Stable highly active supported copper based catalysts
    41.
    发明申请
    Stable highly active supported copper based catalysts 有权
    稳定的高活性负载型铜基催化剂

    公开(公告)号:US20020040161A1

    公开(公告)日:2002-04-04

    申请号:US09966526

    申请日:2001-09-28

    Abstract: Stable highly active supported copper based catalysts of copper oxide or elemental copper crystallites supported on mechanically stable aluminum oxide are disclosed. These catalysts are characterized by high surface area, small copper crystallite size, and high metal loading. The average crystallite size of the copper compound is from about 20 to about 300 A, the copper loading is from about 10 to about 35 weight percent, the average particle diameter is from about 0.1 mm to about 10 mm, and the total surface area is from about 20 to about 400 square meters per gram. The catalysts are useful for hydration of nitrites to amides, especially hydration of acrylonitrile to acrylamide. The catalysts are distinguished by high mechanical stability, extended lifetime, and excellent resistance to hydration and copper leaching.

    Abstract translation: 公开了负载在机械稳定的氧化铝上的稳定的高活性负载型铜基催化剂或氧化铜或元素铜微晶。 这些催化剂的特征在于表面积高,铜微晶尺寸小,金属负载量高。 铜化合物的平均微晶尺寸为约20至约300,铜负载量为约10至约35重量%,平均粒径为约0.1mm至约10mm,总表面积为 约20至约400平方米每克。 催化剂可用于将亚硝酸盐水合成酰胺,特别是将丙烯腈水合成丙烯酰胺。 催化剂的特征在于高机械稳定性,延长的使用寿命和优异的耐水化和铜浸出性。

    Reversible Derivatization of Poly (Aryl Ether Ketones)
    50.
    发明申请
    Reversible Derivatization of Poly (Aryl Ether Ketones) 有权
    聚(芳基醚酮)的可逆衍生化

    公开(公告)号:US20160075840A1

    公开(公告)日:2016-03-17

    申请号:US14878563

    申请日:2015-10-08

    CPC classification number: C08J5/24 C08G65/48 C08J2381/02 C08L71/10 C08L81/06

    Abstract: A method of forming a polymer matrix composite using a soluble derivative of a poly (aryl ether ketone) (PAEK). The method includes mixing a starting PAEK polymer with a solvent and an acid, said solvent being selected from a group consisting of diethylether, tetrahydrofuran (THF), dioxin, and chlorinated solvents; reacting the PAEK mixture with a Lewis acid and a thiol compound in amounts effective to form a poly (aryl ether thioacetal) compound which comprises at least one thioacetal group; and impregnating a plurality of fibers in a solution comprising said poly (aryl ether thioacetal) compound.

    Abstract translation: 使用聚(芳基醚酮)(PAEK)的可溶性衍生物形成聚合物基质复合物的方法。 该方法包括将起始PAEK聚合物与溶剂和酸混合,所述溶剂选自二乙醚,四氢呋喃(THF),二恶英和氯化溶剂; 使PAEK混合物与路易斯酸和硫醇化合物以有效形成包含至少一个硫代缩醛基的聚(芳基醚硫代缩醛)化合物的量反应; 并在包含所述聚(芳基醚硫代缩醛)化合物的溶液中浸渍多根纤维。

Patent Agency Ranking