公开(公告)号：US08907135B2

公开(公告)日：2014-12-09

申请号：US13892143

申请日：2013-05-10

Applicant: Battelle Memorial Institute

Inventor： James J. Strohm ,  Alan H. Zacher ,  James F. White ,  Michel J. Gray ,  Vanessa Lebarbier

IPC: C07C45/52 ,  B01J8/00 ,  B01J27/00 ,  B01J38/04 ,  B01J27/28 ,  B01J27/185 ,  B01J38/12 ,  B01J38/02 ,  B01J27/18 ,  C07C45/00 ,  B01J38/06 ,  B01J21/08

CPC classification number: C07C45/00 ,  B01J8/001 ,  B01J21/08 ,  B01J27/18 ,  B01J27/1806 ,  B01J27/1853 ,  B01J27/285 ,  B01J38/02 ,  B01J38/04 ,  B01J38/06 ,  B01J38/12 ,  C07C45/52 ,  Y02P20/584 ,  C07C47/22

Abstract: The present disclosure relates to facilities, systems, methods and/or catalysts for use in chemical production. In particular, the disclosure provides innovations relating to dehydration of multihydric compounds such as glycerol to form acrolein. Some of these innovations include continuous reaction systems as well as system parameters that allow for long term production.

Abstract translation: 本公开涉及用于化学生产的设备，系统，方法和/或催化剂。 特别地，本公开提供了与多羟基化合物如甘油的脱水相关的创新以形成丙烯醛。 其中一些创新包括连续反应系统以及允许长期生产的系统参数。

公开(公告)号：US20190031585A1

公开(公告)日：2019-01-31

申请号：US16046395

申请日：2018-07-26

Applicant: BATTELLE MEMORIAL INSTITUTE

Inventor： Karthikeyan K. Ramasamy ,  Mond F. Guo ,  Michel J. Gray ,  Senthil Subramaniam

IPC: C07C29/34 ,  C07C29/32

Abstract: A method and catalyst for forming higher alcohols from lower alcohol feedstocks. In one application a highly selective and stable copper pseudo-single-atom supported on MgO—Al2O3 catalyst is provided which provides ethanol condensation to higher alcohols at ˜50% yields and ˜85% selectivity is demonstrated with stable catalyst lifetime over 500 hours in a continuous flow system. In some applications a Guerbet condensation process is further utilized to yield a higher alcohol at a selectivity of near ˜90%.

公开(公告)号：US10745330B2

公开(公告)日：2020-08-18

申请号：US16046395

申请日：2018-07-26

Applicant: BATTELLE MEMORIAL INSTITUTE

Inventor： Karthikeyan K. Ramasamy ,  Mond F. Guo ,  Michel J. Gray ,  Senthil Subramaniam

IPC: C07C29/34 ,  C07C29/32

Abstract: A method and catalyst for forming higher alcohols from lower alcohol feedstocks. In one application a highly selective and stable copper pseudo-single-atom supported on MgO—Al2O3 catalyst is provided which provides ethanol condensation to higher alcohols at ˜50% yields and ˜85% selectivity is demonstrated with stable catalyst lifetime over 500 hours in a continuous flow system. In some applications a Guerbet condensation process is further utilized to yield a higher alcohol at a selectivity of near ˜90%.

公开(公告)号：US20180215692A1

公开(公告)日：2018-08-02

申请号：US15871773

申请日：2018-01-15

Applicant: BATTELLE MEMORIAL INSTITUTE

Inventor： Karthikeyan Kallupalayam Ramasamy ,  Michel J. Gray ,  Carlos A. Alvarez-Vasco ,  Mond F. Guo ,  Senthil Subramaniam

IPC: C07C45/45 ,  B01J23/80 ,  B01J23/72

CPC classification number: C07C45/45 ,  B01J23/72 ,  B01J23/80 ,  C07C49/04

Abstract: Methods, systems and catalysts for converting an alcohol containing feedstock to an upgraded material in a single catalyst bed wherein a feedstock is fed to a catalyst under preselected conditions to obtain an intermediate; and condensing the intermediate through an aldol condensation reaction to yield a product containing an upgraded material. In one instance the feedstock includes ethanol, the catalyst is a mixed metal oxide catalyst and the upgraded material is typically a C5+ ketone(s) or alcohol(s), such as 2-pentanone, 2-heptanone, 4-heptanone and 2-nonanone.

公开(公告)号：US10221119B2

公开(公告)日：2019-03-05

申请号：US15871773

申请日：2018-01-15

Applicant: BATTELLE MEMORIAL INSTITUTE

Inventor： Karthikeyan Kallupalayam Ramasamy ,  Michel J. Gray ,  Carlos A. Alvarez-Vasco ,  Mond F. Guo ,  Senthil Subramaniam

IPC: C07C45/45 ,  B01J23/72 ,  B01J23/80

Abstract: Methods, systems and catalysts for converting an alcohol containing feedstock to an upgraded material in a single catalyst bed wherein a feedstock is fed to a catalyst under preselected conditions to obtain an intermediate; and condensing the intermediate through an aldol condensation reaction to yield a product containing an upgraded material. In one instance the feedstock includes ethanol, the catalyst is a mixed metal oxide catalyst and the upgraded material is typically a C5+ ketone(s) or alcohol(s), such as 2-pentanone, 2-heptanone, 4-heptanone and 2-nonanone.

公开(公告)号：US20130253227A1

公开(公告)日：2013-09-26

申请号：US13892143

申请日：2013-05-10

Applicant: Battelle Memorial Institute

Inventor： James J. Strohm ,  Alan H. Zacher ,  James F. White ,  Michel J. Gray ,  Vanessa Lebarbier

IPC: C07C45/00 ,  B01J8/00

CPC classification number: C07C45/00 ,  B01J8/001 ,  B01J21/08 ,  B01J27/18 ,  B01J27/1806 ,  B01J27/1853 ,  B01J27/285 ,  B01J38/02 ,  B01J38/04 ,  B01J38/06 ,  B01J38/12 ,  C07C45/52 ,  Y02P20/584 ,  C07C47/22

Abstract: The present disclosure relates to facilities, systems, methods and/or catalysts for use in chemical production. In particular, the disclosure provides innovations relating to dehydration of multihydric compounds such as glycerol to form acrolein. Some of these innovations include continuous reaction systems as well as system parameters that allow for long term production.

Abstract translation: 本公开涉及用于化学生产的设备，系统，方法和/或催化剂。 特别地，本公开提供了与多羟基化合物如甘油的脱水相关的创新以形成丙烯醛。 其中一些创新包括连续反应系统以及允许长期生产的系统参数。