Abstract:
IODINATION WITH IODINE AND CHLORINE IN A REACTION MIXTURE BUFFERED TO A WEAKLY ACIDIC PH PRODUCES A SUPERIOR CONVERSION BASED ON BOTH THE IODINE AND THE IODINATED COMPOUND PREPARATION OF IODOMETHYLSULFONES FROM SUBSTITUTED SULFONYL ACETIC ACIDS IS ILLUSTRATED.
Abstract:
WHERE R, R2, R3 and R5 are selected from the group consisting of C2-C20 alkyl, hydrogen, halo, cycloalkyl, aryl, substituted aryl, and haloalkyl; and R1 and R4 are selected from the group consisting of hydrogen lower-alkyl, aryl, haloalkyl, halothioalkyl, arylthio, alkylthio, substituted arylthio, hydroxyalkyl, hydroxyhaloalkyl, alkylcarbamoyl, dialkylcarbamoyl, aryl substituted carbamoyl, substituted diarylcarbamoyl, alkylarylcarbamoyl, alkylsulfonyl, haloalkylsulfonyl, arylsulfonyl, substituted arylsulfonyl, formyl, carboalkoxy, carboalkoxy, pyranyl, thiocarbamoyl, halocarboalkoxy, aroyl, substituted aroyl, aryloxyaceto, substituted aryloxyaceto, arylthioaceto, substituted arylthioaceto, benzyl substituted benzyl, phenacetyl, substituted phenacetyl, phosphonoalkyl, thiophosphonoalkyl, and acetylanilide with the proviso that when R5 is chloro and R3 is hydrogen, the nitrogen in the one position is substituted.
WHERE R, R2, R3 and R5 are selected from the group consisting of alkyl, hydrogen, halo, cycloalkyl, aryl, substituted aryl and haloalkyl; and R1 and R4 are selected from the group consisting of hydrogen, loweralkyl, aryl, substituted aryl, haloalkyl, halothioalkyl, arylthio, alkylthio, substituted arylthio, hydroxyalkyl, hydroxyhaloalkyl, alkylcarbamoyl, dialkylcarbamoyl, aryl substituted carbamoyl, substituted diarylcarbamoyl, alkylarylcarbamoyl, alkylsulfonyl, haloalkylsulfonyl, arylsulfonyl, substituted arylsulfonyl, formyl, carboalkoxy, carboaryloxy, pyranyl, thiocarbamoyl, halocarboalkoxy, aroyl, substituted aroyl, aryloxyaceto, substituted aryloxyaceto, arylthioaceto, substituted arylthioaceto, benzyl, substituted benzyl, phenacetyl, substituted phenacetyl, phosphonoalkyl, thiophosphonoalkyl, acetylanilide and metallic salts of any of the foregoing R1 and R4 groups, in an agronomically acceptable carrier. Also covers certain 4-nitropyrazoles having a formula selected from the group consisting of:
Covers a method of inducing abscission of fruit by applying a chemical composition containing an effective amount of a 4nitropyrazole as the active ingredient in an agronomically acceptable carrier. Said composition comprises in addition to said carrier an effective amount of a compound having a formula selected from the group consisting of:
Abstract:
An improved process for iodinating aminophenyl sulfonyl acetic acids to provide amino phenyl iodomethyl sulfones. The process comprises iodinating the acid with iodine and chlorine in a weakly acidic medium.
where R1 includes halophenyl, loweralkyl, phenyl, nitrophenyl, dinitrophenyl, nitrofuryl, and nitrothienyl; R2 includes hydrogen and loweralkyl; and Nhet includes a heterocyclic moiety bonded through a nitrogen thereof which is sufficiently basic to form quaternary ammonium salts.
Abstract:
COMPOUNDS COMPRISING DISUBSTITUTED ACYL AMIDE OXIMES WITH ONE OF THE SUBSTITUENTS BEING 5-NITRO-2-FURYL. THESE COMPOUNDS ARE USEFUL AS ANTIBACTERIAL AND ANTIFUNGAL AGENTS.
Abstract:
COMPOUNDS COMPRISING 3,5-DISUBSTITUTED-1,2,4-OXADIAZOLES WITH ONE OF THE SUBSTITUENTS BEING 5-NITRO-2-FURYL. THE COMPOUNDS ARE USEFUL AS ANTIBACTERIAL, ANTHELMINTIC, AND ANTI-TRICHOMONAS AGENTS.
Abstract:
WHEREIN N IS AN INTEGER FROM ZERO TO FOUR AND R IS SELECTED FROM THE GROUP CONSISTING OF ALKYL, CYCLOALKYL, T-BUTYLPHENYL, LOWERALKOXYPHENYL, NAPHTHYL, NITROPHENYL, HALONITROPHENYL, NITROLOWERALKYLPHENYL, POLYLOWERALKYLPHENYL, HALOLOWERALKYLPHENYL, OR HALOPHENYL. THE COMPOUNDS ARE USEFUL AS FUNGICIDES.