PROCESS FOR PREPARING GUANIDINO-FUNCTIONAL MONOMERS
    81.
    发明申请
    PROCESS FOR PREPARING GUANIDINO-FUNCTIONAL MONOMERS 有权
    制备官能单体的方法

    公开(公告)号:US20160096802A1

    公开(公告)日:2016-04-07

    申请号:US14787930

    申请日:2014-06-12

    Abstract: A process for preparing guanidino-functional, free radically polymerizable compounds comprises (a) combining (1) an amine compound comprising (i) at least one primary aliphatic amino group and (ii) at least one secondary aliphatic amino group, primary aromatic amino group, or secondary aromatic amino group, and (2) a guanylating agent; (b) allowing or inducing reaction of the amine compound and the guanylating agent to form a guanylated amine compound; (c) combining (1) the guanylated amine compound, and (2) a reactive monomer comprising (i) at least one ethylenically unsaturated group and (ii) at least one group that is reactive with an amino group; and (d) allowing or inducing reaction of the guanylated amine compound and the reactive monomer to form a guanidino-functional, free radically polymerizable compound.

    Abstract translation: 制备胍基官能的可自由基聚合化合物的方法包括(a)将(1)胺化合物(i)至少包含一个伯脂肪族氨基和(ii)至少一个仲脂肪族氨基,伯芳族氨基 或仲芳族氨基,和(2)脒基化剂; (b)允许或诱导胺化合物和脒基化剂反应形成胍化胺化合物; (c)将(1)胍化胺化合物和(2)包含(i)至少一种烯属不饱和基团和(ii)至少一个与氨基反应的基团的反应性单体的组合; 和(d)允许或诱导胍化胺化合物和反应性单体的反应以形成胍基官能的可自由基聚合的化合物。

    ARTICLES CONTAINING A CROSSLINKED GUANIDINYL-CONTAINING POLYMER AND USES THEREOF

    公开(公告)号:US20220279791A1

    公开(公告)日:2022-09-08

    申请号:US17597488

    申请日:2020-07-23

    Abstract: An article, and method of use, wherein the article includes: a substrate; a cationic coating bound to the substrate, wherein the cationic coating includes a guanidinyl-containing polymer that is crosslinked on the substrate; wherein the guanidinyl-containing polymer is of the following Formula (I), wherein: R3 is a H, C1-C12(hetero)alkyl, C5-C12(hetero)aryl, or Polymer; each R4 is independently H, C1-C12(hetero)alkyl, or C5-C12(hetero)aryl; each R5 is H, C1-C12(hetero)alkyl, C5-C12(hetero)aryl, or N(R4)2; Polymer is a residue of an aminopolymer chain; m is 1 or 2; and x is an integer of at least 1; and wherein the guanidinyl-containing polymer is crosslinked with an amine-reactive polyepoxy compound having pendant —OH groups.

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