Abstract:
The present invention relates to optical elements comprising fluorochemical surface treatments. The invention further relates to articles such as retroreflective sheetings, pavement markings and beaded projection screens comprising a binder and the surface treated optical elements. The surface treatment comprises at least one fluoropolymer selected from a) fluoropolymers comprising a fluorinated hydrocarbon backbone and side chains comprising at least one of fluoroalkyl, fluoroether alkyl, fluoroalkoxy and mixtures thereof; and b) fluoropolymers comprising a hydrocarbon backbone and side chains comprising at least one of fluoroether alkyl, fluoroalkoxy and mixtures thereof.
Abstract:
Methods of applying adhesive to a surface of a substrate comprise: digitally applying a fixable fluid material to a portion of the substrate surface, fixing the first fluid material to form a fixed coating in contact with the substrate surface, wherein the fixed coating has at least one boundary that encloses a region of the substrate surface within the at least one boundary, and applying a second fluid material comprising at least one of an adhesive and an adhesive precursor to at least a portion of the enclosed region of the substrate surface. Various products, including laminated products, may be prepared according to such methods.
Abstract:
A process for modifying the surface of a polymeric substrate. The process includes digitally applying a photoreactive material comprising at least one photochemical electron donor to a region of a polymeric substrate and exposing at least a portion of that region to actinic radiation. The modified surface of the polymeric substrate may be bonded to one or more additional substrates, or may be coated with a fluid.
Abstract:
The invention provides an article comprising a first layer comprising a first substantially solid partially-fluorinated thermoplastic polymer, and a second layer comprising a second substantially solid partially-fluorinated thermoplastic polymer, the second layer bonded to the first layer, wherein the first polymer and the second polymer have different compositions. The invention also provides layered articles and processes for preparing layered articles.
Abstract:
This invention concerns a process for modifying a polymeric substrate by contacting the surface with a photoreactive solution of an inorganic photochemical electron donor while irradiating the surface with actinic radiation. Patterns of modified and unmodified surfaces can be produced. Polymeric substrates with modified surfaces may be effectively bonded to polymer films to form composite articles. The process has particular applicability to the surface modification of fluorinated polymers.
Abstract:
In one aspect, the invention provides curable fluoropolymer compositions comprising fluoropolymer, onium, and alkyl or aryl oxalate-blocked compound and carbonate-blocked compound as crosslinking agents. In other aspects, the invention provides methods of making curable fluoropolymer compositions and provides alkyl or aryl oxalate-blocked and carbonate-blocked compounds.
Abstract:
A method of modifying a surface of a substrate comprises: inkjet printing a fluoropolymer solution comprising vaporizable solvent and a non-vaporizable component comprising a dissolved solid fluoropolymer. The dissolved solid fluoropolymer comprises a reaction product of at least one monomer comprising vinylidene fluoride. Various articles may be produced according to the method.
Abstract:
The invention relates to compositions useful for bonding fluoropolymer to substantially non-fluorinated polymer. The compositions of the invention comprise a substantially non-fluorinated polymer or a mixture of said polymers, a base, and a crown ether catalyst. Another aspect of the invention is an article comprising the above composition adhered to a fluoropolymer and methods of making said article.
Abstract:
A multi-layer structure includes a fluoropolymer bonded to a substrate. The structure is prepared by heating a bonding composition to form the bond. The bonding composition includes an amino-substituted organosilane. The bonding composition includes non-adhesive materials.
Abstract:
The present-invention relates to optical elements comprising fluorochemical surface treatments. The invention further relates to materials such as retroreflective sheetings, pavement markings and beaded projection screens comprising a binder and the surface treated optical elements.