Methods of operating surface reactors and reactors employing such methods
    41.
    发明申请
    Methods of operating surface reactors and reactors employing such methods 有权
    使用这种方法操作表面反应器和反应器的方法

    公开(公告)号:US20050053532A1

    公开(公告)日:2005-03-10

    申请号:US10656627

    申请日:2003-09-05

    Applicant: Richard Holl

    Inventor: Richard Holl

    Abstract: Methods of operating surface reactors, and such reactors, particularly spinning disc reactors require that a first reactant is fed to the reactor surface and forms a thin film on the surface. A second reactant is fed to the surface in the form of a second thin film to interact with the first film so as to overcome the impedance to interaction between the two films imposed by the existence of molecular clusters in the films. Thus, each film is fed into the receiving film at a rate such as to break up the molecular clusters in the film and thereby permit the molecules to aggressively and completely interact with one another. In the spinning disc apparatus the films are fed at respective distances from the spin axis. The interaction takes place in a thin chamber (less than 1 mm) between a retaining surface coextensive with the reactor surface whose distance from one another can be varied continuously, with the components being sheared between the surfaces to break up the molecular clusters to facilitate molecular, forced interdiffusion. Preferably each film is fed into the reaction chamber through a respective annular nozzle producing an improved uniformity of initial and continuous contacting of the reactants followed by an increase in forced interdiffusion of reactant molecules.

    Abstract translation: 操作表面反应器和这种反应器,特别是旋转盘式反应器的方法要求将第一反应物进料到反应器表面并在表面上形成薄膜。 将第二反应物以第二薄膜的形式供给到表面以与第一膜相互作用,以克服由膜中分子簇的存在施加的两个膜之间的相互作用的阻抗。 因此,每个膜以一定的速率进入接收膜,以破坏膜中的分子簇,从而允许分子彼此积极地和完全地相互作用。 在旋转圆盘装置中,薄膜以相对于旋转轴线的距离进给。 相互作用发生在与反应器表面共同延伸的保持表面之间的薄室(小于1mm)中,其彼此的距离可以连续变化,其中组分在表面之间剪切以分解分子簇以促进分子 ,强制相互扩散。 优选地,每个膜通过相应的环形喷嘴进料到反应室中,产生反应物的初始和连续接触的改进的均匀性,随后反应物分子的强制相互扩散增加。

    Generator and process for generating a product gas
    43.
    发明授权
    Generator and process for generating a product gas 失效
    用于产生产品气体的发生器和过程

    公开(公告)号:US5900219A

    公开(公告)日:1999-05-04

    申请号:US690331

    申请日:1996-07-25

    Abstract: In order to improve a generator for generating a product gas by means of a chemical reaction between an educt gas and a liquid, comprising a closed reaction chamber with a liquid supply, a liquid discharge, an educt gas supply, a product gas discharge, a liquid bath arranged within the reaction chamber and a substrate member arranged for rotation in the reaction chamber, the axis of rotation of this substrate member being arranged such that during a rotation of the substrate member at least part of the surface of the substrate member alternatingly dips into the liquid bath and emerges from the liquid bath wetted by the liquid, such that a motor arranged outside the reaction chamber for rotating the substrate member can be dispensed with and the requirement of a pressure-tight passage for a drive shaft of the substrate member through a wall of the reaction chamber is not applicable it is suggested that the generator comprise a flow generator for generating a continuous flow of the liquid in the reaction chamber and that the substrate member comprise at least one momentum receiver for receiving part of the momentum of the flow of the liquid and for generating a rotary motion of the substrate member about its axis of rotation.

    Abstract translation: 为了改善用于通过导管气体和液体之间的化学反应产生产物气体的发生器,其包括具有液体供应的封闭反应室,液体排放,排气供应,产物气体排放, 布置在反应室内的液体浴和设置成在反应室中旋转的基底构件,该基底构件的旋转轴线被布置成使得在衬底构件的旋转期间,衬底构件的表面的至少一部分交替地下降 进入液槽并从被液体润湿的液体浴中排出,从而可以省略设置在反应室外部用于旋转基板部件的马达,并且要求用于基板部件的驱动轴的压力通道 通过反应室的壁不适用,建议发电机包括用于产生液体的连续流动的流量发生器 d,并且衬底构件包括至少一个动量接收器,用于接收液体流动的一部分动量并且用于产生衬底构件绕其旋转轴线的旋转运动。

    Gas and liquid contacting process
    45.
    发明授权
    Gas and liquid contacting process 失效
    气体和液体接触过程

    公开(公告)号:US5174928A

    公开(公告)日:1992-12-29

    申请号:US472752

    申请日:1990-01-31

    CPC classification number: F28F13/18 B01J10/02 F28D3/00 F28D9/0031

    Abstract: The structure, method of fabrication and uses of enclosed double plate heat transfer panels with prefabricated main panel bodies are introduced. In most applications, a pane is used to conduct a gas-liquid interaction such as vaporization, condesation, gas absorption, gas description, endothermic and exothermic chemical reactions inside while having a heat interaction with a fluid outside that undergoes a complementary operation. A panel (41) incorporates one or more of the following key features:(a) It comprises a prefabricated main body (42) and two reinforced mainfold conduits (47) and (49) welded to the main panel body by welds (45).(b) It has nozzles (48) for applying a liquid film inside the panel.(c) The inside surfaces (51) are textured to improve wettability and drainage.

    Abstract translation: 介绍了带有预制主面板的封闭双板传热面板的结构,制造方法和使用方法。 在大多数应用中,使用窗格进行气 - 液相互作用,例如汽化,凝结,气体吸收,气体描述,吸热和放热化学反应,同时与经过互补操作的外部流体发生热相互作用。 面板(41)包含一个或多个以下主要特征:(a)它包括预制主体(42)和两个通过焊接(45)焊接到主面板主体的加强主折叠导管(47)和(49) 。 (b)具有用于在面板内部施加液膜的喷嘴(48)。 (c)内表面(51)被纹理化以改善润湿性和排水性。

    Reactor having a discontinuous conduit means between surfaces of a
downwardly extending stationary spiral
    46.
    发明授权
    Reactor having a discontinuous conduit means between surfaces of a downwardly extending stationary spiral 失效
    具有不连续导管的反应器在向下延伸的固定螺旋的表面之间

    公开(公告)号:US5171405A

    公开(公告)日:1992-12-15

    申请号:US588993

    申请日:1990-09-27

    Abstract: Organic constituents in a liquid, such as a waste water from a municipal or industrial process (e.g. bleach plant extraction liquor from the bleaching of paper pulp) may proceed effectively without the addition of alkali. When the organic constituents are reacted with an oxygen containing gas at appropriate pressure and temperature conditions, oxidized organics and gaseous acidic products of oxidation (e.g. CO.sub.2) that are produced are continuously and immediately removed from the liquid so that they do not significantly contribute to lowering of the pH of the liquid, so that the reaction may proceed and the liquid remain alkaline. This may be accomplished in a gas sparged hydrocyclone in which the liquid is introduced into the first end of a vortex while oxygen is introduced from exteriorly of the vortex into contact with the liquid, or may be accomplished by causing the liquid to flow in a thin film in a downwardly extending spiral path and removing the acidic gases from a center portion of the spiral path. A reactor for effecting the last mentioned specific procedure includes a pressurized vertical vessel having a downwardly extending stationary spiral surface mounted in the vessel substantially concentric with it. Surface manifestations may be provided on the spiral surface for enhancing mixing of liquid with surrounding gas.

    Abstract translation: 液体中的有机成分,例如来自市政或工业方法的废水(例如漂白纸浆漂白植物提取液)可以有效地进行而不加碱。 当有机成分在合适的压力和温度条件下与含氧气体反应时,产生的氧化有机物和氧化的气态酸性产物(例如CO 2)连续地立即从液体中除去,使得它们不显着地有助于降低 的液体的pH值,使得反应可以进行并且液体保持碱性。 这可以在气体喷射式水力旋流器中完成,其中液体被引入涡流的第一端,而氧气从涡流外部引入与液体接触,或者可以通过使液体以薄的方式流动 膜以向下延伸的螺旋路径并从螺旋路径的中心部分去除酸性气体。 用于实现最后提到的具体方法的反应器包括加压的垂直容器,其具有安装在容器中的与其基本同心的向下延伸的固定螺旋表面。 可以在螺旋表面上提供表面表现,以增强液体与周围气体的混合。

    Process for producing .alpha.,.beta.-unsaturated carboxylic acid polymer
    48.
    发明授权
    Process for producing .alpha.,.beta.-unsaturated carboxylic acid polymer 失效
    制备α,β-不饱和羧酸聚合物的方法

    公开(公告)号:US4743664A

    公开(公告)日:1988-05-10

    申请号:US932316

    申请日:1986-11-19

    CPC classification number: B01J19/247 B01J10/02 C08F20/04 Y10S526/917

    Abstract: A less colored .alpha., .beta.-unsaturated carboxylic acid polymer having a relatively small molecular weigth and a sharp molecular weight distribution is produced by supplying an .alpha.,.beta.-unsaturated carboxylic acid monomer and a hydrogensulfite from one side of a reaction column and simultaneously supplying an oxygen-containing gas concurrently with the monomer to the reaction column. The polymer obtained is preferably used as a dispersant and an antiscaling agent.

    Abstract translation: 通过从反应塔的一侧供应α,β-不饱和羧酸单体和亚硫酸氢盐,同时提供一种较少着色的α,β-不饱和羧酸聚合物,其具有相对较小的分子重量和尖锐的分子量分布 含氧气体与单体同时进入反应塔。 所得聚合物优选用作分散剂和防垢剂。

    Gas-liquid reactor and a method for reacting liquids and gases
    49.
    发明授权
    Gas-liquid reactor and a method for reacting liquids and gases 失效
    气液反应器和液体和气体的反应方法

    公开(公告)号:US4604362A

    公开(公告)日:1986-08-05

    申请号:US691246

    申请日:1985-01-14

    Abstract: A gas-liquid reactor comprising an outside containment vessel and an inside reaction vessel rotatably supported within the outside containment vessel. A liquid is conducted into the inside reaction vessel, and that vessel is rotated to force the liquid therein against a wall of the reaction vessel and into a film having a stable and geometrically simple shape. A gas is also conducted into the inside reaction vessel to react with the liquid therein. Because of the stable and simple shape of the liquid, the reactions between the liquid and gases are relatively easy to analyze quantitatively.

    Abstract translation: 一种气液反应器,包括外部容纳容器和可旋转地支撑在外部容纳容器内的内部反应容器。 将液体引入内部反应容器中,并且使该容器旋转以迫使其中的液体抵靠反应容器的壁并且形成具有稳定且几何简单形状的膜。 气体也被引入到内部反应容器中以与其中的液体反应。 由于液体的稳定和简单的形状,液体和气体之间的反应相对容易定量分析。

    Apparatus for the sulfonation or sulfation of organic liquids
    50.
    发明授权
    Apparatus for the sulfonation or sulfation of organic liquids 失效
    用于有机液体磺化或硫酸化的装置

    公开(公告)号:US4335079A

    公开(公告)日:1982-06-15

    申请号:US198779

    申请日:1980-10-20

    Abstract: A continuous process is disclosed which comprises introducing a sulfonatable or sulfatable organic liquid onto a rotating reaction surface as a thin film, rotating the reaction surface at a velocity such that the thin film is continuously moved toward the periphery of the reaction surface, dividing the reaction surface into a plurality of areas, depositing within each area a controlled quantity of gaseous sulfur trioxide over the liquid film, maintaining the pressure during the reaction at subatmospheric levels, controlling the temperature of the reaction surface, moving the reaction product by centrifugal action to the periphery of the reaction surface and continuously collecting the reaction product.An apparatus for carrying out such a process is also disclosed.

    Abstract translation: 公开了一种连续的方法,其包括将可磺化或可硫化的有机液体作为薄膜引入到旋转的反应表面上,以使得薄膜连续移动到反应表面的周边的速度旋转反应表面, 将表面沉积到多个区域中,在液体膜内在每个区域内沉积受控量的气态三氧化硫,将反应期间的压力维持在低于大气压的水平,控制反应表面的温度,通过离心作用将反应产物移动到 反应表面的周边,并连续收集反应产物。 还公开了一种用于执行这种处理的装置。

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