SYSTEM AND COMPUTER-IMPLEMENTED METHOD FOR EXTRAPOLATING CALIBRATION SPECTRA

    公开(公告)号:US20210318280A1

    公开(公告)日:2021-10-14

    申请号:US16842849

    申请日:2020-04-08

    Abstract: The present disclosure relates to a computer-implemented method for forecasting calibration spectra including a step of providing a machine learning model trained using historical calibration data corresponding to different gas species at different pressures. The computer-implemented method also includes steps of performing a calibration scan of one gas species at one pressure using an analyzer and generating calibration curves for the analyzer corresponding to one or multiple gas species at multiple pressures using the machine learning model and the calibration scan. Thereafter, a spectrum is obtained using the analyzer, and a concentration measurement is generated using the spectrum and at least one of the calibration curves.

    SPECTROMETER WITH WIDE-SCAN TUNABLE DIODE LASER

    公开(公告)号:US20210018433A1

    公开(公告)日:2021-01-21

    申请号:US16511429

    申请日:2019-07-15

    Abstract: A method for implementation by a laser spectrometer is provided. The method includes first scanning, by a control unit using a first set of laser spectrometer operating parameters, a first wavelength range by adjusting a wavelength of light of a beam emitted by a laser light source and passing through a sample gas. The first wavelength range encompasses a first spectral feature corresponding to a first constituent. The method also includes at least one second scanning, by the control unit using a second set of laser spectrometer operating parameters, a second wavelength range by adjusting the wavelength of light emitted from the laser light source and passing through the sample gas. The second wavelength range has a second spectral feature corresponding to at least one second constituent. The control unit also determines a first concentration of the first constituent and a second concentration of the at least one second constituent.

    Dynamic reconstruction of a calibration state of an absorption spectrometer
    35.
    发明授权
    Dynamic reconstruction of a calibration state of an absorption spectrometer 有权
    吸收光谱仪的校准状态的动态重建

    公开(公告)号:US09360415B2

    公开(公告)日:2016-06-07

    申请号:US14263942

    申请日:2014-04-28

    Abstract: A reference harmonic absorption curve of a laser absorption spectrometer can have a reference curve shape derived from a reference signal generated by the detector in response to light passing from the laser light source through a reference gas or gas mixture. The reference gas or gas mixture can include one or more of a target analyte and a background gas expected to be present during analysis of the target analyte. A test harmonic absorption curve having a test curve shape is compared with the reference harmonic absorption curve to detect a difference between the test curve shape and the reference curve shape. Operating and/or analytical parameters of the laser absorption spectrometer are adjusted to correct the test curve shape to reduce the difference between the test curve shape and the reference curve shape.

    Abstract translation: 激光吸收光谱仪的参考谐波吸收曲线可以具有根据由检测器响应于从激光源通过参考气体或气体混合物的光而产生的参考信号导出的参考曲线形状。 参考气体或气体混合物可以包括目标分析物和预期在目标分析物的分析期间存在的背景气体中的一种或多种。 将具有测试曲线形状的测试谐波吸收曲线与参考谐波吸收曲线进行比较,以检测测试曲线形状与参考曲线形状之间的差异。 调整激光吸收光谱仪的操作和/或分析参数以校正测试曲线形状,以减小测试曲线形状与参考曲线形状之间的差异。

    Optical reflectors for spectrometer gas cells
    36.
    发明授权
    Optical reflectors for spectrometer gas cells 有权
    用于光谱仪气体电池的光学反射器

    公开(公告)号:US08842282B2

    公开(公告)日:2014-09-23

    申请号:US13712923

    申请日:2012-12-12

    Abstract: A spectrometer cell can include a spacer, at least one end cap, and at least one mirror with a reflective surface. The end cap can be positioned proximate to a first contact end of the spacer such that the end cap and spacer at least partially enclose an internal volume of the spectrometer cell. The mirror can be secured in place by a mechanical attachment that includes attachment materials that are chemically inert to at least one reactive gas compound. The mechanical attachment can hold an optical axis of the reflective surface in a fixed orientation relative to other components of the spectrometer cell and or a spectrometer device that comprises the spectrometer cell. The mirror can optionally be constructed of a material such as stainless steel, ceramic, or the like. Related methods, articles of manufacture, systems, and the like are described.

    Abstract translation: 光谱仪单元可以包括间隔物,至少一个端盖和至少一个具有反射表面的反射镜。 端盖可以定位成靠近隔离物的第一接触端,使得端盖和间隔件至少部分地包围光谱仪单元的内部体积。 镜子可以通过机械附件固定在适当的位置,该机械附件包括对至少一种反应性气体化合物具有化学惰性的附着材料。 机械附件可以将反射表面的光轴相对于分光计单元的其他部件和包括光谱仪单元的光谱仪装置固定在一定方向。 镜子可以任意地由诸如不锈钢,陶瓷等的材料构成。 描述了相关方法,制品,系统等。

    Dynamic Reconstruction Of A Calibration State Of An Absorption Spectrometer
    37.
    发明申请
    Dynamic Reconstruction Of A Calibration State Of An Absorption Spectrometer 有权
    吸收光谱仪的校准状态的动态重建

    公开(公告)号:US20140253922A1

    公开(公告)日:2014-09-11

    申请号:US14263942

    申请日:2014-04-28

    Abstract: A reference harmonic absorption curve of a laser absorption spectrometer can have a reference curve shape derived from a reference signal generated by the detector in response to light passing from the laser light source through a reference gas or gas mixture. The reference gas or gas mixture can include one or more of a target analyte and a background gas expected to be present during analysis of the target analyte. A test harmonic absorption curve having a test curve shape is compared with the reference harmonic absorption curve to detect a difference between the test curve shape and the reference curve shape. Operating and/or analytical parameters of the laser absorption spectrometer are adjusted to correct the test curve shape to reduce the difference between the test curve shape and the reference curve shape.

    Abstract translation: 激光吸收光谱仪的参考谐波吸收曲线可以具有根据由检测器响应于从激光源通过参考气体或气体混合物的光而产生的参考信号导出的参考曲线形状。 参考气体或气体混合物可以包括目标分析物和预期在目标分析物的分析期间存在的背景气体中的一种或多种。 将具有测试曲线形状的测试谐波吸收曲线与参考谐波吸收曲线进行比较,以检测测试曲线形状与参考曲线形状之间的差异。 调整激光吸收光谱仪的操作和/或分析参数以校正测试曲线形状,以减小测试曲线形状与参考曲线形状之间的差异。

    Reactive gas detection in complex backgrounds
    38.
    发明授权
    Reactive gas detection in complex backgrounds 有权
    复杂背景下的反应性气体检测

    公开(公告)号:US08500849B2

    公开(公告)日:2013-08-06

    申请号:US13428626

    申请日:2012-03-23

    Abstract: A differential absorption spectrum for a reactive gas in a gas mixture can be generated for sample absorption data by subtracting background absorption data set from the sample absorption data. The background absorption data can be characteristic of absorption characteristics of the background composition in a laser light scan range that includes a target wavelength. The differential absorption spectrum can be converted to a measured concentration of the reactive gas using calibration data. A determination can be made whether the background composition has substantially changed relative to the background absorption data, and new background absorption data can be used if the background composition has substantially changed. Related systems, apparatus, methods, and/or articles are also described.

    Abstract translation: 可以通过从样品吸收数据中减去设置的背景吸收数据,为样品吸收数据产生气体混合物中的反应气体的差分吸收光谱。 背景吸收数据可以是包括目标波长的激光扫描范围中背景组合物的吸收特性的特征。 使用校准数据可以将差示吸收光谱转换为测量的反应气体浓度。 可以确定背景组合物是否相对于背景吸收数据基本上改变,并且如果背景组合物已经基本上改变,则可以使用新的背景吸收数据。 还描述了相关系统,装置,方法和/或制品。

    Reactive gas detection in complex backgrounds

    公开(公告)号:US07819946B2

    公开(公告)日:2010-10-26

    申请号:US12763124

    申请日:2010-04-19

    Abstract: A differential absorption spectrum for a reactive gas in a gas mixture can be generated for sample absorption data by subtracting background absorption data set from the sample absorption data. The background absorption data can be characteristic of absorption characteristics of the background composition in a laser light scan range that includes a target wavelength. The differential absorption spectrum can be converted to a measured concentration of the reactive gas using calibration data. A determination can be made whether the background composition has substantially changed relative to the background absorption data, and new background absorption data can be used if the background composition has substantially changed. Related systems, apparatus, methods, and/or articles are also described.

    Reactive gas detection in complex backgrounds
    40.
    发明授权
    Reactive gas detection in complex backgrounds 有权
    复杂背景下的反应性气体检测

    公开(公告)号:US07704301B2

    公开(公告)日:2010-04-27

    申请号:US12101890

    申请日:2008-04-11

    Abstract: A differential absorption spectrum for a reactive gas in a gas mixture can be generated for sample absorption data by subtracting background absorption data set from the sample absorption data. The background absorption data can be characteristic of absorption characteristics of the background composition in a laser light scan range that includes a target wavelength. The differential absorption spectrum can be converted to a measured concentration of the reactive gas using calibration data. A determination can be made whether the background composition has substantially changed relative to the background absorption data, and new background absorption data can be used if the background composition has substantially changed. Related systems, apparatus, methods, and/or articles are also described.

    Abstract translation: 可以通过从样品吸收数据中减去设置的背景吸收数据,为样品吸收数据产生气体混合物中的反应气体的差分吸收光谱。 背景吸收数据可以是包括目标波长的激光扫描范围中背景组合物的吸收特性的特征。 使用校准数据可以将差示吸收光谱转换为测量的反应气体浓度。 可以确定背景组合物是否相对于背景吸收数据基本上改变,并且如果背景组合物已经基本上改变,则可以使用新的背景吸收数据。 还描述了相关系统,装置,方法和/或制品。

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