Abstract:
Methods of operating surface reactors, and such reactors, particularly spinning disc reactors require that a first reactant is fed to the reactor surface and forms a thin film on the surface. A second reactant is fed to the surface in the form of a second thin film to interact with the first film so as to overcome the impedance to interaction between the two films imposed by the existence of molecular clusters in the films. Thus, each film is fed into the receiving film at a rate such as to break up the molecular clusters in the film and thereby permit the molecules to aggressively and completely interact with one another. In the spinning disc apparatus the films are fed at respective distances from the spin axis. The interaction takes place in a thin chamber (less than 1 mm) between a retaining surface coextensive with the reactor surface whose distance from one another can be varied continuously, with the components being sheared between the surfaces to break up the molecular clusters to facilitate molecular, forced interdiffusion. Preferably each film is fed into the reaction chamber through a respective annular nozzle producing an improved uniformity of initial and continuous contacting of the reactants followed by an increase in forced interdiffusion of reactant molecules.
Abstract:
A reactor including a rotatable disc (3) having a trough (13) in an upper surface (5) thereof. Reactant (15) is supplied to the trough (13) by way or a feed (4), the disc (3) is rotated at high speed, and the reactant (15) spills out of the trough (13) so as to form a film (17) on the surface (5). As the reactant (15) traverses the surface (5) of the disc (3), it undergoes chemical or physical process before being thrown from the periphery of the disc (3) into collector means (7).
Abstract:
In order to improve a generator for generating a product gas by means of a chemical reaction between an educt gas and a liquid, comprising a closed reaction chamber with a liquid supply, a liquid discharge, an educt gas supply, a product gas discharge, a liquid bath arranged within the reaction chamber and a substrate member arranged for rotation in the reaction chamber, the axis of rotation of this substrate member being arranged such that during a rotation of the substrate member at least part of the surface of the substrate member alternatingly dips into the liquid bath and emerges from the liquid bath wetted by the liquid, such that a motor arranged outside the reaction chamber for rotating the substrate member can be dispensed with and the requirement of a pressure-tight passage for a drive shaft of the substrate member through a wall of the reaction chamber is not applicable it is suggested that the generator comprise a flow generator for generating a continuous flow of the liquid in the reaction chamber and that the substrate member comprise at least one momentum receiver for receiving part of the momentum of the flow of the liquid and for generating a rotary motion of the substrate member about its axis of rotation.
Abstract:
Devices for making reaction products by atomizing into droplets a first liquid containing a first reactant into a gas containing a second reactant in a manner to form a reaction product within the droplets. The reaction is controlled by monitoring the transient conversion (conversion taking place in the time interval between the formation of the droplets and their coalescence into a mass of liquid) of first reactant to reaction product just before the droplets coalesce into a mass of a second liquid.
Abstract:
The structure, method of fabrication and uses of enclosed double plate heat transfer panels with prefabricated main panel bodies are introduced. In most applications, a pane is used to conduct a gas-liquid interaction such as vaporization, condesation, gas absorption, gas description, endothermic and exothermic chemical reactions inside while having a heat interaction with a fluid outside that undergoes a complementary operation. A panel (41) incorporates one or more of the following key features:(a) It comprises a prefabricated main body (42) and two reinforced mainfold conduits (47) and (49) welded to the main panel body by welds (45).(b) It has nozzles (48) for applying a liquid film inside the panel.(c) The inside surfaces (51) are textured to improve wettability and drainage.
Abstract:
Organic constituents in a liquid, such as a waste water from a municipal or industrial process (e.g. bleach plant extraction liquor from the bleaching of paper pulp) may proceed effectively without the addition of alkali. When the organic constituents are reacted with an oxygen containing gas at appropriate pressure and temperature conditions, oxidized organics and gaseous acidic products of oxidation (e.g. CO.sub.2) that are produced are continuously and immediately removed from the liquid so that they do not significantly contribute to lowering of the pH of the liquid, so that the reaction may proceed and the liquid remain alkaline. This may be accomplished in a gas sparged hydrocyclone in which the liquid is introduced into the first end of a vortex while oxygen is introduced from exteriorly of the vortex into contact with the liquid, or may be accomplished by causing the liquid to flow in a thin film in a downwardly extending spiral path and removing the acidic gases from a center portion of the spiral path. A reactor for effecting the last mentioned specific procedure includes a pressurized vertical vessel having a downwardly extending stationary spiral surface mounted in the vessel substantially concentric with it. Surface manifestations may be provided on the spiral surface for enhancing mixing of liquid with surrounding gas.
Abstract:
In plant for the production of alkylated resins from an alcohol of boiling point greater than 100.degree. C. at atmospheric pressure, comprising an alkylation reactor, a distillation column, a condenser, and a separator, structure is provided to ensure that contact between descending alcohol-rich liquid phase and the vapor stream of alcohol and water ascending from the reactor is confined essentially to the walls of the column.
Abstract:
A less colored .alpha., .beta.-unsaturated carboxylic acid polymer having a relatively small molecular weigth and a sharp molecular weight distribution is produced by supplying an .alpha.,.beta.-unsaturated carboxylic acid monomer and a hydrogensulfite from one side of a reaction column and simultaneously supplying an oxygen-containing gas concurrently with the monomer to the reaction column. The polymer obtained is preferably used as a dispersant and an antiscaling agent.
Abstract:
A gas-liquid reactor comprising an outside containment vessel and an inside reaction vessel rotatably supported within the outside containment vessel. A liquid is conducted into the inside reaction vessel, and that vessel is rotated to force the liquid therein against a wall of the reaction vessel and into a film having a stable and geometrically simple shape. A gas is also conducted into the inside reaction vessel to react with the liquid therein. Because of the stable and simple shape of the liquid, the reactions between the liquid and gases are relatively easy to analyze quantitatively.
Abstract:
A continuous process is disclosed which comprises introducing a sulfonatable or sulfatable organic liquid onto a rotating reaction surface as a thin film, rotating the reaction surface at a velocity such that the thin film is continuously moved toward the periphery of the reaction surface, dividing the reaction surface into a plurality of areas, depositing within each area a controlled quantity of gaseous sulfur trioxide over the liquid film, maintaining the pressure during the reaction at subatmospheric levels, controlling the temperature of the reaction surface, moving the reaction product by centrifugal action to the periphery of the reaction surface and continuously collecting the reaction product.An apparatus for carrying out such a process is also disclosed.