derived from a (meth)acrylate including one or more of one or more types of backbone selected from the group consisting of a benzotriazole backbone, a triazine backbone, and a benzophenone backbone per molecule; (a2) 10-50 mol % of a structural unit derived from an alkyl (meth)acrylate; and (a3) 10-70 mol % of a structural unit derived from a compound including one or more isocyanate groups per molecule; the sum of the structural unit derived from a (meth)acrylate of component (a1), the structural unit derived from an alkyl (meth)acrylate of component (a2), and the structural unit derived from an isocyanate-group-including compound of component (a3) being 100 mol %.

    Multilayer hard coating film
    34.
    发明授权

    公开(公告)号:US11065851B2

    公开(公告)日:2021-07-20

    申请号:US15559400

    申请日:2016-02-05

    Abstract: One embodiment provides a multilayer hard coating film which sequentially includes, from the superficial layer side, a first hard coating and a resin film, and wherein: the first hard coating is formed from a coating material that contains a specific amount of (A) a polyfunctional (meth)acrylate and a specific amount of (B) a water repellent agent, while containing no inorganic particles; and the resin film includes at least one layer of (α) an acrylic resin that contains 50-95% by mole of a structural unit derived from methyl methacrylate and 50-5% by mole of a structural unit derived from vinyl cyclohexane when the total of the structural units derived from polymerizable monomers is taken as 100% by mole. Another embodiment provides a multilayer hard coating film which includes a second hard coating in addition to a first hard coating, and wherein: the first hard coating contains (C) a silane coupling agent in addition to the above-described components (A) and (B); and the second hard coating is formed from a coating material that contains a specific amount of (A) a polyfunctional (meth)acrylate and a specific amount of (D) inorganic fine particles having an average particle diameter of 1-300 nm.

    MULTILAYER FILM
    35.
    发明申请

    公开(公告)号:US20210122146A1

    公开(公告)日:2021-04-29

    申请号:US16622643

    申请日:2018-05-18

    Abstract: Embodiments provide a multilayer film in which: a first acrylic resin layer (α1), an aromatic polycarbonate resin layer (β), and a second acrylic resin layer (α2) are directly laminated in the stated order; the aromatic polycarbonate resin constituting the aromatic polycarbonate resin layer (β) is a product of ester exchange between a polycarbonic acid ester of an aromatic dihydroxy compound and a low-crystalline or amorphous aromatic polyester; and the relationships (Tβ−Tα1)≤30 and (Tβ−Tα2)≤30 (where Tal is the glass transition temperature of the acrylic resin constituting the first acrylic resin layer (α1), Tα2 is the glass transition temperature of the acrylic resin constituting the second acrylic resin layer (α2), Tβ is the glass transition temperature of the aromatic polycarbonate resin constituting the aromatic polycarbonate resin layer (β), and all of the temperatures are measured in degrees Celsius) are satisfied. The glass transition temperature of the aromatic polycarbonate resin should be 100-140° C.

    Packing box
    37.
    发明授权

    公开(公告)号:US10549881B2

    公开(公告)日:2020-02-04

    申请号:US16116398

    申请日:2018-08-29

    Inventor: Motohiro Shimizu

    Abstract: Embodiments provide a packing box whereby strength is improved and efficiency of opening, content retrieval, etc. is improved. Embodiments provide a packing box obtained from an upper cover and a lower box configured from cardboard for accommodating articles therein, in which: the upper cover is obtained from a top board that covers the entire interior of the lower box and side boards that extend vertically downward from each side of the top board and substantially covers the side surfaces of the lower box; and at least one notch is provided on one of the lower edges of the upper cover.

    Method for producing anti-blocking hard coat film

    公开(公告)号:US10538673B2

    公开(公告)日:2020-01-21

    申请号:US15809821

    申请日:2017-11-10

    Abstract: Embodiments of the invention provide a hard coat film, including a film base material and a hard coat arranged on at least one surface of the film base material, wherein the hard coat is comprised of an active energy ray-curable resin composition. The active energy ray-curable resin composition includes 100 parts by mass of (P) a urethane (meth)acrylate compound, 0.02 to 5 parts by mass of (Q) organic fine particles having an average particle size of 10 to 300 nm, and 0.0002 to 2 parts by mass of (R) an acrylic silicon leveling agent. The (R) acrylic silicon leveling agent is loaded in the active energy ray-curable resin composition in an amount of 1 part by mass or more based on 100 parts by mass of the (Q) organic fine particles.

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