公开(公告)号：US20110196059A1

公开(公告)日：2011-08-11

申请号：US13122789

申请日：2009-09-09

Applicant: Akinori Nagai ,  Yoshiaki Chino ,  Masami Kobata ,  Osamu Isozaki

Inventor： Akinori Nagai ,  Yoshiaki Chino ,  Masami Kobata ,  Osamu Isozaki

IPC: C08F2/46 ,  C07F7/10

CPC classification number: C09D143/04 ,  C07F7/21 ,  C08F230/08 ,  C08G77/04 ,  C08G77/20 ,  C08G77/26

Abstract: To provide a composition comprising a silsesquioxane compound that is capable of producing a coating film with excellent heat resistance and scratch resistance, and that has excellent compatibility with general polymerizable unsaturated compounds as well as polymerizable unsaturated compounds with high polarity.A silsesquioxane compound comprising organic groups each directly attached to a silicon atom of the compound, at least one of the organic groups being an organic group having one or more urethane bonds and one (meth)acryloyloxy group.

Abstract translation: 本发明提供一种能够制造耐热性，耐划伤性优异的涂膜的倍半硅氧烷化合物，与一般的聚合性不饱和化合物以及具有高极性的聚合性不饱和化合物的相容性优异的组合物。 包含与化合物的硅原子直接相连的有机基团的倍半硅氧烷化合物，所述有机基团中的至少一个为具有1个以上的氨基甲酸酯键和1个（甲基）丙烯酰氧基的有机基团。

公开(公告)号：US07981507B2

公开(公告)日：2011-07-19

申请号：US11870685

申请日：2007-10-11

Applicant: Koichi Higuchi ,  Masaaki Yamaya

Inventor： Koichi Higuchi ,  Masaaki Yamaya

IPC: B32B9/04 ,  C08K3/36

CPC classification number: C09D143/04 ,  C08J7/047 ,  C08J2443/00 ,  Y10T428/259 ,  Y10T428/31663 ,  Y10T428/31667

Abstract: A primer composition for a polysiloxane hard coating is provided. This primer composition comprises (A) a vinyl polymer having a hydrolyzable silyl group and/or SiOH group and an organic UV absorbing group bonded to its side chain, and (B) fine silica particles dispersed in an organic solvent, and the primer layer formed after coating and curing has a coefficient of linear expansion of up to 150×10−6/° C.

Abstract translation: 提供了一种用于聚硅氧烷硬涂层的底漆组合物。 该底漆组合物包含（A）具有水解性甲硅烷基和/或SiOH基的乙烯基聚合物和与侧链结合的有机UV吸收基团，（B）分散在有机溶剂中的二氧化硅微粒，形成底涂层 涂层固化后的线膨胀系数可达150×10-6 /℃。

公开(公告)号：US07977407B1

公开(公告)日：2011-07-12

申请号：US13061750

申请日：2009-12-17

Applicant: Kiyomi Mori ,  Hidenori Waku ,  Nobuyuki Hamaura ,  Takayoshi Fujimoto ,  Satoshi Minamino

Inventor： Kiyomi Mori ,  Hidenori Waku ,  Nobuyuki Hamaura ,  Takayoshi Fujimoto ,  Satoshi Minamino

IPC: C09D5/14 ,  C09D5/16 ,  C08K5/098

CPC classification number: C09D5/165 ,  C08L93/04 ,  C09D5/1618 ,  C09D143/04 ,  C09D193/04 ,  Y10T428/31663 ,  C08L2666/26

Abstract: An object of the present invention is to provide a composition for forming an environment friendly antifouling coating film that can effectively exhibit an antifouling effect in seawater for a long period of time and furthermore exhibits a small temperature dependency of the coating film dissolving amount. The present invention provides an antifouling coating composition comprising: (A) a triorganosilyl ester-containing copolymer obtained by a mixture of (a) a triorganosilyl methacrylate monomer represented by a general formula (1) in which R1, R2, and R3 are equal or different each other, and each represent an alkyl group having 3 to 6 carbons and branched on α-position or a phenyl group, and (b) a methoxyalkyl methacrylate monomer represented by a general formula (2) in which R4 represents an alkylene group having 2 to 4 carbons, wherein a content ratio of the monomer (a) in the mixture is 45 to 65 weight %, and a total content of the monomer (a) and the monomer (b) in the mixture is 80 weight % or more, and a copper salt that is at least one member selected from the group consisting of rosin copper salts and copper salts of rosin derivatives.

Abstract translation: 本发明的目的是提供一种环境友好的防污涂膜的组合物，其能够长时间有效地在海水中显示防污效果，并且还显示出涂膜溶解量的温度依赖性。 本发明提供了一种防污涂料组合物，其包含：（A）通过（a）由通式（1）表示的甲基丙烯酸三有机甲硅烷酯单体（其中R 1，R 2和R 3相同）的混合物获得的含三有机甲硅烷基酯的共聚物，或 各自表示碳原子数为3〜6的烷基，在α-位或苯基上分支，（b）由通式（2）表示的甲基丙烯酸甲氧基烷基酯单体，其中，R 4表示具有 2至4个碳，其中混合物中单体（a）的含量比为45-65重量％，并且混合物中单体（a）和单体（b）的总含量为80重量％以上 以及选自由松香铜盐和松香衍生物的铜盐组成的组中的至少一种的铜盐。

公开(公告)号：US20110166253A1

公开(公告)日：2011-07-07

申请号：US13061750

申请日：2009-12-17

Applicant: Kiyomi Mori ,  Hidenori Waku ,  Nobuyuki Hamaura ,  Takayoshi Fujimoto ,  Satoshi Minamino

Inventor： Kiyomi Mori ,  Hidenori Waku ,  Nobuyuki Hamaura ,  Takayoshi Fujimoto ,  Satoshi Minamino

IPC: C09D5/16

CPC classification number: C09D5/165 ,  C08L93/04 ,  C09D5/1618 ,  C09D143/04 ,  C09D193/04 ,  Y10T428/31663 ,  C08L2666/26

Abstract: An object of the present invention is to provide a composition for forming an environment friendly antifouling coating film that can effectively exhibit an antifouling effect in seawater for a long period of time and furthermore exhibits a small temperature dependency of the coating film dissolving amount. The present invention provides an antifouling coating composition comprising: (A) a triorganosilyl ester-containing copolymer obtained by a mixture of (a) a triorganosilyl methacrylate monomer represented by a general formula (1) in which R1, R2, and R3 are equal or different each other, and each represent an alkyl group having 3 to 6 carbons and branched on α-position or a phenyl group, and (b) a methoxyalkyl methacrylate monomer represented by a general formula (2) in which R4 represents an alkylene group having 2 to 4 carbons, wherein a content ratio of the monomer (a) in the mixture is 45 to 65 weight %, and a total content of the monomer (a) and the monomer (b) in the mixture is 80 weight % or more, and a copper salt that is at least one member selected from the group consisting of rosin copper salts and copper salts of rosin derivatives.

Abstract translation: 本发明的目的是提供一种环境友好的防污涂膜的组合物，其能够长时间有效地在海水中显示防污效果，并且还显示出涂膜溶解量的温度依赖性。 本发明提供了一种防污涂料组合物，其包含：（A）通过（a）由通式（1）表示的甲基丙烯酸三有机甲硅烷酯单体（其中R 1，R 2和R 3相同）的混合物获得的含三有机甲硅烷基酯的共聚物，或 各自表示碳原子数为3〜6的烷基，在α-位或苯基上分支，（b）由通式（2）表示的甲基丙烯酸甲氧基烷基酯单体，其中，R 4表示具有 2至4个碳，其中混合物中单体（a）的含量比为45-65重量％，并且混合物中单体（a）和单体（b）的总含量为80重量％以上 以及选自由松香铜盐和松香衍生物的铜盐组成的组中的至少一种的铜盐。

公开(公告)号：US20110151265A1

公开(公告)日：2011-06-23

申请号：US13058679

申请日：2009-08-13

Applicant: T. Howard Killilea ,  Michael C. Wildman ,  Bruce A. Johnson ,  Carl H. Weber

Inventor： T. Howard Killilea ,  Michael C. Wildman ,  Bruce A. Johnson ,  Carl H. Weber

IPC: B32B13/12 ,  C09D133/08 ,  B05D3/02

CPC classification number: C09D143/04 ,  C08K5/54 ,  Y10T428/31663

Abstract: Coating compositions for cementitious substrates may be made from a multistage latex polymer; silane; and a water-soluble acid, acid anhydride or acid salt capable of etching or otherwise reacting with the surface of the substrate to provide improved coating adhesion. The silane my may be present as a silane coupling agent distinct from the multistage latex polymer, or may be present as silane functionality on the multistage latex polymer. The coating compositions adhere well to cementitious substrates and have a self-etching capability which improves coating adhesion, especially near edges and corners.

Abstract translation: 水泥基材的涂料组合物可以由多级胶乳聚合物制成; 硅烷 以及能够蚀刻或以其它方式与基材表面反应的水溶性酸，酸酐或酸盐，以提供改进的涂料粘合性。 硅烷my可以作为不同于多级胶乳聚合物的硅烷偶联剂存在，或者可以作为硅烷官能团存在于多级胶乳聚合物上。 涂料组合物很好地粘附到水泥质基材上，并且具有自蚀刻能力，其改善了涂层的附着力，特别是在边缘和角落附近。

公开(公告)号：US07928175B2

公开(公告)日：2011-04-19

申请号：US10548638

申请日：2004-03-12

Applicant: Mitsunori Sugihara ,  Yukihiro Ikegami ,  Kazuhiko Hotta ,  Kunio Iwase ,  Junichi Nakamura

Inventor： Mitsunori Sugihara ,  Yukihiro Ikegami ,  Kazuhiko Hotta ,  Kunio Iwase ,  Junichi Nakamura

IPC: C09D153/00

CPC classification number: C09D143/04 ,  C09D5/165 ,  C09D5/1668 ,  Y10T428/31663

Abstract: An object of the present invention is to provide an antifouling paint composition which shows an excellent antifouling effect in seawater for a long period of time, and has excellent adhesion and recoating properties to a substrate. The present invention relates to an antifouling pain composition comprising a copolymer which is obtained by polymerizing a monomer mixture comprising silicon-containing polymerizable monomer (a) having two (meth)acryl end groups, and which contains bivalent metal atom. The copolymer is also obtained by polymerizing a monomer mixture comprising silicon-containing polymerizable monomer (b) having one (meth)acryl end group, and metal atom containing polymerizable monomer (c,) having two unsaturated groups and metal atom selected from Mg, Zn, and Cu.

Abstract translation: 本发明的目的是提供一种防污涂料组合物，其在海水中长时间显示出优异的防污效果，并且对基材具有优异的粘附性和重涂性。 本发明涉及一种防污性疼痛组合物，其包含通过聚合包含含有两个（甲基）丙烯酸端基的含硅可聚合单体（a）并且含有二价金属原子的单体混合物而获得的共聚物。 共聚物也可以通过聚合包含具有一个（甲基）丙烯酸端基的含硅可聚合单体（b）和含有两个不饱和基团的金属原子的可聚合单体（c））和选自Mg，Zn ，和Cu。

公开(公告)号：US20110049146A1

公开(公告)日：2011-03-03

申请号：US12991826

申请日：2009-05-19

Applicant: Derek Ronald Illsley ,  Graham Trevor Street

Inventor： Derek Ronald Illsley ,  Graham Trevor Street

IPC: B65D21/02 ,  C08L29/04 ,  C08K3/34 ,  B05D3/02 ,  B32B27/00 ,  B32B1/02 ,  B82Y30/00

CPC classification number: C09D7/67 ,  B32B7/12 ,  B32B23/04 ,  B32B27/06 ,  B32B27/281 ,  B32B27/302 ,  B32B27/304 ,  B32B27/308 ,  B32B27/32 ,  B32B27/34 ,  B32B27/36 ,  B32B29/002 ,  B32B2250/24 ,  B32B2255/10 ,  B32B2255/12 ,  B32B2255/20 ,  B32B2255/26 ,  B32B2264/102 ,  B32B2307/546 ,  B32B2307/718 ,  B32B2307/7244 ,  B32B2307/7246 ,  B32B2439/46 ,  B32B2439/70 ,  B32B2439/80 ,  B65D65/42 ,  B65D77/06 ,  C08K3/36 ,  C08K2201/008 ,  C09D129/04 ,  C09D143/04 ,  Y10T428/1383 ,  C08L2666/04

Abstract: The use of a colloidal silica having a specific surface area greater than 300 m2/g in a gas barrier coating additionally comprising polyvinyl alcohol and/or ethylene vinyl alcohol copolymer and/or a silylated derivative thereof improves wet bond strength.

Abstract translation: 在另外包含聚乙烯醇和/或乙烯乙烯醇共聚物和/或其甲硅烷基化衍生物的阻气涂层中使用比表面积大于300m 2 / g的胶体二氧化硅改善了湿粘结强度。

公开(公告)号：US07879407B2

公开(公告)日：2011-02-01

申请号：US11576347

申请日：2005-10-08

Applicant: Andreas Poppeq ,  Guenter Klein ,  Michael Kutschera

Inventor： Andreas Poppeq ,  Guenter Klein ,  Michael Kutschera

IPC: B05D1/36 ,  C08G77/08

CPC classification number: C09D143/04

Abstract: The invention relates to coating agents, containing (A) at least 50 wt. %, (in relation to the content of non-volatile substances in said coating agent), of at least one compound (A1) and/or (A1′) comprising at least two reactive groups of formula (I): —X—SiR″x(OR′)3-x, in which R′=hydrogen, alkyl or cycloalkyl, whereby the carbon chain can be interrupted by non-adjacent oxygen, sulphur or NRa groups, Ra=alkyl, cycloalkyl, aryl or aralkyl, X=a linear and/or branched alkene or cycloalkene group comprising between 2 and 20 carbon atoms, R″=alkyl, cycloalkyl, aryl or aralkyl, whereby the carbon chain can be interrupted by non-adjacent oxygen, sulphur or NRa groups, and x=0 to 2, (B) a catalyst for cross-linking the —Si(OR′)3-x units, and (C) an organic solvent or a mixture of organic solvents. According to the invention, during the curing of the coating agents, the reactive groups (I) are cross-linked in such a way, that the following characteristics are noted during the nanoindentation test on the cured coating: elastic recovery of volume >86.5%; plastic deformation

Abstract translation: 本发明涉及包含（A）至少50wt。 至少一种包含至少两个式（I）的反应性基团的化合物（A1）和/或（A1'）：-X-SiR（相对于所述涂层剂中的非挥发性物质的含量） “x（OR'）3-x，其中R'=氢，烷基或环烷基，由此碳链可被非相邻的氧，硫或NR a基团中断，R a =烷基，环烷基，芳基或芳烷基，X =包含2至20个碳原子的直链和/或支链烯烃或环烯烃，R“=烷基，环烷基，芳基或芳烷基，由此碳链可以被不相邻的氧，硫或NRa基团中断，x = 0〜2，（B）交联-Si（OR'）3-x单元的催化剂，（C）有机溶剂或有机溶剂的混合物。 根据本发明，在涂层剂固化期间，反应性基团（I）以这种方式交联，在固化涂层的纳米压痕测试中注意到以下特征：弹性恢复体积> 86.5％ ; 塑性变形<3.5％; 脆性变形<10.0％。

公开(公告)号：US20110015340A1

公开(公告)日：2011-01-20

申请号：US12921769

申请日：2009-02-26

Applicant: Abdulmajid Hashemzadeh

Inventor： Abdulmajid Hashemzadeh

IPC: C08L83/04 ,  C08F283/01

CPC classification number: C09D143/04 ,  C08J3/14 ,  C08J2383/04 ,  C08K5/54 ,  C08L83/04 ,  C08L83/06 ,  C08L83/08 ,  C08L2666/04 ,  C09D5/033 ,  C09D7/65 ,  C09D183/04 ,  C09J143/04 ,  C14C11/003

Abstract: The object of the invention are methods for producing composite particles, characterized in that α) one or more silicon compounds of the general formula: (RO)nSiR14-n (1), wherein R denotes an optionally substituted alkyl or aryl residue having 1 to 20 carbon atoms or a hydrogen atom, R1 denotes an optionally substituted hydrocarbon residue or a hydrogen atom, and n assumes a value of 1 to 4, or β) one or more condensation products of the silicon compounds of formula (1) are condensed in the presence of one or more soluble polymers in a solvent or a mixture of multiple solvents, wherein said soluble polymers are obtainable by radically initiated polymerization of a) one or more ethylenic unsaturated monomers having one or more further functional group selected from the group comprising carboxyl groups or the derivatives thereof, silane, sulfonic acid, sulfate, phosphate, phosphonate, isocyanate, amine, quaternized amine, hydrazine, epoxy, ether, hydroxyl, or CO groups, and b) one or more ethylenic unsaturated monomers selected from the group comprising vinyl esters of carboxylic acids having 1 to 15 C atoms, methacryclic acid esters or acrylic acid esters of carboxylic acids with branched or unbranched alcohols having 1 to 15 C atoms, olefins and dienes, vinyl aromatics and vinyl halides, and wherein condensation products thus formed of said silicon compounds α) or condensation products β) or the condensation products thereof are fixed on one or more soluble polymers.

Abstract translation: 本发明的目的是制备复合颗粒的方法，其特征在于α）一种或多种通式为（RO）nSiR 14-n（1）的硅化合物，其中R表示任选取代的烷基或芳基，其具有1至 20个碳原子或氢原子，R1表示任选取代的烃残基或氢原子，n表示1〜4的值，或者＆lt; bgr）;式（1）的硅化合物的一种以上缩合产物被缩合 在一种或多种可溶性聚合物存在下的溶剂或多种溶剂的混合物中，其中所述可溶性聚合物可通过自动引发聚合得到a）一种或多种具有一个或多个另外的官能团的烯属不饱和单体，所述另外的官能团选自： 羧基或其衍生物，硅烷，磺酸，硫酸根，磷酸酯，膦酸酯，异氰酸酯，胺，季铵，肼，环氧，醚，羟基或CO基团，和b）一 或更多的选自包含具有1至15个碳原子的羧酸的乙烯基酯的乙烯类不饱和单体，羧酸的甲基丙烯酸酯或丙烯酸酯与具有1至15个碳原子的支链或非支链醇，烯烃和二烯，乙烯基芳族化合物 和乙烯基卤化物，并且其中由所述硅化合物α）或缩合产物（bgr））形成的缩合产物或其缩合产物固定在一种或多种可溶性聚合物上。

公开(公告)号：US20100310865A1

公开(公告)日：2010-12-09

申请号：US12810107

申请日：2008-12-16

Applicant: Ramesh C. Kumar ,  Taun L. McKenzie ,  Ying-Yuh Lu

Inventor： Ramesh C. Kumar ,  Taun L. McKenzie ,  Ying-Yuh Lu

IPC: C08F292/00 ,  C08G77/14 ,  B32B27/18

CPC classification number: C09D143/04 ,  B82Y30/00 ,  C08F2/38 ,  C08F283/122 ,  C08L83/08 ,  C09D151/085 ,  C09J7/401 ,  C09J151/085 ,  C09J2433/005 ,  C09J2483/005 ,  C08F230/08

Abstract: A copolymer comprises the reaction product of (a) (meth)acrylate functionalized nanoparticles, (b) vinyl monomer, and (c) mercapto-functional silicone. The (meth)acrylate functionalize nanoparticles are selected from the group consisting of silica nanoparticles, zirconia nanoparticles, titania nanoparticles, and combinations thereof.

Abstract translation: 共聚物包含（a）（甲基）丙烯酸酯官能化纳米颗粒，（b）乙烯基单体和（c）巯基官能化硅氧烷的反应产物。 （甲基）丙烯酸酯官能化纳米颗粒选自二氧化硅纳米颗粒，氧化锆纳米颗粒，二氧化钛纳米颗粒及其组合。