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公开(公告)号:US09995681B2
公开(公告)日:2018-06-12
申请号:US14808041
申请日:2015-07-24
Applicant: Authentix, Inc.
Inventor: Jeffrey L. Conroy , Philip B. Forshee , Paul J. Cronin , Olusola Soyemi
CPC classification number: G01N21/643 , G01N33/2882 , G01N2021/6439
Abstract: Device and methods for detecting/quantifying a fluorescent taggant in a liquid sample. Generally, the liquid samples are fuels having low concentrations (measured in ppb) of a fluorescent taggant. The detection/quantification generates a predicted concentration of the fluorescent tagging compound using a process selected from the group of a multivariate process, a background subtraction process, or a combination of both. The invention addresses the detection of an adulteration of gasoline and diesel fuels.
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公开(公告)号:US09366661B1
公开(公告)日:2016-06-14
申请号:US14806404
申请日:2015-07-22
Applicant: Authentix, Inc.
Inventor: Jeffrey L. Conroy , Philip B. Forshee , John-Christopher Boyer
IPC: G01N33/22 , C07C323/20 , C07C43/263 , G01N24/08 , G01N30/72 , G01N30/02
CPC classification number: C10L1/2406 , C07B2200/05 , C07C43/2055 , C07C43/21 , C07C43/263 , C07C43/275 , C07C321/30 , C07C323/20 , C07C2601/14 , C07C2601/16 , C10L1/003 , C10L1/1608 , C10L1/1852 , C10L1/2412 , C10L10/00 , C10L2200/0263 , C10L2200/0446 , C10L2230/16 , G01N21/65 , G01N24/08 , G01N30/7206 , G01N33/22 , G01N2030/025
Abstract: A method of determining adulteration of a fuel including subjecting to an analytical technique a marked fuel mixture comprising (a) a fuel; (b) a compound characterized by Formula I: wherein X is carbon, oxygen, or sulfur; when X is O or S, R1 and R2 are lone non-bonding electron pairs; when X is C, R1 and R2 each independently are hydrogen, C1 to C20 alkyl, or C6 to C10 aryl; R3 and R3′ each independently are hydrogen or C1 to C4 alkyl; R4 and R4′ each independently are hydrogen, C1 to C4 alkyl, C4 to C10 cycloalkyl, or C6 to C10 aryl; R5 and R5′ each independently are C4 to C10 alkyl; R6 and R6′ each independently are hydrogen or C1 to C6 alkyl; and R7 and R7′ each independently are hydrogen or C1 to C4 alkyl; and (c) a heavy compound, wherein the heavy compound comprises a compound of Formula I having at least one atom replaced with an isotope tag.
Abstract translation: 一种确定燃料掺假的方法,包括对分析技术进行标记的燃料混合物,其包括(a)燃料; (b)由式I表征的化合物:其中X是碳,氧或硫; 当X为O或S时,R 1和R 2为单键非键电子对; 当X为C时,R 1和R 2各自独立地为氢,C 1至C 20烷基或C 6至C 10芳基; R 3和R 3'各自独立地为氢或C 1至C 4烷基; R 4和R 4'各自独立地为氢,C 1至C 4烷基,C 4至C 10环烷基或C 6至C 10芳基; R5和R5'各自独立地为C4至C10烷基; R6和R6'各自独立地为氢或C1-C6烷基; 并且R 7和R 7'各自独立地为氢或C 1至C 4烷基; 和(c)重质化合物,其中重质化合物包含具有至少一个原子被同位素标记替换的式I化合物。
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公开(公告)号:US09631152B2
公开(公告)日:2017-04-25
申请号:US14806389
申请日:2015-07-22
Applicant: Authentix, Inc.
Inventor: Jeffrey L. Conroy , Philip B. Forshee , John-Christopher Boyer
IPC: C10L1/24 , G01N33/22 , C07C323/20 , C07C43/263 , G01N30/72 , C07C43/205 , C07C43/21 , C07C43/275 , C07C321/30 , C10L1/185 , C10L10/00 , G01N21/65 , G01N24/08 , G01N30/02
CPC classification number: C10L1/2406 , C07B2200/05 , C07C43/2055 , C07C43/21 , C07C43/263 , C07C43/275 , C07C321/30 , C07C323/20 , C07C2601/14 , C07C2601/16 , C10L1/003 , C10L1/1608 , C10L1/1852 , C10L1/2412 , C10L10/00 , C10L2200/0263 , C10L2200/0446 , C10L2230/16 , G01N21/65 , G01N24/08 , G01N30/7206 , G01N33/22 , G01N2030/025
Abstract: A method of forming a composition comprising contacting a fuel and at least one compound of Formula I: wherein X is carbon, oxygen, or sulfur; R1 and R2 each independently are hydrogen, a C1 to C20 alkyl, or a C6 to C10 aryl; R3 and R3′ each independently are hydrogen or a C1 to C4 alkyl; R4 and R4′ each independently are hydrogen, a C1 to C4 alkyl, a C4 to C10 cycloalkyl, or a C6 to C10 aryl; R5 and R5′ each independently are a C4 to C10 alkyl; R6 and R6′ each independently are hydrogen or a C1 to C6 alkyl; and R7 and R7′ each independently are hydrogen or C1 to C4 alkyl; and wherein the compound of Formula I when subjected to GC-MS using electron ionization at greater than 70 eV produces at least one ion having a mass-to-charge ratio of 300 to 600.
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公开(公告)号:US09448171B2
公开(公告)日:2016-09-20
申请号:US14728684
申请日:2015-06-02
Applicant: Authentix, Inc.
Inventor: Mohamed Lazzouni , Paul A. Carr , Olusola O. Soyemi , Jeffrey L. Conroy
CPC classification number: G01N21/6408 , G01N21/6428 , G01N21/6458 , G01N2021/6439 , G01N2201/0221 , G07D7/003 , G07D7/0054
Abstract: At least two luminescent materials are intermingled within a security feature. The materials are selected from among a larger set of luminescent materials each having a different individual exponential decay characteristic (decay constant and initial amplitude response to the degree of excitation) for photo-luminescent emission from the respective material following excitation. The ratio of the decay constants for any two materials is greater than or equal to about 1.5. The selected materials are mixed in one of a plurality of predetermined ratios. The combined emissions from the intermingled materials appear, to an unsophisticated measuring device, to have a single exponential decay constant. Based on measurements for the decay of the combined emissions following excitation, estimates of the individual decay constants and associated initial emission amplitudes allow decoding of the particular combination of materials and/or their ratios to validate the security feature, authenticating the article.
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公开(公告)号:US09732296B2
公开(公告)日:2017-08-15
申请号:US14806381
申请日:2015-07-22
Applicant: Authentix, Inc.
Inventor: Jeffrey L. Conroy , Philip B. Forshee , John-Christopher Boyer
IPC: C10L1/24 , C07C43/205 , C07C323/20 , C10L1/185 , C07C43/275 , G01N33/22 , C07C43/263 , G01N30/72 , C07C43/21 , C07C321/30 , C10L10/00 , G01N21/65 , G01N24/08 , G01N30/02
CPC classification number: C10L1/2406 , C07B2200/05 , C07C43/2055 , C07C43/21 , C07C43/263 , C07C43/275 , C07C321/30 , C07C323/20 , C07C2601/14 , C07C2601/16 , C10L1/003 , C10L1/1608 , C10L1/1852 , C10L1/2412 , C10L10/00 , C10L2200/0263 , C10L2200/0446 , C10L2230/16 , G01N21/65 , G01N24/08 , G01N30/7206 , G01N33/22 , G01N2030/025
Abstract: A composition comprising a fuel and at least one compound characterized by Formula I: wherein X is carbon, oxygen, or sulfur; R1 and R2 each independently are hydrogen, a C1 to C20 alkyl, or a C6 to C10 aryl; R3 and R3′ each independently are hydrogen or a C1 to C4 alkyl; R4 and R4′ each independently are hydrogen, a C1 to C4 alkyl, a C4 to C10 cycloalkyl, or a C6 to C10 aryl; R5 and R5′ each independently are a C4 to C10 alkyl; R6 and R6′ each independently are hydrogen or a C1 to C6 alkyl; and R7 and R7′ each independently are hydrogen or a C1 to C4 alkyl; and wherein the compound of Formula I when subjected to GC-MS using electron ionization at greater than about 70 eV produces at least one ion having a mass-to-charge ratio of from 300 to 600.
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公开(公告)号:US20150260653A1
公开(公告)日:2015-09-17
申请号:US14728684
申请日:2015-06-02
Applicant: Authentix, Inc.
Inventor: Mohamed Lazzouni , Paul A. Carr , Olusola O. Soyemi , Jeffrey L. Conroy
CPC classification number: G01N21/6408 , G01N21/6428 , G01N21/6458 , G01N2021/6439 , G01N2201/0221 , G07D7/003 , G07D7/0054
Abstract: At least two luminescent materials are intermingled within a security feature. The materials are selected from among a larger set of luminescent materials each having a different individual exponential decay characteristic (decay constant and initial amplitude response to the degree of excitation) for photo-luminescent emission from the respective material following excitation. The ratio of the decay constants for any two materials is greater than or equal to about 1.5. The selected materials are mixed in one of a plurality of predetermined ratios. The combined emissions from the intermingled materials appear, to an unsophisticated measuring device, to have a single exponential decay constant. Based on measurements for the decay of the combined emissions following excitation, estimates of the individual decay constants and associated initial emission amplitudes allow decoding of the particular combination of materials and/or their ratios to validate the security feature, authenticating the article.
Abstract translation: 至少两种发光材料混合在安全特征内。 这些材料选自对于来自激发后的各材料的光致发光的各种具有不同的指数衰减特性(衰减常数和激发程度的初始振幅响应)的较大组的发光材料。 任何两种材料的衰变常数之比大于或等于约1.5。 所选择的材料以多个预定比率之一混合。 来自混合材料的组合发射出现在不复杂的测量装置上,具有单个指数衰减常数。 基于对激发后的组合发射的衰减的测量,单个衰减常数和相关联的初始发射幅度的估计允许对材料的特定组合和/或其比率进行解码以验证安全特征,认证该文章。
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公开(公告)号:US10351789B2
公开(公告)日:2019-07-16
申请号:US15632532
申请日:2017-06-26
Applicant: Authentix, Inc.
Inventor: Jeffrey L. Conroy , Philip B. Forshee
IPC: C10L1/00 , C10L1/16 , G01N21/64 , G01N21/77 , G01N33/22 , G01N33/28 , C10L1/182 , C10L1/20 , G01N30/02 , H01J49/26 , G01N21/33 , G01N21/3504
Abstract: A method of increasing the accuracy of the quantification of an analyte in a hydrocarbon, the analyte containing a marking compound, by obtaining a first sample containing (a) the hydrocarbon and (b) the marking compound, obtaining a homogeneity inducing material, contacting the homogeneity inducing material with an aliquot of the first sample in a volumetric ratio of greater than or equal to about 5:1 to produce a second sample, and determining an amount of the marking compound in the second sample using an analytical technique based on the marking material.
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