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公开(公告)号：US09890342B2
公开(公告)日：2018-02-13
申请号：US14580450
申请日：2014-12-23
Applicant: Jochen Lauterbach , Jason R. Hattrick-Simpers , Cun Wen
Inventor： Jochen Lauterbach , Jason R. Hattrick-Simpers , Cun Wen
CPC classification number: C10L1/06 , B01J29/043 , C10G3/47 , C10G3/49 , C10L1/04 , C10L2270/02 , C10L2290/54 , Y02P30/20
Abstract: Methods for deriving a high-C hydrocarbon fuel from an organic source feedstock are provided. The method can include: contacting a mixture of the organic source feedstock and an aldehyde with a catalytic material to produce a product stream comprising a high-C hydrocarbon fuel, and separating the high-C hydrocarbon fuel in the product stream from any remaining organic source feedstock or aldehyde. The catalytic material comprises a metal and a zeolite.
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Patent Agency Ranking
2.发明授权公开(公告)号：US09169167B2
公开(公告)日：2015-10-27
申请号：US14252169
申请日：2014-04-14
Applicant: Jochen A. Lauterbach , Jason R. Hattrick-Simpers , Cun Wen
Inventor： Jochen A. Lauterbach , Jason R. Hattrick-Simpers , Cun Wen
CPC classification number: C07C1/045 , B01J21/00 , B01J23/005 , B01J23/75 , B01J35/0013 , B01J35/002 , B01J35/023 , B01J35/026 , B01J37/031 , B01J37/18 , C10G2/332
Abstract: A self-healing reaction process for a chemical reaction is provided by exposing a catalyst a reaction mixture that includes carbon monoxide and hydrogen gas such that hydrocarbons are produced. The catalyst includes Co3O4 nanorods having both Co2+ and Co3+ exposed thereon. The Co3O4 nanorods can have a spinel crystal structure such that the Co3O4 nanorods define a {110} facet having both Co2+ and Co3+ exposed thereon. During reaction conditions, water can oxidize portions of the catalyst, while the exposed Co3+ can reduce any oxidized portions of the catalyst such that the catalyst is self-healing during reaction conditions, especially when the reaction mixture further comprises water.
Abstract translation: 通过使催化剂暴露出包括一氧化碳和氢气的反应混合物以产生烃，从而提供化学反应的自愈反应过程。 该催化剂包括其上露出Co2 +和Co3 +的Co3O4纳米棒。 Co 3 O 4纳米棒可以具有尖晶石晶体结构，使得Co 3 O 4纳米棒限定了其上露出Co2 +和Co3 +的{110}面。 在反应条件下，水可以氧化催化剂的一部分，而暴露的Co 3+可以减少催化剂的任何氧化部分，使得催化剂在反应条件下自愈，特别是当反应混合物还包含水时。
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3.发明申请One-Step Synthesis of Monodisperse Transition Metal Core-Shell Nanoparticles with Solid Solution Shells 有权一步合成具有固溶体壳的单分散过渡金属核壳纳米颗粒公开(公告)号：US20130288892A1
公开(公告)日：2013-10-31
申请号：US13855349
申请日：2013-04-02
Applicant: Jochen A. Lauterbach , Jason R. Hattrick-Simpers , Cun Wen
Inventor： Jochen A. Lauterbach , Jason R. Hattrick-Simpers , Cun Wen
CPC classification number: B01J23/864 , B01J13/02 , B01J23/75 , B01J23/755 , B01J35/002 , B01J35/006 , B01J35/008 , B01J37/08 , B22F9/26 , B82Y40/00
Abstract: Methods of forming monodispersed core-shell nanoparticles are provided. A cobalt(II)-ligand component, a metal(II)-ligand component, an organic reducing agent, and a capping agent can be added to an organic solvent to form a reaction mixture. The reaction mixture is then heated to a dissolving temperature while under a gas (e.g., including methane) such that the reaction mixture becomes a reaction solution while stirring at the dissolving temperature. The reaction solution is then be heated to a reaction temperature (e.g., about 200° C. or more) while under the gas to form the core-shell nanoparticles, and the core-shell nanoparticles can be collected from the reaction solution.
Abstract translation: 提供了形成单分散核 - 壳纳米粒子的方法。 可以将钴（II）配位成分，金属（II）配位成分，有机还原剂和封端剂加入到有机溶剂中以形成反应混合物。 然后将反应混合物在气体（例如包括甲烷）下加热至溶解温度，使得反应混合物在溶解温度下搅拌的同时变成反应溶液。 然后将反应溶液加热至反应温度（例如约200℃或更高），同时在气体下形成核 - 壳纳米颗粒，并且可以从反应溶液中收集核 - 壳纳米颗粒。
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4.发明申请Self-Healing Catalysts: CO3O4 Nanorods for Fischer-Tropsch Synthesis 有权自愈合催化剂：用于费 - 托合成的CO 3 O 4纳米棒公开(公告)号：US20140309316A1
公开(公告)日：2014-10-16
申请号：US14252169
申请日：2014-04-14
Applicant: Jochen A. Lauterbach , Jason R. Hattrick-Simpers , Cun Wen
Inventor： Jochen A. Lauterbach , Jason R. Hattrick-Simpers , Cun Wen
IPC: C07C1/04
CPC classification number: C07C1/045 , B01J21/00 , B01J23/005 , B01J23/75 , B01J35/0013 , B01J35/002 , B01J35/023 , B01J35/026 , B01J37/031 , B01J37/18 , C10G2/332
Abstract: A self-healing reaction process for a chemical reaction is provided by exposing a catalyst a reaction mixture that includes carbon monoxide and hydrogen gas such that hydrocarbons are produced. The catalyst includes Co3O4 nanorods having both Co2+ and Co3+ exposed thereon. The Co3O4 nanorods can have a spinel crystal structure such that the Co3O4 nanorods define a {110} facet having both Co2+ and Co3+ exposed thereon. During reaction conditions, water can oxidize portions of the catalyst, while the exposed Co3+ can reduce any oxidized portions of the catalyst such that the catalyst is self-healing during reaction conditions, especially when the reaction mixture further comprises water.
Abstract translation: 通过使催化剂暴露出包括一氧化碳和氢气的反应混合物以产生烃，从而提供化学反应的自愈反应过程。 该催化剂包括其上露出Co2 +和Co3 +的Co3O4纳米棒。 Co 3 O 4纳米棒可以具有尖晶石晶体结构，使得Co 3 O 4纳米棒限定了其上露出Co2 +和Co3 +的{110}面。 在反应条件下，水可以氧化催化剂的一部分，而暴露的Co 3+可以减少催化剂的任何氧化部分，使得催化剂在反应条件下自愈，特别是当反应混合物还包含水时。
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5.发明授权One-step synthesis of monodisperse transition metal core-shell nanoparticles with solid solution shells 有权一步合成具有固溶体壳的单分散过渡金属核 - 壳纳米粒子公开(公告)号：US09205410B2
公开(公告)日：2015-12-08
申请号：US13855349
申请日：2013-04-02
Applicant: Jochen A. Lauterbach , Jason R. Hattrick-Simpers , Cun Wen
Inventor： Jochen A. Lauterbach , Jason R. Hattrick-Simpers , Cun Wen
CPC classification number: B01J23/864 , B01J13/02 , B01J23/75 , B01J23/755 , B01J35/002 , B01J35/006 , B01J35/008 , B01J37/08 , B22F9/26 , B82Y40/00
Abstract: Methods of forming monodispersed core-shell nanoparticles are provided. A cobalt(II)-ligand component, a metal(II)-ligand component, an organic reducing agent, and a capping agent can be added to an organic solvent to form a reaction mixture. The reaction mixture is then heated to a dissolving temperature while under a gas (e.g., including methane) such that the reaction mixture becomes a reaction solution while stirring at the dissolving temperature. The reaction solution is then be heated to a reaction temperature (e.g., about 200° C. or more) while under the gas to form the core-shell nanoparticles, and the core-shell nanoparticles can be collected from the reaction solution.
Abstract translation: 提供了形成单分散核 - 壳纳米粒子的方法。 可以将钴（II）配位成分，金属（II）配位成分，有机还原剂和封端剂加入到有机溶剂中以形成反应混合物。 然后将反应混合物在气体（例如包括甲烷）下加热至溶解温度，使得反应混合物在溶解温度下搅拌的同时变成反应溶液。 然后将反应溶液加热至反应温度（例如约200℃或更高），同时在气体下形成核 - 壳纳米颗粒，并且可以从反应溶液中收集核 - 壳纳米颗粒。
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6.发明申请One-Step Production of Long-Chain Hydrocarbons from Waste-Biomass-Derived Chemicals 有权从废物生物质衍生化学品一步生产长链烃公开(公告)号：US20150175497A1
公开(公告)日：2015-06-25
申请号：US14580450
申请日：2014-12-23
Applicant: Jochen Lauterbach , Jason R. Hattrick-Simpers , Cun Wen
Inventor： Jochen Lauterbach , Jason R. Hattrick-Simpers , Cun Wen
CPC classification number: C10L1/06 , B01J29/043 , C10G3/47 , C10G3/49 , C10L1/04 , C10L2270/02 , C10L2290/54 , Y02P30/20
Abstract: Methods for deriving a high-C hydrocarbon fuel from an organic source feedstock are provided. The method can include: contacting a mixture of the organic source feedstock and an aldehyde with a catalytic material to produce a product stream comprising a high-C hydrocarbon fuel, and separating the high-C hydrocarbon fuel in the product stream from any remaining organic source feedstock or aldehyde. The catalytic material comprises a metal and a zeolite.
Abstract translation: 提供了从有机源原料得到高C烃燃料的方法。 该方法可以包括：将有机源原料和醛的混合物与催化材料接触以产生包含高C烃燃料的产物流，并将产物流中的高C烃燃料与任何剩余的有机源分离 原料或醛。 催化材料包括金属和沸石。
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