Hydrocarbon conversion with an acidic multimetallic catalytic composite
    45.
    发明授权
    Hydrocarbon conversion with an acidic multimetallic catalytic composite 失效
    用酸性多金属催化复合材料进行烃转化

    公开(公告)号:US3998723A

    公开(公告)日:1976-12-21

    申请号:US581249

    申请日:1975-05-27

    CPC classification number: B01J23/6567 B01J37/22 C10G35/09

    Abstract: Hydrocarbons are converted by contacting them at hydrocarbon conversion conditions with an acidic multimetallic catalytic composite comprising a combination of catalytically effective amounts of a platinum or palladium component, a rhodium component, a rhenium component, a tin component, and a halogen component with a porous carrier material. The platinum or palladium component, rhodium component, rhenium component, tin component, and halogen component are present in the multimetallic catalyst in amounts respectively, calculated on an elemental basis, corresponding to about 0.01 to about 2 wt. % platinum or palladium metal, about 0.01 to about 2 wt. % rhodium, about 0.01 to about 2 wt. % rhenium, about 0.01 to about 5 wt. % tin, and about 0.1 to about 3.5 wt. % halogen. Moreover, these metallic components are uniformly dispersed throughout the porous carrier material in carefully controlled oxidation states such that substantially all of the platinum or palladium component is present therein in the elemental metallic state, substantially all of the rhenium and rhodium components are present therein in the elemental metallic state or in a state which is reducible to the elemental metallic state under hydrocarbon conversion conditions or in a mixture of these states and substantially all of the tin component is present in an oxidation state above that of the elemental metal and in a particle size which is less than 100 Angstroms in maximum dimension. A specific example of the type of hydrocarbon conversion process disclosed is a process for the catalytic reforming of a low-octane gasoline fraction wherein the gasoline fraction and a hydrogen stream are contacted with the acidic multimetallic catalyst disclosed herein at reforming conditions.

    Abstract translation: 通过在烃转化条件下使它们与酸性多金属催化复合物接触来转化烃,所述酸性多金属催化复合物包含催化有效量的铂或钯组分,铑组分,铼组分,锡组分和卤素组分与多孔载体的组合 材料。 铂或钯组分,铑组分,铼组分,锡组分和卤素组分分别以基于元素计算的量存在于多金属催化剂中,相当于约0.01至约2重量% %铂或钯金属,约0.01至约2重量% %铑,约0.01至约2wt。 %铼,约0.01至约5wt。 %锡,和约0.1至约3.5重量% %卤素。 此外,这些金属组分在仔细控制的氧化态下均匀分散在整个多孔载体材料中,使得基本上所有的铂或钯组分都存在于元素金属状态中,基本上所有的铼和铑组分都存在于 元素金属状态或在烃转化条件下或在这些状态的混合物中可还原成元素金属状态的状态和基本上所有锡组分的状态存在于高于元素金属的氧化态,并且具有粒径 最小尺寸小于100埃。 所公开的烃转化方法的具体实例是一种低辛烷值汽油馏分的催化重整方法,其中汽油馏分和氢气流在重整条件下与本文公开的酸性多金属催化剂接触。

    Hydrocarbon conversion with an acidic multimetallic catalytic composite
    46.
    发明授权
    Hydrocarbon conversion with an acidic multimetallic catalytic composite 失效
    用酸性多金属催化复合材料进行烃转化

    公开(公告)号:US3956103A

    公开(公告)日:1976-05-11

    申请号:US555648

    申请日:1975-03-05

    Inventor: George J. Antos

    CPC classification number: C10G35/09 B01J23/6567

    Abstract: Hydrocarbons are converted by contacting them at hydrocarbon conversion conditions with an acidic multimetallic catalytic composite comprising a combination of catalytically effective amounts of a platinum or palladium component, a rhodium component, a rhenium component, and a halogen component with a porous carrier material. The platinum or palladium component, rhodium component, rhenium component, and halogen component are present in the multimetallic catalyst in amounts respectively, calculated on an elemental basis, corresponding to about 0.01 to about 2 wt. % platinum or palladium metal, about 0.01 to about 2 wt. % rhodium, about 0.01 to about 2 wt. % rhenium, and about 0.1 to about 3.5 wt. % halogen. Moreover, these metallic components are uniformly dispersed throughout the porous carrier material in carefully controlled oxidation states such that substantially all of the platinum or palladium component is present therein in the elemental metallic state and substantially all of the rhenium and rhodium components are present therein in the elemental metallic state or in a state which is reducible to the elemental metallic state under hydrocarbon conversion conditions or in a mixture of these states. A specific example of the type of hydrocarbon conversion process disclosed is a process for the catalytic reforming of a low-octane gasoline fraction wherein the gasoline fraction and a hydrogen stream are contacted with the acidic multimetallic catalyst disclosed herein at reforming conditions.

    Abstract translation: 通过在碳氢化合物转化条件下与含有催化有效量的铂或钯组分,铑组分,铼组分和卤素组分的组合的多元载体材料的酸性多金属催化复合物接触来转化碳氢化合物。 铂或钯组分,铑组分,铼组分和卤素组分分别以基于元素计算的量存在于多金属催化剂中,相当于约0.01至约2重量% %铂或钯金属,约0.01至约2重量% %铑,约0.01至约2wt。 %铼,和约0.1至约3.5wt。 %卤素。 此外,这些金属组分在仔细控制的氧化状态下均匀地分散在整个多孔载体材料中,使得基本上所有的铂或钯组分都存在于元素金属状态中,并且基本上所有的铼和铑组分都存在于 元素金属状态或在烃转化条件下或以这些状态的混合物中可还原成元素金属状态的状态。 所公开的烃转化方法的具体实例是一种低辛烷值汽油馏分的催化重整方法,其中汽油馏分和氢气流在重整条件下与本文公开的酸性多金属催化剂接触。

    Reforming with a group IIB-containing catalyst
    47.
    发明授权
    Reforming with a group IIB-containing catalyst 失效
    用含II​​B的催化剂进行重整

    公开(公告)号:US3951782A

    公开(公告)日:1976-04-20

    申请号:US233236

    申请日:1972-03-09

    Inventor: Waldeen C. Buss

    CPC classification number: C10G35/09 B01J23/60 B01J23/622 B01J23/6567 C10G49/06

    Abstract: A catalytic composition of matter comprising 0.01 to 5 weight percent of a platinum group component, 0.01 to 5 weight percent of a Group IIB component, 0.01 to 3 weight percent of a component selected from the group consisting of a rhenium component and a germanium component and 0.1 to 3 weight percent of a halogen in association with a porous solid carrier and processes for the hydroconversion of hydrocarbons using said catalyst.

    Abstract translation: 一种催化组合物,其包含0.01至5重量%的铂族组分,0.01至5重量%的IIB族组分,0.01至3重量%的选自铼组分和锗组分的组分,以及 与多孔固体载体相关的0.1至3重量%的卤素和使用所述催化剂加氢转化烃的方法。

    High surface area catalyst bodies
    49.
    发明授权
    High surface area catalyst bodies 失效
    高表面积催化剂体

    公开(公告)号:US3894963A

    公开(公告)日:1975-07-15

    申请号:US32410573

    申请日:1973-01-16

    Applicant: NORTON CO

    Abstract: High surface area alumina bodies for use as catalysts, catalyst carriers, and sorbents are made by controlled mixing of fine particle size platy boehmite alumina aggregates with a monobasic acid to produce non-pasty free-flowing particulate mass of aggregates of boehmite. This mass can then be formed by pressure into selected shapes such as rings, saddles, cylinders, solid, or hollow, or pellets, dried and fired to produce bodies of boehmite, gamma alumina, delta alumina, theta alumina or alpha alumina ranging in surface area of from 10 square meters per gram to greater than 300 square meters per gram. Catalytic metal can be included in the bodies by impregnation, before or after firing, or can be incorporated by inclusion in the aqueous acid treating solution.

    Abstract translation: 用作催化剂,催化剂载体和吸附剂的高表面积氧化铝体是通过将微粒尺寸的扁平勃姆石氧化铝聚集体与一​​元酸控制混合制成勃姆石聚集体的非糊状自由流动的颗粒物。 然后可以通过压力将该质量形成为选定的形状,例如环,鞍座,圆柱体,固体或中空或颗粒,干燥和烧制以产生勃姆石,γ氧化铝,δ氧化铝,θ氧化铝或α氧化铝的表面 面积从10平方米每克到大于300平方米每克。 催化金属可以通过浸渍,烧制之前或之后包含在体内,或通过包含在酸性水溶液中而被引入。

    Process for hydrogen isotope exchange and concentration between liquid water and hydrogen gas and catalyst assembly therefor
    50.
    发明授权
    Process for hydrogen isotope exchange and concentration between liquid water and hydrogen gas and catalyst assembly therefor 失效
    氢同位素交换过程和液体与氢气和催化剂组合之间的浓度

    公开(公告)号:US3888974A

    公开(公告)日:1975-06-10

    申请号:US37916473

    申请日:1973-07-13

    CPC classification number: C01B5/02 B01D59/32 B01D59/33

    Abstract: A bithermal, catalytic, hydrogen isotope exchange process between liquid water and hydrogen gas to effect concentration of the deuterium isotope of hydrogen, wherein liquid water and hydrogen gas are contacted with one another and with at least one catalytically active metal selected from Group VIII of the Periodic Table, the catalyst body has a water repellent, gas and water vapour permeable, organic polymer or resin coating, preferably a fluorinated olefin polymer or silicone resin coating, so that the isotope exchange takes place by two simultaneously occurring, and closely coupled in space, steps namely, using protium (H) and deuterium (D) as the example, HD gas + H2O vapour catalyst H2 gas + HDO vapour

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