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    Magnesium aluminate anion exchangers
    82.
    发明授权
    Magnesium aluminate anion exchangers 失效
    铝酸镁阴离子交换剂

    公开(公告)号：US4326961A

    公开(公告)日：1982-04-27

    申请号：US183907

    申请日：1980-09-04

    Applicant: John M. Lee ,  William C. Bauman

    Inventor： John M. Lee ,  William C. Bauman

    IPC: B01J41/08 ,  B01J47/00 ,  C01B25/45 ,  C01D3/14 ,  C01F7/00 ,  C01G37/14 ,  B01J41/02

    CPC classification number: C01B25/45 ,  B01J41/08 ,  B01J47/006 ,  C01D3/145 ,  C01F7/002 ,  C01G37/14 ,  C01P2002/22

    Abstract: Preparations and uses are shown for novel crystalline aluminates which conform generally to the empirical formulaMgA.sub.a.sup.V Z.sub.b.sup.v .multidot.nAl(OH).sub.3 .multidot.mH.sub.2 OwhereA and Z represent negative-valence ions or radicals selected from the group comprising hydroxyl, halide, inorganic acid, and organic acid,n is a value of from about 1 to about 2,v is a negative valence of 1, 2, or 3,a and b each have values of from zero to 2, with (va)+(vb) equal to 2, and with m being a value of zero or more.

    Abstract translation: 显示了新型结晶铝酸盐的制备和用途，其通常符合经验式MgAaVZbvxnAl（OH）3·xH2O，其中A和Z表示负价离子或选自羟基，卤化物，无机酸和有机酸的基团，n为 值为约1至约2，v为1,2或3的负数，a和b各自具有0至2的值，其中（va）+（vb）等于2，并且与m 值为零或以上。

    Strong anion exchange composition
    83.
    发明授权
    Strong anion exchange composition 失效
    强阴离子交换组成

    公开(公告)号：US4322542A

    公开(公告)日：1982-03-30

    申请号：US112964

    申请日：1980-01-17

    Applicant: Seth R. Abbott

    Inventor： Seth R. Abbott

    IPC: B01J20/281 ,  B01J20/32 ,  B01J41/08 ,  B01J41/10 ,  C07H19/10 ,  C07H19/20 ,  G01N30/88 ,  C07F7/10

    CPC classification number: B01J41/20 ,  B01J20/28004 ,  B01J20/28057 ,  B01J20/28083 ,  B01J20/286 ,  B01J20/3204 ,  B01J20/3217 ,  B01J20/3257 ,  B01J2220/54 ,  B01J2220/58

    Abstract: A strong anion exchange composition useful in monophosphate nucleotide isomer separations is comprised of an inert porous particle having a silyl alkyl ammonium compound fixedly attached by a covalent silicon-oxygen-silicon bond to the surface thereof. A process for synthesizing the strong anion exchange composition in an aqueous solvent is disclosed together with methods for separation of monophosphate nucleotide isomers, highly phosphorylated nucleotides and aldopentose carbohydrates using a column packed with this strong anion exchange composition.

    Abstract translation: 用于单磷酸核苷酸异构体分离的强阴离子交换组合物由具有通过共价硅 - 氧 - 硅键固定连接到其表面的甲硅烷基烷基铵化合物的惰性多孔颗粒组成。 公开了一种在水性溶剂中合成强阴离子交换组合物的方法以及使用填充有该强阴离子交换组合物的柱分离单磷酸核苷酸异构体，高度磷酸化的核苷酸和戊糖醛糖的方法。

    Recovery of Mg.sup.++ from brines
    85.
    发明授权
    Recovery of Mg.sup.++ from brines 失效
    回收Mg {hu {30 {30 {{{{{

    公开(公告)号：US4116857A

    公开(公告)日：1978-09-26

    申请号：US812542

    申请日：1977-07-05

    Applicant: John M. Lee ,  William C. Bauman

    Inventor： John M. Lee ,  William C. Bauman

    IPC: B01D15/04 ,  B01J41/08 ,  B01J47/00 ,  C01F7/00

    CPC classification number: B01J47/006 ,  B01J41/08 ,  C01F7/002

    Abstract: Magnesium values are selectively recovered from salt brines, even salt brines which contain competing ions such as Li.sup.+, Ca.sup.++, and Sr.sup.++, by contacting the brine with an anion exchange resin which has dispersed therein a microcrystalline structure of the formula MgX.sub.2.2Al(OH).sub.3, where X is a halide.

    Abstract translation: 通过使盐水与分散有式MgX2.2Al（OH）的微晶结构的阴离子交换树脂接触，从盐盐水，甚至含有竞争离子的盐盐，即Li +，Ca ++和Sr ++的盐水中选择性地回收镁值， 3，其中X是卤化物。

    High performance ion exchange composition
    86.
    发明授权
    High performance ion exchange composition 失效
    高效离子交换组成

    公开(公告)号：US4101460A

    公开(公告)日：1978-07-18

    申请号：US593345

    申请日：1975-07-07

    Applicant: Hamish Small ,  Timothy S. Stevens

    Inventor： Hamish Small ,  Timothy S. Stevens

    IPC: B08B3/12 ,  B01D15/04 ,  B01D15/36 ,  B01J20/281 ,  B01J20/285 ,  B01J39/16 ,  B01J41/08 ,  B01J47/00 ,  C08J7/04 ,  G01N30/88 ,  C08J5/20

    CPC classification number: B01D15/361 ,  B01J20/3221 ,  B01J47/006 ,  C08J7/04

    Abstract: An ion exchange composition comprising an insoluble substrate of a synthetic resin having ion exchanging sites at least on its available surface; and a finely divided, insoluble material comprising synthetic resin particles of from about 0.1 to about 5 microns median diameter (with respect to volume) having, at least on their outer surfaces, ion exchanging sites which attract the ion exchanging sites of the substrate, irreversibly attached as a monolayer to the available surface of the substrate. The composition is used for removal and separation of ions, and is especially useful in liquid ion exchange chromatography. For example, a chromatographic separation of halide ions is effected with high speed and resolution by contacting an aqueous solution thereof with a bed of the ion exchange composition which consists of surface sulfonated resin beads of a styrene-divinylbenzene copolymer to the surface of which is irreversibly attached a monolayer of quaternary ammonium-bearing styrene-divinylbenzene copolymer resin particles in the hydroxy form, and then eluting the bed with an aqueous sodium hydroxide solution.

    Abstract translation: 一种离子交换组合物，其包含至少在其可用表面上具有离子交换位点的合成树脂的不溶性底物; 和细碎的不溶性材料，其包含约0.1至约5微米中等直径（相对于体积）的合成树脂颗粒，其至少在其外表面上具有吸引衬底的离子交换位点的离子交换位点，不可逆地 作为单层附着到基材的可用表面。 该组合物用于离子的去除和分离，并且在液体离子交换色谱中特别有用。 例如，通过使其水溶液与由苯乙烯 - 二乙烯基苯共聚物的表面磺化树脂珠组成的离子交换组合物的床接触，使其卤化物离子的色谱分离以高速和分辨率进行，其表面不可逆地 将含有羟基的季铵含量苯乙烯 - 二乙烯基苯共聚物树脂颗粒单层，然后用氢氧化钠水溶液洗脱床。

    Process for the production of silicon dioxide ion exchangers
    87.
    发明授权
    Process for the production of silicon dioxide ion exchangers 失效
    生产二氧化硅离子交换剂的方法

    公开(公告)号：US3936388A

    公开(公告)日：1976-02-03

    申请号：US364116

    申请日：1973-05-25

    Applicant: Klaus Unger ,  Karlheinz Berg

    Inventor： Klaus Unger ,  Karlheinz Berg

    IPC: B01J39/16 ,  B01J39/17 ,  B01J41/08 ,  B01J41/09 ,  B01J21/08 ,  B01J37/02

    CPC classification number: B01J41/085 ,  B01J39/165 ,  Y10T428/2993

    Abstract: An improved process for the production of silicon dioxide ion exchangers, which comprises the step of reacting silicon dioxide with benzyltrichlorosilane, in the absence of solvent and air, followed by hydrolysis, to produce a benzylated silicon dioxide whose benzyl groups can then be substituted with ion exchange reactive groups in a conventional manner.

    Abstract translation: 一种用于生产二氧化硅离子交换剂的改进方法，其包括在不存在溶剂和空气的情况下使二氧化硅与苄基三氯硅烷反应，然后水解的步骤，以产生苄基化的二氧化硅，其苄基可以被离子 以常规方式交换反应性基团。

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