公开(公告)号：US09366661B1

公开(公告)日：2016-06-14

申请号：US14806404

申请日：2015-07-22

Applicant: Authentix, Inc.

Inventor： Jeffrey L. Conroy ,  Philip B. Forshee ,  John-Christopher Boyer

IPC: G01N33/22 ,  C07C323/20 ,  C07C43/263 ,  G01N24/08 ,  G01N30/72 ,  G01N30/02

CPC classification number: C10L1/2406 ,  C07B2200/05 ,  C07C43/2055 ,  C07C43/21 ,  C07C43/263 ,  C07C43/275 ,  C07C321/30 ,  C07C323/20 ,  C07C2601/14 ,  C07C2601/16 ,  C10L1/003 ,  C10L1/1608 ,  C10L1/1852 ,  C10L1/2412 ,  C10L10/00 ,  C10L2200/0263 ,  C10L2200/0446 ,  C10L2230/16 ,  G01N21/65 ,  G01N24/08 ,  G01N30/7206 ,  G01N33/22 ,  G01N2030/025

Abstract: A method of determining adulteration of a fuel including subjecting to an analytical technique a marked fuel mixture comprising (a) a fuel; (b) a compound characterized by Formula I: wherein X is carbon, oxygen, or sulfur; when X is O or S, R1 and R2 are lone non-bonding electron pairs; when X is C, R1 and R2 each independently are hydrogen, C1 to C20 alkyl, or C6 to C10 aryl; R3 and R3′ each independently are hydrogen or C1 to C4 alkyl; R4 and R4′ each independently are hydrogen, C1 to C4 alkyl, C4 to C10 cycloalkyl, or C6 to C10 aryl; R5 and R5′ each independently are C4 to C10 alkyl; R6 and R6′ each independently are hydrogen or C1 to C6 alkyl; and R7 and R7′ each independently are hydrogen or C1 to C4 alkyl; and (c) a heavy compound, wherein the heavy compound comprises a compound of Formula I having at least one atom replaced with an isotope tag.

Abstract translation: 一种确定燃料掺假的方法，包括对分析技术进行标记的燃料混合物，其包括（a）燃料; （b）由式I表征的化合物：其中X是碳，氧或硫; 当X为O或S时，R 1和R 2为单键非键电子对; 当X为C时，R 1和R 2各自独立地为氢，C 1至C 20烷基或C 6至C 10芳基; R 3和R 3'各自独立地为氢或C 1至C 4烷基; R 4和R 4'各自独立地为氢，C 1至C 4烷基，C 4至C 10环烷基或C 6至C 10芳基; R5和R5'各自独立地为C4至C10烷基; R6和R6'各自独立地为氢或C1-C6烷基; 并且R 7和R 7'各自独立地为氢或C 1至C 4烷基; 和（c）重质化合物，其中重质化合物包含具有至少一个原子被同位素标记替换的式I化合物。

公开(公告)号：US09631152B2

公开(公告)日：2017-04-25

申请号：US14806389

申请日：2015-07-22

Applicant: Authentix, Inc.

Inventor： Jeffrey L. Conroy ,  Philip B. Forshee ,  John-Christopher Boyer

IPC: C10L1/24 ,  G01N33/22 ,  C07C323/20 ,  C07C43/263 ,  G01N30/72 ,  C07C43/205 ,  C07C43/21 ,  C07C43/275 ,  C07C321/30 ,  C10L1/185 ,  C10L10/00 ,  G01N21/65 ,  G01N24/08 ,  G01N30/02

CPC classification number: C10L1/2406 ,  C07B2200/05 ,  C07C43/2055 ,  C07C43/21 ,  C07C43/263 ,  C07C43/275 ,  C07C321/30 ,  C07C323/20 ,  C07C2601/14 ,  C07C2601/16 ,  C10L1/003 ,  C10L1/1608 ,  C10L1/1852 ,  C10L1/2412 ,  C10L10/00 ,  C10L2200/0263 ,  C10L2200/0446 ,  C10L2230/16 ,  G01N21/65 ,  G01N24/08 ,  G01N30/7206 ,  G01N33/22 ,  G01N2030/025

Abstract: A method of forming a composition comprising contacting a fuel and at least one compound of Formula I: wherein X is carbon, oxygen, or sulfur; R1 and R2 each independently are hydrogen, a C1 to C20 alkyl, or a C6 to C10 aryl; R3 and R3′ each independently are hydrogen or a C1 to C4 alkyl; R4 and R4′ each independently are hydrogen, a C1 to C4 alkyl, a C4 to C10 cycloalkyl, or a C6 to C10 aryl; R5 and R5′ each independently are a C4 to C10 alkyl; R6 and R6′ each independently are hydrogen or a C1 to C6 alkyl; and R7 and R7′ each independently are hydrogen or C1 to C4 alkyl; and wherein the compound of Formula I when subjected to GC-MS using electron ionization at greater than 70 eV produces at least one ion having a mass-to-charge ratio of 300 to 600.

公开(公告)号：US09732296B2

公开(公告)日：2017-08-15

申请号：US14806381

申请日：2015-07-22

Applicant: Authentix, Inc.

Inventor： Jeffrey L. Conroy ,  Philip B. Forshee ,  John-Christopher Boyer

IPC: C10L1/24 ,  C07C43/205 ,  C07C323/20 ,  C10L1/185 ,  C07C43/275 ,  G01N33/22 ,  C07C43/263 ,  G01N30/72 ,  C07C43/21 ,  C07C321/30 ,  C10L10/00 ,  G01N21/65 ,  G01N24/08 ,  G01N30/02

CPC classification number: C10L1/2406 ,  C07B2200/05 ,  C07C43/2055 ,  C07C43/21 ,  C07C43/263 ,  C07C43/275 ,  C07C321/30 ,  C07C323/20 ,  C07C2601/14 ,  C07C2601/16 ,  C10L1/003 ,  C10L1/1608 ,  C10L1/1852 ,  C10L1/2412 ,  C10L10/00 ,  C10L2200/0263 ,  C10L2200/0446 ,  C10L2230/16 ,  G01N21/65 ,  G01N24/08 ,  G01N30/7206 ,  G01N33/22 ,  G01N2030/025

Abstract: A composition comprising a fuel and at least one compound characterized by Formula I: wherein X is carbon, oxygen, or sulfur; R1 and R2 each independently are hydrogen, a C1 to C20 alkyl, or a C6 to C10 aryl; R3 and R3′ each independently are hydrogen or a C1 to C4 alkyl; R4 and R4′ each independently are hydrogen, a C1 to C4 alkyl, a C4 to C10 cycloalkyl, or a C6 to C10 aryl; R5 and R5′ each independently are a C4 to C10 alkyl; R6 and R6′ each independently are hydrogen or a C1 to C6 alkyl; and R7 and R7′ each independently are hydrogen or a C1 to C4 alkyl; and wherein the compound of Formula I when subjected to GC-MS using electron ionization at greater than about 70 eV produces at least one ion having a mass-to-charge ratio of from 300 to 600.