Low-platinum catalyst based on nitride nanoparticles and preparation method thereof

    公开(公告)号:US11524280B2

    公开(公告)日:2022-12-13

    申请号:US16726836

    申请日:2019-12-25

    Abstract: The present invention discloses a low-platinum catalyst based on nitride nanoparticles and a preparation method thereof. A component of an active metal of the catalyst directly clades on a surface of nitride particles or a surface of nitride particles loaded on a carbon support in an ultrathin atomic layer form. Preparation steps including: preparing a transition-metal ammonia complex first, nitriding the obtained ammonia complex solid under an atmosphere of ammonia gas to obtain nitride nanoparticles; loading the nitride nanoparticles on a surface of a working electrode, depositing an active component on a surface of the nitride nanoparticles by pulsed deposition, to obtain the low platinum loading catalyst using a nitride as a substrate. The catalyst may be used as an anode or a cathode catalyst of a low temperature fuel cell, has very high catalytic activity and stability, can greatly reduce a usage amount of a precious metal in the fuel cell, and greatly reduces a cost of the fuel cell. The present invention has important characteristics of being controllable in deposition amount, simple and convenient to operate, free of protection of inert atmosphere, and etc., and is suitable for large-scale industrial production.

    Self-polishing zwitterionic anti-fouling resin having main chain degradability and preparation therefor and use thereof

    公开(公告)号:US11512158B2

    公开(公告)日:2022-11-29

    申请号:US16605112

    申请日:2018-03-29

    Abstract: The present invention belongs to the technical field of marine anti-fouling materials, and discloses a self-polishing zwitterionic anti-fouling resin having a main chain degradability and the preparation therefor and the use thereof. The self-polishing zwitterionic anti-fouling resin is formed by copolymerizing the following three monomers (in the total mass of the monomers): 1% to 80% of an olefinic reactive monomer, 1% to 80% of a cycloketene acetal monomer, and 1% to 80% of a betaine type precursor. The anti-fouling resin has a main chain degradability and a side chain hydrolyzability, and the transition of a coating from being hydrophobic to being hydrophilic is achieved by the hydrolysis of a surface to produce a super-hydrophilic zwitterionic surface, in order to further enhance the anti-fouling ability of the system. The material not only overcomes the disadvantages of poor mechanical properties and poor solubility in an organic solvent of a zwitterionic material, but can also effectively control the long-term stable release of an anti-fouling agent, so as to achieve a synergistic anti-fouling effect of the anti-fouling agent and an anti-protein. The method of the present invention is simple, has a relatively low cost, and is suitable for industrial production. The material is used in the field of marine anti-fouling coatings.

    CONTROLLABLE PHASE CHANGE MATERIAL BAG AND PREPARATION METHOD THEREOF AND APPLICATION THEREOF

    公开(公告)号:US20220307773A1

    公开(公告)日:2022-09-29

    申请号:US17612573

    申请日:2019-10-28

    Abstract: A controllable phase change material bag and a preparation method and an application thereof are provided. The preparation method comprises the following steps: 1, form a metal plate or a metal bar with a rough surface, embedding a powder seed crystal that induces a phase change material to nucleate on the surface, then placing the metal plate or the metal bar in a sodium acetate solution to obtain a controllable trigger metal electrode (1); and 2, mixing a sodium acetate trihydrate crystal, water and a thickener to obtain an oversaturated phase change heat storage solution, pouring the solution into a metal ball (2), carrying out encapsulation after inserting the controllable trigger metal electrode obtained in the step 1 and a conducting electrode (3), and finally placing in the water bath to preserve heat to obtain the controllable phase change material bag.

    Filtering, power-dividing and phase-shifting integrated antenna array feed network

    公开(公告)号:US11450951B2

    公开(公告)日:2022-09-20

    申请号:US17262759

    申请日:2020-03-11

    Abstract: The invention discloses a feed network for an antenna array with integrated filtering, power splitting and phase shifting, comprising upper and lower metal floors, metal connecting posts, coaxial feed terminals, a suspended dielectric substrate, suspended strip lines and two phase-adjusting dielectric substrates; the upper and lower metal floors share a common ground through the metal connecting posts, the suspended strip lines are provided on the suspended dielectric substrate, the suspended dielectric substrate is positioned horizontally between the two phase-adjusting dielectric substrates, the two phase-adjusting dielectric substrates are positioned horizontally between the upper and lower metal floors; the suspended strip lines comprise a one-to-three filtering power splitting unit, two one-to-two unequal filtering power splitting units, two first phase-shifting lines and two second phase-shifting lines, the two phase-adjusting dielectric substrates cover the one-to-three filtering power splitting unit, part of the two first phase-shifting lines and the two second phase-shifting lines. The invention provides integrated design of the three functional circuits with filtering, power splitting and phase shifting to avoid cascading mismatch between different functional circuits in conventional designs.

    SYNCHRONOUS FLUORESCENCE DETECTOR FOR OBSERVING INTERFACE CONCENTRATION OF FLUORESCENT POLLUTANTS AND APPLICATION METHOD

    公开(公告)号:US20220276166A1

    公开(公告)日:2022-09-01

    申请号:US17749162

    申请日:2022-05-20

    Abstract: Provided are a synchronous fluorescence detector for observing the interface concentration of fluorescent pollutants and application method. The detector comprises a first electric displacement platform, a quartz cuvette, an excitation light path, a collection light path and a second electric displacement platform. The application method comprises the following steps: first exciting fluorescent pollutants by utilizing UV light with specific wavelengths to emit fluorescent light; then collecting fluorescence signals emitted by the excited fluorescent pollutants to the greatest extent by utilizing an UV anti-reflection convex lens combination; and finally, processing the fluorescent signals acquired by a photomultiplier by utilizing a difference method to determine a precise light intensity of a thin layer which is moved at a specific spacing by utilizing the electric displacement platforms so as to determine fugacity distribution of the fluorescent pollutants in the microlayer near an interface.

    A LITHIUM NEGATIVE ELECTRODE WITH PROTECTIVE LAYER, PREPARATION METHOD AND APPLICATION THEREOF

    公开(公告)号:US20220271280A1

    公开(公告)日:2022-08-25

    申请号:US17438035

    申请日:2020-10-30

    Abstract: Disclosed are a lithium negative electrode with a protective layer (1), a preparation method and an application thereof. The protective layer (1) of the lithium negative electrode is located on a surface of the electrode, and the protective layer (1) is a lithiated perfluorosulfonic acid membrane doped with nano molybdenum disulfide (3). The preparation method for the lithium negative electrode with the protective layer (1) comprises the following steps of: I. lithiation of a perfluorosulfonic acid; II. loading of the molybdenum disulfide (3); and III. coating and curing of the protective layer (1). The protective layer (1) of the lithium metal negative electrode of a lithium battery is capable of effectively inhibiting lithium dendrites, and weakening a shuttle effect, thereby improving a charge and discharge capacity, a rate capability and a cycle life of a lithium-sulfur battery.

    STARCH-BASED CARRIER MATERIAL WITH M CELL TARGETING PERFORMANCE AND PH RESPONSIVENESS, AND PREPARATION METHOD THEREFOR AND USE THEREOF

    公开(公告)号:US20220249677A1

    公开(公告)日:2022-08-11

    申请号:US17621728

    申请日:2019-11-28

    Abstract: Disclosed are a M-cell targeting and pH-responsive starch-based carrier material, and a preparation method and application thereof. The starch-based carrier material has a molecular structure as follows, a molecular weight of 7.04×104 to 2.11×106 g/mol, a degree of substitution of carboxymethyl groups of 0.04 to 0.28, and a grafting amount of targeting peptide GRGDS of 0.01% to 1.12% (calculated based on the content of N). The material is not dissolved in water when protonated at pH (pH=1.2) of the stomach, and is slowly dissolved in water when deprotonated at pH (pH=6.8) of the small intestine, therefore it has good responsiveness to pH of the gastrointestinal tract. The material can efficiently encapsulate a positively charged active substance by means of electrostatic interaction, therefore it can protect the active substances from being destroyed and inactivated in the gastrointestinal tract. Meanwhile, the material can target M cells to improve the transport efficiency of the active substance by M cells, thereby improving the bioavailability of the active substance.

    METHOD FOR CONTROLLING VIBRATION OF FLEXIBLE MECHANICAL ARM BASED ON COOPERATIVE TRACKING

    公开(公告)号:US20220234198A1

    公开(公告)日:2022-07-28

    申请号:US17614075

    申请日:2021-03-12

    Abstract: A method for controlling vibration of flexible mechanical arms based on cooperative tracking is disclosed, including: building a dynamic model of the flexible mechanical arm, according to a dynamic characteristic, constructing a flexible mechanical arm group made up of a plurality of flexible mechanical arms, assigning one of the plurality of flexible mechanical arms as a leader and the rest ones as followers which are required to track the leader's motion trajectory so as to realize cooperative work; designing cooperative control-based boundary controllers in combination with a Lyapunov method to realize cooperative work and suppress vibration of the flexible mechanical arms; and constructing a Lyapunov function using Lyapunov direct method to validate stability of the flexible mechanical arms under the control.

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