Abstract:
Compounds of the formula ##STR1## wherein R.sub.1 and R.sub.2 are independently lower alkyl or hydrogen, provided that only one of R.sub.1 and R.sub.2 is hydrogen,R.sub.3 is --(A).sub.q --COOR.sub.4 or CN whereA is alkylene of 1 to 6 carbon atoms,R.sub.4 is alkyl of 1 to 24 carbon atoms, phenyl or alkyl substituted phenyl,q is 0 or 1, and R.sub.11 is alkylene of 1 to 34 carbon atoms, arylene or a direct bond, are suitable for stabilizing organic material against thermal, oxidative and ultraviolet light degradation.
Abstract:
Phosphorylated alkylated phenol/phenol ester mixtures in which the weight ratio of the alkyl moiety to the phenol moiety ranges from 0.05 to about 0.65, and the number of carbon atoms per alkyl moiety ranges from 3 to 16, preferably from 3 to 12, which mixtures have satisfactory viscosity range and impart to polymeric materials and especially to polyvinylchloride plasticized therewith good light and heat stability: a process for producing such phosphorylated alkylated phenol/phenol ester mixtures; and polymeric materials plasticized therewith.
Abstract:
Gasoline compositions having improved driveability comprise gasoline containing a minor amount of a compound having the formula ##STR1## WHEREIN R.sub.f is a perfluorinated radical selected from the group consisting of aliphatic C.sub.n F.sub.2n + 1 and cycloaliphatic C.sub.n F.sub.2n - 1, n is an integer from 1 - 18, q is 0 or an integer from 1 to 18, R is hydrogen or an alkyl radical having from 1 to 12 carbon atoms, R.sub.1 is an alkylene bridging radical having from 2 to 12 carbon atoms, m is 1 or 2, and X is chlorine, hydroxyl, --OMe (where Me is a metal), or a residual moiety of an active hydrogen-containing organic compound.
Abstract:
Phosphorylated alkylated phenol/phenol ester mixtures in which the weight ratio of the alkyl moiety to the phenol moiety ranges from 0.05 to about 0.65, and the number of carbon atoms per alkyl moiety ranges from 3 to 16, preferably from 3 to 12, which mixtures have satisfactory viscosity range and impart to polymeric materials and especially to polyvinylchloride plasticized therewith good light and heat stability: a process for producing such phosphorylated alkylated phenol/phenol ester mixtures; and polymeric materials plasticized therewith.
Abstract:
Exhaust valve seat wear of automotive engines operated on unleaded gasoline can be catastrophic under severe operating conditions. This results in severe loss of engine power, marked reduction in fuel economy and sharp increases in exhaust emissions to intolerable levels. This problem may be ameliorated by utilizing high octane gasolines containing suitable quantities of phosphorus esters. Methods of preparing and dispensing the fuels are also described.
Abstract:
A COMPOUND SELECTED FROM THE GROUP CONSISTING OF
(R2)(3-B)-N-(R3-COO-P AND (R2)(3-B)-N-(R3-COO-P WHEREIN R IS INDEPENDENTLY SELECTED FROM THE GROUP CONSISTING OF HYDROGEN AND ALKYL, R2 IS INDEPENDENTLY SELECTED FROM THE GROUP CONSISTING OF ALKYL RADICALS OF 1 TO 12 CARBON ATOMS, AND ARYL RADICALS OF 6 TO 18 CARBONS ATOMS, R3 IS INDEPENDENTLY SELECTED FROM THE GROUP CONSISTING OF ALKYLENE OF 1 TO 4 CARBON ATOMS, A IS A CALCOGEN INDEPENDENTLY SELECTED FROM THE GROUP CONSISTING OF OXYGEN AND SULFUR, B IS 1 TO 3 AND N IS 0 TO 1. THE COMPOUNDS ARE PREPARED BY REACTING UNDERANHYDROUS CONDITIONS A PHOSPHOROHALIDITE WITH THE COMPOUND
(R2)(3-B)-N-(R3-COO-M)B
WHEREIN M IS SELECTED FROM THE GROUP CONSISTING OF AMMONIUM, ALKALI METAL AND ALKALINE EARTH METAL. THE COMPOUNDS ARE USEFUL AS CHEMICAL INTERMEDIATES, STABILIZERS, PLASTICIZERS, GASOLINE OR LUBRICATING OIL ADDITIVES, OR FLAME RETARDING ADDITIVES.
Abstract:
A method of reducing manganese containing deposits formed on the surfaces of jet engines from burning fuel containing organomanganese compounds as a smoke reducer is described. The deposits are reduced by adding an organic molybdenum compound to the organomanganese containing fuel. Cyclopentadienyl manganese tricarbonyl compounds are useful organomanganese compounds; molybdenum naphthenate is a useful molybdenum compound.
Abstract:
PHOSPHORYLATED ALKYLPHENOL/PHENOL ESTER MIXTURES IN WHICH THE WEIGHT RATIO OF THE ALKYL MOIETY TO THE PHENOL MOIETY RANGES FROM 0.005 TO ABOUT 0.65, AND THE NUMBER OF CARBON ATOMS PER ALKYL MOIETY RANGES FROM 3 TO 16, PREFERABLY FROM 3 TO 12, WHICH MIXTURES HAVE SATISFACTORY VISCOSITY RANGE AND IMPART TO POLYMERIC MATERIALS AND ESPECIALLY TO POLYVINYLCHLORIDE PLASTICIZED THEREWITH GOOD LIGHT AND HEAT STABILITY; A PROCESS FOR PRODUCING SUCH PHOSPHORYLATED ALKYLPHENOL/PHENOL ESTER MIXTURES; AND POLYMERIC MATERIALS PLASTICIZED THEREWITH.