公开(公告)号：US07829150B2

公开(公告)日：2010-11-09

申请号：US11155453

申请日：2005-06-17

Applicant: James R. Engstrom ,  Aravind S. Killampalli ,  Paul F. Ma

Inventor： James R. Engstrom ,  Aravind S. Killampalli ,  Paul F. Ma

IPC: B05D1/36 ,  B05D7/00 ,  C23C16/00

CPC classification number: H01L21/02172 ,  B05D1/185 ,  B05D1/60 ,  B82Y30/00 ,  B82Y40/00 ,  H01L21/02205 ,  H01L21/31604 ,  H01L51/56

Abstract: Systems and methods for preparing inorganic-organic interfaces using organo-transition metal complexes and self-assembled monolayers as organic surfaces. In one embodiment, a silicon wafer is cleaned and reacted with stabilized pirhana etch to provide an oxide surface. The surface is reacted with the trichlorosilyl end of alkyltrichlorosilanes to prepare self assembling monomers (SAMs). The alkyltrichlorosilanes have the general formula R1-R—SiCl3, where R1 is —OH, —NH2, —COOH, —SH, COOCH3, —CN, and R is a conjugated hydrocarbon, such as (CH2)n where n is in the range of 3 to 18. The functionalized end of the SAM can optionally modified chemically as appropriate, and is then reacted with metal-bearing species such as tetrakis(dimethylamido)titanium, Ti[N(CH3)2]4, (TDMAT) to provide a titanium nitride layer.

Abstract translation: 使用有机过渡金属络合物和自组装单层作为有机表面制备无机 - 有机界面的系统和方法。 在一个实施例中，清洁硅晶片并与稳定的pirhana蚀刻反应以提供氧化物表面。 表面与烷基三氯硅烷的三氯甲硅烷基末端反应以制备自组装单体（SAM）。 烷基三氯硅烷具有通式R 1 -R R 1 SiCl 3，其中R 1是-OH，-NH 2，-COOH，-SH，COOCH 3，-CN，R是共轭烃，如（CH 2）n，其中n是 SAM的官能化端可以任选地适当地化学修饰，然后与含金属的物质如四（二甲基氨基）钛，Ti [N（CH 3）2] 4，（TDMAT）与 提供氮化钛层。

公开(公告)号：US07829139B2

公开(公告)日：2010-11-09

申请号：US11886464

申请日：2006-02-24

Applicant: Mark Reeves ,  Jiajie Diao

Inventor： Mark Reeves ,  Jiajie Diao

IPC: B05D1/24 ,  B05D5/00 ,  B05D1/18

CPC classification number: B82Y30/00 ,  B05D1/18 ,  B05D1/185 ,  B05D2203/35 ,  B05D2401/32 ,  B82Y10/00 ,  B82Y15/00

Abstract: A new method of making self-assembled nanoparticle wires involves: (1) at about ambient temperature and at or near atmospheric pressure, immersing a hydrophilic solid substrate at a non-horizontal angle (e.g., vertically) into a suspension of nanoparticles in a solvent, the suspension having a negative meniscus, the immersion forming a solid-liquid-air interface at the meniscus of the suspension; (2) gradually exposing the immersed substrate to air by gradually removing (preferably evaporating) the suspension, thereby causing deposition of the nanoparticles at a first location on the substrate at the meniscus, thereby forming a first nanoparticle wire on the substrate; (3) after a first deposition time period, rapidly removing a portion of the suspension, thereby causing deposition to stop and then re-start at a second location on the substrate at the meniscus; (4) continuing to gradually expose the immersed substrate to air by gradually removing the suspension for a second deposition period, thereby forming a second nanoparticle wire on the substrate; and optionally (5) repeating steps (3) and (4) one or more times to form one or more successive nanoparticle wires on the substrate. The above method can also be used to form integrated nanoparticle wire arrays.

Abstract translation: 制造自组装纳米线的新方法包括：（1）在大约环境温度和大气压附近，将亲水性固体基质以非水平角度（例如垂直）浸入纳米颗粒在溶剂中的悬浮液中 ，悬浮液具有负弯液面，浸渍在悬浮液的弯液面处形成固 - 液 - 空 - 界面; （2）通过逐渐去除（优选蒸发）悬浮液，使浸没的基板逐渐暴露于空气中，从而使纳米颗粒沉积在基板上的弯液面处的第一位置处，从而在基板上形成第一纳米颗粒线; （3）在第一沉积时间段之后，迅速去除悬浮液的一部分，从而使沉积物停止，然后在弯月面处的基底上的第二位置重新开始; （4）通过在第二沉积期间逐渐除去悬浮液，继续将浸没的基板逐渐暴露于空气中，从而在基板上形成第二纳米线; 和（5）重复步骤（3）和（4）一次或多次以在基底上形成一个或多个连续的纳米粒子线。 上述方法也可用于形成集成纳米线阵列。

公开(公告)号：US07776403B2

公开(公告)日：2010-08-17

申请号：US10553109

申请日：2004-04-14

Applicant: Nobuo Kimura ,  Yoshitaka Fujita ,  Norifumi Nakamoto ,  Tomoya Hidaka

Inventor： Nobuo Kimura ,  Yoshitaka Fujita ,  Norifumi Nakamoto ,  Tomoya Hidaka

IPC: B05D1/00 ,  B05D1/02 ,  B05D1/18 ,  B05D1/28 ,  B05D7/24 ,  C08J7/06 ,  C03C17/30

CPC classification number: C09D5/00 ,  B05D1/185 ,  C03C17/30 ,  Y10T428/261 ,  Y10T428/31504

Abstract: An object of the present invention is to provide a method for producing an organic thin film, which enables rapid film formation, and enables a dense organic thin film with minimal impurities to be formed stably, and in a plurality of consecutive repetitions.The present invention provides a method for producing an organic thin film in which an organic thin film is formed on the surface of a substrate, including a step (A) of bringing the substrate into contact with an organic solvent solution containing a metal-based surfactant having at least one hydrolyzable group, and a catalyst capable of interacting with the metal-based surfactant, wherein the water content within the organic solvent solution is either set or maintained within a predetermined range.

Abstract translation: 本发明的目的在于提供一种能够快速成膜的有机薄膜的制造方法，能够稳定地形成具有最小杂质的致密有机薄膜，并且能够连续重复多次。 本发明提供一种有机薄膜的制造方法，其中在基材表面上形成有机薄膜，其包括使基板与含有金属类表面活性剂的有机溶剂溶液接触的工序（A） 具有至少一个可水解基团和能够与金属基表面活性剂相互作用的催化剂，其中有机溶剂溶液中的水含量被设定或保持在预定范围内。

公开(公告)号：US20100183861A1

公开(公告)日：2010-07-22

申请号：US12666971

申请日：2007-12-27

Applicant: Kazufumi Ogawa

Inventor： Kazufumi Ogawa

IPC: C09D5/33 ,  B32B5/16 ,  C09D7/12 ,  B32B5/02 ,  C09D1/00

CPC classification number: G02B1/18 ,  B05D1/185 ,  B05D5/083 ,  C03C12/02 ,  C03C17/30 ,  C03C2217/76 ,  C08K3/22 ,  C08K3/36 ,  C08K3/40 ,  C08K9/06 ,  C09D5/004 ,  C09D7/62 ,  C09D7/68 ,  C09D7/69 ,  G02B27/0006 ,  Y10T428/249924 ,  Y10T428/25 ,  Y10T428/251 ,  Y10T428/256 ,  Y10T428/2933 ,  Y10T428/2991

Abstract: The present invention relates to light-reflection coating composition, characterized in that transparent particles having surfaces covered with a water-repellent and oil-repellent coating film are dispersed in the coating composition. Furthermore, there is provided, using the coating composition, a water-repellent, oil-repellent, and soil-resistant light-reflection coat, wherein the transparent particles covered with a water-repellent, oil-repellent, and soil-resistant coating film.

Abstract translation: 本发明涉及光反射涂料组合物，其特征在于，将具有防水防油涂层的表面的透明颗粒分散在涂料组合物中。 此外，使用涂料组合物提供防水，防油，耐污光的光反射涂层，其中透明颗粒被防水，防油和防污涂层覆盖 。

公开(公告)号：US07759114B2

公开(公告)日：2010-07-20

申请号：US11327660

申请日：2006-01-06

Applicant: Lisandra Lorraine Martin ,  Daniel Luke Johnson

Inventor： Lisandra Lorraine Martin ,  Daniel Luke Johnson

IPC: C12M1/34 ,  G01N33/53 ,  G01N33/553 ,  G01N33/24

CPC classification number: B05D1/185 ,  B01J2219/00572 ,  B01J2219/00605 ,  B01J2219/0061 ,  B01J2219/00612 ,  B01J2219/00626 ,  B01J2219/00637 ,  B01J2219/00653 ,  B01J2219/00725 ,  B01J2219/00738 ,  B01J2219/00745 ,  B01J2219/0075 ,  B05D3/105 ,  B05D2202/40 ,  B82Y30/00 ,  B82Y40/00 ,  C40B40/10 ,  C40B40/18 ,  C40B70/00 ,  G01N33/54353 ,  Y10S514/836

Abstract: A method for selectively orienting molecules on a surface of a solid support. The method includes the steps of: (a) attaching a linker molecule to the surface of the solid support, the linker molecule including a head group that is capable of binding to the solid support, and a tail group that is capable of chelating to a metal ion; (b) subsequently treating the solid support with a solution containing the metal ion; (c) attaching a metal ion chelating tag to the molecules to form tagged molecules; and (d) capturing the tagged molecules on the solid support by contacting it with the tagged molecules to form a monolayer of molecules on the surface of the solid support in which a majority of the molecules are held in the same orientation with respect to the surface. The invention also provides a sensor chip formed using the methods of the invention.

Abstract translation: 用于选择性地定向固体支持物表面上的分子的方法。 该方法包括以下步骤：（a）将连接分子连接到固体支持物的表面，所述连接分子包括能够结合固体支持物的头基和能够螯合到固体支持物上的尾基 金属离子; （b）随后用含有金属离子的溶液处理固体载体; （c）将金属离子螯合标签附着在分子上以形成标记分子; 和（d）通过使其与标记的分子接触来捕获固体支持物上的标记分子，以在固体支持物的表面上形成单分子层，其中大部分分子相对于表面保持相同的取向 。 本发明还提供了使用本发明的方法形成的传感器芯片。

公开(公告)号：US07750174B2

公开(公告)日：2010-07-06

申请号：US11907501

申请日：2007-10-12

Applicant: Arthur W. Snow ,  Edward E. Foos

Inventor： Arthur W. Snow ,  Edward E. Foos

IPC: C07F7/18 ,  C07F7/16

CPC classification number: C07F7/1804 ,  B05D1/185 ,  B05D7/52 ,  B82Y30/00 ,  B82Y40/00 ,  C03C25/24 ,  C03C25/305 ,  C03C25/40

Abstract: The compound is a silane surface treatment agent and is useful for modifying the surfaces of silicon oxide and other metal oxides with hexafluorodimethyl carbinol functional groups. Additionally provided is a surface treatment procedure that effectively bonds it and other alkoxysilanes via homogeneous and heterogeneous amine catalysis onto metal oxide surfaces.

Abstract translation: 该化合物是硅烷表面处理剂，可用于用六氟二甲基甲醇官能团改性氧化硅和其它金属氧化物的表面。 另外提供了一种表面处理方法，其通过均相和非均相胺催化有效地将其和其它烷氧基硅烷键合到金属氧化物表面上。

公开(公告)号：US20100167067A1

公开(公告)日：2010-07-01

申请号：US12423778

申请日：2009-04-14

Applicant: Chi-Hsiang Hung

Inventor： Chi-Hsiang Hung

IPC: B32B9/04 ,  C08K3/22 ,  B29C71/04

CPC classification number: B05D5/083 ,  B05D1/185 ,  B05D7/52 ,  Y10T428/24372

Abstract: A coating structure includes a UV-cured resin layer and a fluoride monomolecular layer. Organosilicon groups of organosilicon molecules extend from the surface of the resin layer. Wax fine powder and oxide nanoparticles emerge from the surface of the resin layer to form mountain-valley-like microstructures. Fluoride molecules of the fluoride monomolecular layer are chemically bonded with the surface of the resin layer to expose the fluoride groups. During the formation of the coating structure, the UV-curable resin layer is first partially cured, then the fluoride molecules are activated to chemically bond to the surface of the resin layer, and thereafter, the UV-curable resin layer is completely cured.

Abstract translation: 涂层结构包括UV固化树脂层和氟化物单分子层。 有机硅分子的有机硅基团从树脂层的表面延伸。 蜡细粉末和氧化物纳米颗粒从树脂层的表面露出，形成山谷状微结构。 氟化物单分子层的氟化物分子与树脂层的表面化学键合以暴露氟化物基团。 在形成涂层结构时，首先将UV固化树脂层部分固化，然后激活氟化物分子以与树脂层的表面化学键合，然后使紫外线固化树脂层完全固化。

公开(公告)号：US07744963B2

公开(公告)日：2010-06-29

申请号：US11933181

申请日：2007-10-31

Applicant: Chad A. Mirkin ,  Seunghun Hong ,  Vinayak P. Dravid

Inventor： Chad A. Mirkin ,  Seunghun Hong ,  Vinayak P. Dravid

IPC: B05D1/28 ,  B05D3/14

CPC classification number: G03F7/0002 ,  B05D1/007 ,  B05D1/185 ,  B05D1/26 ,  B82B3/00 ,  G01Q80/00 ,  G03F7/165 ,  Y10S977/85 ,  Y10S977/857 ,  Y10S977/86 ,  Y10S977/862 ,  Y10S977/863 ,  Y10S977/878 ,  Y10S977/882 ,  Y10S977/884 ,  Y10S977/885 ,  Y10S977/886

Abstract: In one aspect, a method of nanolithography is provided, the method comprising providing a substrate; providing a scanning probe microscope tip; coating the tip with a deposition compound; and subjecting said coated tip to a driving force to deliver said deposition compound to said substrate so as to produce a desired pattern. Another aspect of the invention provides a tip for use in nanolithography having an internal cavity and an aperture restricting movement of a deposition compound from the tip to the substrate. The rate and extent of movement of the deposition compound through the aperture is controlled by a driving force.

Abstract translation: 一方面，提供一种纳米光刻方法，该方法包括提供基底; 提供扫描探针显微镜尖端; 用沉积化合物涂覆尖端; 并使所述涂覆的尖端经受驱动力以将所述沉积化合物输送到所述基底，以产生所需的图案。 本发明的另一方面提供了一种用于纳米光刻的尖端，其具有内腔和限制沉积化合物从尖端到基底的运动的孔。 沉积化合物通过孔的运动速度和程度由驱动力控制。

公开(公告)号：US20100124666A1

公开(公告)日：2010-05-20

申请号：US12292466

申请日：2008-11-19

Applicant: Mazen M. Khaled ,  Basel F. Abu-Sharkh

Inventor： Mazen M. Khaled ,  Basel F. Abu-Sharkh

IPC: B32B15/04 ,  B05D5/12

CPC classification number: B05D7/16 ,  B05D1/185 ,  B05D7/56 ,  C09D5/4488

Abstract: The method of applying a polyelectrolyte multilayer film for corrosion control involves chemical and/or electrochemical pretreatment of a metallic substrate for better adherence of the protective film to the substrate. The method includes anodically polarizing the substrate in a solution of an acid for a period from one second to five hundred seconds before multilayer deposition. The acid may be an inorganic acid, such as sulfuric acid, phosphoric acid, hydrochloric acid, nitric acid, etc., or an organic acid, such as oxalic acid, acetic acid, etc. The method may include abrading the substrate and rinsing the substrate with deionized water before polarizing the substrate, and applying the polyelectrolyte multilayers following pretreatment.

Abstract translation: 施加用于腐蚀控制的聚电解质多层膜的方法包括金属基底的化学和/或电化学预处理，以更好地粘附保护膜到基底。 该方法包括在多层沉积之前将基底在酸溶液中阳极极化一秒至五百秒的时间。 酸可以是无机酸，例如硫酸，磷酸，盐酸，硝酸等，或有机酸如草酸，乙酸等。该方法可以包括研磨底物并漂洗 在使底物偏振之前用去离子水进行底物，以及在预处理之后施加聚电解质多层。

公开(公告)号：US07717693B2

公开(公告)日：2010-05-18

申请号：US11597570

申请日：2005-05-27

Applicant: Matthias Keil ,  Göran Frennesson ,  Marc Beck ,  Babak Heidari

Inventor： Matthias Keil ,  Göran Frennesson ,  Marc Beck ,  Babak Heidari

IPC: B29C59/00 ,  B29C33/56 ,  B28B7/38

CPC classification number: B05D1/60 ,  B05D1/185 ,  B29C33/56 ,  B82Y10/00 ,  B82Y30/00 ,  B82Y40/00 ,  G03F7/0002 ,  G03F7/0017 ,  Y10T428/31678

Abstract: The invention relates to a novel metal mold having anti-adhesive properties comprising a base metal mold and an anti-adhesive layer comprising a fluorinated alkyl phosphoric acid derivative or a fluorinated alkyl poly-phosphoric acid derivative, including a phosphorous atom and an alkyl chain. The anti-adhesive layer is bonded directly onto a surface of the base metal mold. The base metal mold may be e.g. Nickel, and said fluorinated alkyl phosphoric acid derivative or said fluorinated alkyl poly-phosphoric acid derivative may be selected from the group consisting of phosphonic acids, phosphonic acids, phosphonates and phosphonate salts, phosphonates and phosphonate salts, or their respective oligomers, such that the phosphorous atom is coupled directly to the alkyl chain, such that the phosphorous atom is coupled directly to the alkyl chain.

Abstract translation: 本发明涉及一种具有抗粘性的新型金属模具，其特征在于包括贱金属模和包含磷原子和烷基链的氟化烷基磷酸衍生物或氟化烷基聚磷酸衍生物的防粘层。 抗粘剂层直接粘结在母模金属模的表面上。 贱金属模可以是例如。 镍和所述氟代烷基磷酸衍生物或所述氟化烷基聚磷酸衍生物可以选自膦酸，膦酸，膦酸盐和膦酸盐，膦酸盐和膦酸盐或它们各自的低聚物，使得 磷原子直接与烷基链结合，使得磷原子直接与烷基链结合。