公开(公告)号：US11505705B2

公开(公告)日：2022-11-22

申请号：US16119319

申请日：2018-08-31

Applicant: CHEMETALL GMBH

Inventor： Daniel Wasserfallen ,  Michael Schwamb ,  Aliaksandr Frenkel ,  Vera Sotke ,  Wolfgang Bremser ,  Martin Droll ,  Oliver Seewald ,  Ron Eilinghoff ,  Stephanie Gerold ,  Evgenija Niesen ,  Lars Schachtsiek ,  Manuel Traut

IPC: C09D101/00 ,  C09D103/00 ,  C09D103/12 ,  C08G71/04 ,  C08G73/00 ,  C09D5/08 ,  B05D7/14 ,  B05D1/18 ,  C25D13/04 ,  C25D13/16 ,  B05D3/02

Abstract: The invention relates to a method for coating surfaces, to a corresponding coating, and to the use of the objects coated in accordance with said method. The invention relates to a method for coating metal surfaces of substrates, comprising or consisting of the following steps: I. providing a substrate having a cleaned metal surface, II. contacting and coating metal surfaces with an aqueous composition in the form of a dispersion and/or suspension, IX. optionally rinsing the organic coating, and X. drying and/or baking the organic coating or XI. optionally drying the organic coating and coating with a coating composition of the same type or a further coating composition before a drying process and/or baking process, wherein in step II the coating is performed with an aqueous composition in the form of a dispersion and/or suspension containing 2.5 to 45 wt % of at least one non-ionic stabilized binder and 0.1 to 2.0 wt % of a gelling agent, wherein the aqueous composition has a pH value in the range of 0.5 to 7 and forms, with the cations eluted from the metal surface in the pretreatment step and/or during the contacting in step II, a coating based on an ionogenic gel.

公开(公告)号：US11261337B2

公开(公告)日：2022-03-01

申请号：US16512919

申请日：2019-07-16

Applicant: Chemetall GmbH

Inventor： Daniel Wasserfallen ,  Michael Schwamb ,  Aliaksandr Frenkel ,  Vera Sotke ,  Wolfgang Bremser ,  Martin Droll ,  Ron Eilinghoff ,  Stephanie Gerold ,  Evgenija Niesen ,  Lars Schachtsiek ,  Manuel Traut ,  Oliver Seewald

IPC: C09D7/61 ,  C09D175/04 ,  B05D7/14 ,  B05D7/16 ,  B05D7/00 ,  C09D133/08 ,  C09D163/00 ,  C09D7/40 ,  C08F2/18 ,  C09D5/08 ,  C09D101/02 ,  C09D103/02 ,  C09D103/12 ,  C09D105/00 ,  C09D105/02 ,  C09D105/04 ,  C09D105/06 ,  C09D105/08 ,  C09D105/12 ,  C09D189/00 ,  C09D189/06 ,  C09D197/00 ,  C23C18/12 ,  C23C22/34 ,  C23C22/74 ,  C09D133/06

Abstract: A coating, a method for coating surfaces, and the coated surfaces. The method includes providing a substrate with a cleaned metal surface; contacting and coating the metal surface with an aqueous composition having a ph of from 0.5 to 7.0 and in the form of a dispersion and/or a suspension; optionally rinsing the organic coating; and drying and/or baking the organic coating, or optionally drying the organic coating and coating same with a similar or another coating composition thereto. The composition contains a complex fluoride in a quantity of 1.1 10−6 mol/l to 0.30 mol/l based on the cations. An anionic polyelectrolyte in a quantity of 0.01 to 5.0 wt % based on the total mass of the resulting mixture is added to an anionically stabilized dispersion made of film-forming polymers and/or a suspension made of film-forming inorganic particles.

公开(公告)号：US20190300722A1

公开(公告)日：2019-10-03

申请号：US16308206

申请日：2017-06-08

Applicant: Chemetall GmbH

Inventor： Wolfgang Bremser ,  Martin Droll ,  Oliver Seewald ,  Evgenija Niesen-Warkentin ,  Lars Schachtsiek ,  Manuel Traut ,  Michael Schwamb ,  Daniel Wasserfallen ,  Nawel Souad Khelfallah ,  Vera Sotke ,  Aliaksandr Frenkel ,  Ron Eilinghoff ,  Stephanie Gerold ,  Felix Kleimenhagen

IPC: C09D5/08 ,  C08G18/83 ,  C08G18/42 ,  C08G18/32 ,  C08G18/34 ,  C08G18/66 ,  C08G18/76 ,  C09D175/16 ,  C09D5/02 ,  C09D7/40

Abstract: Binders stabilized in an aqueous phase and capable of codeposition with ionogenic gel-formers are disclosed. The binder may be a resin or polymer, including polyacrylates, polyurethanes, polyepoxides, urethane acrylates, aromatic and (cyclo)-aliphatic epoxy acrylates, polyesters, and mixtures thereof. The binders are modified by reactions between reactive groups on the binder and hydrophilic, functional molecules. Reactive groups on the binder may include isocyanates, hydroxyls, carboxyls, oxiranes, vinyls and amines. A method of producing such dispersions is disclosed.

公开(公告)号：US09556523B2

公开(公告)日：2017-01-31

申请号：US14377048

申请日：2013-02-07

Applicant: Chemetall GmbH

Inventor： Daniel Wasserfallen ,  Michael Schwamb ,  Aliaksandr Frenkel ,  Vera Sotke ,  Wolfgang Bremser ,  Martin Droll ,  Oliver Seewald ,  Ron Eilinghoff ,  Stephanie Gerold ,  Evgenija Niesen ,  Lars Schachtsiek ,  Manuel Traut

IPC: C23C18/16 ,  B05D7/16 ,  C09D5/08 ,  C09D133/14 ,  C23C18/18 ,  B05D7/14 ,  B05D1/18

CPC classification number: C23C18/1637 ,  B05D1/18 ,  B05D7/14 ,  B05D7/142 ,  B05D7/16 ,  C09D5/088 ,  C09D133/14 ,  C23C18/1692 ,  C23C18/1803

Abstract: A method and composition for coating surfaces, a corresponding coating and the use of objects coated according to said method. A cleaned, metallic surface is contacted with an aqueous composition that is a dispersion or suspension, and drying and/or baking the organic coating or optionally, drying the organic coating and coating with an equivalent or additional coating composition prior to a drying and/or baking. The aqueous composition has a pH of 4 to 11 and contains an anionic polyelectrolyte in a quantity of 0.01 to 5.0 wt. % relative to the total mass of the composition, which may have a solids content of from 2 to 40 wt. %. The solids have an average particle size from 10 to 1000 nm. A coating forms on the basis of an ionogenic gel which binds cations released from the metallic surface that originate from a pretreatment stage or from the contacting.

Abstract translation: 用于涂覆表面的方法和组合物，相应的涂层以及根据所述方法涂覆的物体的使用。 将清洁的金属表面与作为分散体或悬浮液的水性组合物接触，并干燥和/或烘烤有机涂层或任选地在干燥之前干燥有机涂层和用相当的或附加的涂料组合物涂覆和/或 烘烤 水性组合物的pH为4〜11，含有0.01〜5.0重量％的阴离子性聚电解质。 相对于组合物的总质量，其可以具有2至40重量％的固体含量。 ％。 固体的平均粒度为10〜1000nm。 基于结合起始于预处理阶段或接触的金属表面释放的阳离子的离子发生凝胶形成涂层。

公开(公告)号：US20150322288A1

公开(公告)日：2015-11-12

申请号：US14646973

申请日：2013-11-25

Applicant: Chemetall GmbH

Inventor： Daniel Wasserfallen ,  Michael Schwamb ,  Aliaksandr Frenkel ,  Vera Sotke ,  Wolfgang Bremser ,  Martin Droll ,  Oliver Seewald ,  Ron Eilinghoff ,  Stephanie Gerold ,  Evgenija Niesen ,  Lars Schachtsiek ,  Manuel Traut

IPC: C09D175/04 ,  C09D163/00 ,  B05D7/00 ,  C09D133/08 ,  B05D7/14 ,  B05D7/16

CPC classification number: C09D175/04 ,  B05D7/148 ,  B05D7/16 ,  B05D7/51 ,  B05D7/52 ,  C08F2/18 ,  C08L2205/025 ,  C09D5/084 ,  C09D7/61 ,  C09D7/67 ,  C09D7/68 ,  C09D101/02 ,  C09D103/02 ,  C09D103/12 ,  C09D105/00 ,  C09D105/02 ,  C09D105/04 ,  C09D105/06 ,  C09D105/08 ,  C09D105/12 ,  C09D133/06 ,  C09D133/08 ,  C09D163/00 ,  C09D189/00 ,  C09D189/06 ,  C09D197/005 ,  C23C18/1241 ,  C23C18/1254 ,  C23C22/34 ,  C23C22/74 ,  C08L5/06 ,  C08F2220/1825 ,  C08F220/14 ,  C08F220/20 ,  C08F222/02

Abstract: A coating, a method for coating surfaces, and the coated surfaces. The method includes providing a substrate with a cleaned metal surface; contacting and coating the metal surface with an aqueous composition having a ph of from 0.5 to 7.0 and in the form of a dispersion and/or a suspension; optionally rinsing the organic coating; and drying and/or baking the organic coating, or optionally drying the organic coating and coating same with a similar or another coating composition thereto. The composition contains a complex fluoride in a quantity of 1.1 10−6 mol/l to 0.30 mol/l based on the cations. An anionic polyelectrolyte in a quantity of 0.01 to 5.0 wt % based on the total mass of the resulting mixture is added to an anionically stabilized dispersion made of film-forming polymers and/or a suspension made of film-forming inorganic particles.

Abstract translation: 涂层，涂布表面的方法和涂覆表面。 该方法包括提供具有清洁的金属表面的基底; 用pH为0.5至7.0的水性组合物和分散体和/或悬浮液的形式接触和涂覆金属表面; 任选地漂洗有机涂层; 干燥和/或烘烤有机涂层，或任选地将有机涂层干燥并用相似或另一种涂料组合物涂覆其上。 该组合物含有基于阳离子的1.1×10 -6 mol / l至0.30mol / l的复合氟化物。 将所得混合物的总质量为0.01〜5.0重量％的阴离子聚电解质加入到由成膜聚合物和/或由成膜无机颗粒制成的悬浮液的阴离子稳定的分散体中。

公开(公告)号：US20190382615A1

公开(公告)日：2019-12-19

申请号：US16512919

申请日：2019-07-16

Applicant: Chemetall GmbH

Inventor： Daniel Wasserfallen ,  Michael Schwamb ,  Aliaksandr Frenkel ,  Vera Sotke ,  Wolfgang Bremser ,  Martin Droll ,  Ron Eilinghoff ,  Stephanie Gerold ,  Evgenija Niesen ,  Lars Schachtsiek ,  Manuel Traut ,  Oliver Seewald

IPC: C09D175/04 ,  B05D7/14 ,  C23C22/74 ,  C23C22/34 ,  C23C18/12 ,  B05D7/16 ,  B05D7/00 ,  C08F2/18 ,  C09D5/08 ,  C09D7/61 ,  C09D7/40 ,  C09D101/02 ,  C09D103/02 ,  C09D103/12 ,  C09D105/00 ,  C09D105/02 ,  C09D105/04 ,  C09D105/06 ,  C09D105/08 ,  C09D105/12 ,  C09D133/08 ,  C09D163/00 ,  C09D189/00 ,  C09D189/06 ,  C09D197/00

Abstract: A coating, a method for coating surfaces, and the coated surfaces. The method includes providing a substrate with a cleaned metal surface; contacting and coating the metal surface with an aqueous composition having a ph of from 0.5 to 7.0 and in the form of a dispersion and/or a suspension; optionally rinsing the organic coating; and drying and/or baking the organic coating, or optionally drying the organic coating and coating same with a similar or another coating composition thereto. The composition contains a complex fluoride in a quantity of 1.1 10−6 mol/l to 0.30 mol/l based on the cations. An anionic polyelectrolyte in a quantity of 0.01 to 5.0 wt % based on the total mass of the resulting mixture is added to an anionically stabilized dispersion made of film-forming polymers and/or a suspension made of film-forming inorganic particles.

公开(公告)号：US10400135B2

公开(公告)日：2019-09-03

申请号：US14646973

申请日：2013-11-25

Applicant: Chemetall GmbH

Inventor： Daniel Wasserfallen ,  Michael Schwamb ,  Aliaksandr Frenkel ,  Vera Sotke ,  Wolfgang Bremser ,  Martin Droll ,  Oliver Seewald ,  Ron Eilinghoff ,  Stephanie Gerold ,  Evgenija Niesen ,  Lars Schachtsiek ,  Manuel Traut

IPC: C09D175/04 ,  B05D7/14 ,  B05D7/16 ,  B05D7/00 ,  C09D133/08 ,  C09D163/00 ,  C09D5/08 ,  C09D105/00 ,  C09D105/06 ,  C23C18/12 ,  C23C22/34 ,  C23C22/74 ,  C09D101/02 ,  C09D103/02 ,  C09D103/12 ,  C09D105/02 ,  C09D105/04 ,  C09D105/08 ,  C09D105/12 ,  C09D189/00 ,  C09D189/06 ,  C09D197/00 ,  C08F2/18 ,  C09D7/61 ,  C09D7/40 ,  C09D133/06

Abstract: A coating, a method for coating surfaces, and the coated surfaces. The method includes providing a substrate with a cleaned metal surface; contacting and coating the metal surface with an aqueous composition having a ph of from 0.5 to 7.0 and in the form of a dispersion and/or a suspension; optionally rinsing the organic coating; and drying and/or baking the organic coating, or optionally drying the organic coating and coating same with a similar or another coating composition thereto. The composition contains a complex fluoride in a quantity of 1.1 10−6 mol/l to 0.30 mol/l based on the cations. An anionic polyelectrolyte in a quantity of 0.01 to 5.0 wt % based on the total mass of the resulting mixture is added to an anionically stabilized dispersion made of film-forming polymers and/or a suspension made of film-forming inorganic particles.

公开(公告)号：US10040955B2

公开(公告)日：2018-08-07

申请号：US15115872

申请日：2015-02-03

Applicant: CHEMETALL GMBH

Inventor： Ron Eilinghoff ,  Michael Schwamb ,  Daniel Wasserfallen ,  Vera Sotke ,  Aliaksandr Frenkel ,  Stephanie Gerold ,  Wolfgang Bremser ,  Martin Droll ,  Oliver Seewald ,  Evgenija Niesen-Warkentin ,  Lars Schachtsiek ,  Manuel Traut

IPC: B08B3/00 ,  C09D9/00 ,  C23C18/18 ,  C23G1/14 ,  C23G1/18 ,  C23G1/24 ,  C23G1/26 ,  B05D1/02 ,  B05D1/18

Abstract: The invention relates to a method for removing a substrate that is coated with an organic coated coating by means of ionogenic gel formation. In said method, a wet or dry organic coating that has not yet formed a film on the substrate is treated with an aqueous solution of a metal salt from main group I in the periodic table of the elements, a complexing agent and/or a basic compound having a pH value >10.

公开(公告)号：US20160168711A1

公开(公告)日：2016-06-16

申请号：US14903677

申请日：2014-07-16

Applicant: CHEMETALL GMBH

Inventor： Daniel Wasserfallen ,  Michael Schwamb ,  Aliakasandr Frenkel ,  Vera Sotke Sotke ,  Wolfgang Bremser ,  Martin Droll ,  Oliver Seewald ,  Ron Eilinghoff ,  Stephanie Gerold ,  Evgenija Niesen ,  Lars Schachtsiek ,  Manuel Traut ,  Philipp Klopzig

IPC: C23C16/56 ,  C09D5/08

CPC classification number: C23C16/56 ,  C08L2205/025 ,  C09D5/02 ,  C09D5/08 ,  C09D101/02 ,  C09D103/02 ,  C09D103/12 ,  C09D105/00 ,  C09D105/02 ,  C09D105/04 ,  C09D105/06 ,  C09D105/08 ,  C09D105/12 ,  C09D133/04 ,  C09D189/00 ,  C09D189/06 ,  C09D197/005 ,  C23C18/125 ,  C25D9/10 ,  C08L5/06 ,  C08L5/00

Abstract: The invention relates to a method for coating surfaces, to a corresponding coating, and to the use of the objects coated according to said method. According to the invention, the method has or consists of the following steps: I. providing a substrate with a cleaned surface, II. contacting and coating the surfaces with an aqueous composition in the form of a dispersion and/or suspension, VI. if necessary rinsing the organic coating, and VII. drying and/or baking the organic coating or VIII. if necessary drying the organic coating and carrying out a coating process using a similar or additional coating composition prior to a drying and/or baking process, wherein between step I and step II, the coating process is carried out using an aqueous composition in the form of a dispersion and/or suspension on the basis of a colloidal silicate sol, which incorporates multivalent metal cations, or a silane- or silicate-modified polymer and if necessary a rinsing process is carried out.

Abstract translation: 本发明涉及一种用于将表面，相应的涂层以及根据所述方法涂覆的物体的使用的方法。 根据本发明，该方法具有或包括以下步骤：I.提供具有清洁表面的基底，II。 以分散体和/或悬浮液形式的水性组合物接触和涂覆表面。 如有必要，有机涂层进行冲洗，和VII。 干燥和/或烘烤有机涂层或VIII。 如果需要干燥有机涂层并且在干燥和/或烘烤过程之前使用相似或另外的涂料组合物进行涂覆工艺，其中在步骤I和步骤II之间，使用水性组合物的形式 基于胶体硅酸盐溶胶（其包含多价金属阳离子）或硅烷或硅酸盐改性聚合物的分散体和/或悬浮液，并且如果需要，进行漂洗处理。

公开(公告)号：US20200207995A1

公开(公告)日：2020-07-02

申请号：US16633694

申请日：2018-07-20

Applicant: Chemetall GmbH

Inventor： Aliaksandr Frenkel ,  Ron Eilinghoff ,  Martin Droll

IPC: C09D7/65 ,  C08G18/08 ,  C08G18/28 ,  C08G18/64 ,  C09D5/08 ,  C08G18/80 ,  C09D7/40 ,  C09D7/63 ,  B05D3/00 ,  B05D7/00 ,  B05D1/18 ,  C09D175/04

Abstract: Aqueous coating compositions are provided. The aqueous compositions include at least one type of organic polymer particles having an average particle size of 10 to 1000 nm, including isocyanate-reactive polymers (A), one or more ketoxime- and/or pyrazole-blocked polyisocyanates (B) including at least one aromatic hydrocarbyl radical or at least one cycloaliphatic hydrocarbyl radical, at least one polyanionic polymer (C), at least one complex fluoride (D) selected from the group consisting of hexa- or tetrafluorides of metallic elements of groups IVb, Vb and VIb of the Periodic Table of the Elements, and at least one aminosilane (E), wherein the aqueous coating compositions have a pH of 3 to 5, and have a total solids content of 5% to 35% by weight. Also provided are processes for producing these aqueous coating compositions, processes for coating metal ion-releasing surfaces with the aqueous coating compositions, and coatings obtained therefrom.