公开(公告)号：US09833774B2

公开(公告)日：2017-12-05

申请号：US15300139

申请日：2015-05-14

Applicant: Dow Global Technologies LLC

Inventor： Vera P. Santos Castro ,  Adam Chojecki ,  Garmt R. Meima ,  Adrianus Koeken ,  Matthijs Ruitenbeek ,  Thomas Davidian ,  Gascon Jorge ,  Michiel Makkee ,  Freek Kapteijn ,  Tim A. Wezendonk

IPC: B01J23/78 ,  B01J37/08 ,  B01J37/02 ,  B01J35/02

CPC classification number: B01J23/78 ,  B01J27/22 ,  B01J31/1691 ,  B01J31/223 ,  B01J35/002 ,  B01J35/006 ,  B01J35/023 ,  B01J37/0201 ,  B01J37/0203 ,  B01J37/086 ,  B01J37/18 ,  B01J2231/648 ,  B01J2531/0216 ,  B01J2531/842 ,  C10G2/332 ,  C10G2300/70

Abstract: Preparation of a catalyst suitable for use in Fischer-Tropsch Synthesis reactions using a two step process in which the steps may be performed in either order. In step a), impregnate an iron carboxylate metal organic framework selected from a group consisting of iron-1,3,5-benzenetricarboxylate (Fe-(BTC), Basolite™ F-300 and/or MIL-100 (Fe)), iron-1,4 benzenedicarboxylate (MIL-101(Fe)), iron fumarate (MIL-88 A (Fe)), iron-1,4 benzenedicarboxylate (MIL-53 (Fe)), iron-1,4 benzenedicarboxylate (MIL-68 (Fe)) or iron azobenzenetetracarboxylate (MIL-127 (Fe)) with a solution of a promoter element selected from alkali metals and alkaline earth metals. In step b) thermally decompose the iron carboxylate metal organic framework under an inert gaseous atmosphere to yield a catalyst that is a porous carbon matrix having embedded therein a plurality of discrete aliquots of iron carbide. If desired, add a step intermediate between steps a) and b) or preceding step b) wherein the metal organic framework is impregnated with an oxygenated solvent solution of a polymerizable additional carbon source and the polymerizable additional carbon source is thereafter polymerized.

公开(公告)号：US09694345B2

公开(公告)日：2017-07-04

申请号：US14889483

申请日：2014-06-25

Applicant: Dow Global Technologies LLC

Inventor： Thomas Davidian ,  Matthijs Ruitenbeek ,  Adam Chojecki ,  Adrianus Koeken

IPC: C07C1/04 ,  B01J21/06 ,  B01J23/02 ,  B01J23/04 ,  B01J23/10 ,  B01J23/745 ,  B01J23/76 ,  B01J23/83 ,  B01J27/053 ,  B01J27/22 ,  B01J37/02 ,  B01J37/08 ,  B01J23/78

CPC classification number: B01J23/10 ,  B01J21/066 ,  B01J23/745 ,  B01J23/78 ,  B01J23/83 ,  B01J27/22 ,  B01J37/0205 ,  B01J37/084 ,  C07C1/044 ,  C07C2521/06 ,  C07C2523/04 ,  C07C2523/10 ,  C07C2523/745 ,  C07C2523/78 ,  C07C2523/83 ,  C07C2527/224 ,  Y02P20/52 ,  C07C11/04 ,  C07C11/06

Abstract: A catalyst composition and process for preparing it and for using it to enhance the selectivity to light (C2 to C3) olefins in a Fischer-Tropsch conversion of synthesis gas is disclosed. The catalyst composition is an iron-based catalyst on an yttria/zirconia support. In a Fischer-Tropsch reaction the selectivity to ethylene may be enhanced by at least 20 mole percent and to propylene by at least 4 mole percent, in comparison with use of an otherwise identical catalyst that is free of yttria, in an otherwise identical Fischer-Tropsch reaction.

公开(公告)号：US20160107144A1

公开(公告)日：2016-04-21

申请号：US14889483

申请日：2014-06-25

Applicant: DOW GLOBAL TECHNOLOGIES LLC

Inventor： Thomas Davidian ,  Matthijs Ruitenbeek ,  Adam Chojecki ,  Adrianus Koeken

IPC: B01J23/10 ,  B01J23/745 ,  B01J23/78 ,  C07C1/04

CPC classification number: B01J23/10 ,  B01J21/066 ,  B01J23/745 ,  B01J23/78 ,  B01J23/83 ,  B01J27/22 ,  B01J37/0205 ,  B01J37/084 ,  C07C1/044 ,  C07C2521/06 ,  C07C2523/04 ,  C07C2523/10 ,  C07C2523/745 ,  C07C2523/78 ,  C07C2523/83 ,  C07C2527/224 ,  Y02P20/52 ,  C07C11/04 ,  C07C11/06

Abstract: A catalyst composition and process for preparing it and for using it to enhance the selectivity to light (C2 to C3) olefins in a Fischer-Tropsch conversion of synthesis gas is disclosed. The catalyst composition is an iron-based catalyst on an yttria/zirconia support. In a Fischer-Tropsch reaction the selectivity to ethylene may be enhanced by at least 20 mole percent and to propylene by at least 4 mole percent, in comparison with use of an otherwise identical catalyst that is free of yttria, in an otherwise identical Fischer-Tropsch reaction.

Abstract translation: 公开了一种催化剂组合物及其制备方法和用于在合成气的费 - 托转化中提高对光（C 2至C 3）烯烃的选择性的方法。 催化剂组合物是氧化钇/氧化锆载体上的铁基催化剂。 在费 - 托反应中，与使用另外相同的不含氧化钇的催化剂相比，在其它相同的费 - 托反应中，对乙烯的选择性可以提高至少20摩尔％，丙烯至少为4摩尔％ 托反应。

公开(公告)号：US20240051901A1

公开(公告)日：2024-02-15

申请号：US18257895

申请日：2021-12-15

Applicant: Dow Global Technologies LLC

Inventor： Lin Luo ,  Yang Yang ,  Adrianus Koeken ,  Brien Stears ,  Luis Bollmann ,  Andrzej Malek ,  Brian W. Goodfellow

IPC: C07C5/333 ,  B01J23/62 ,  B01J21/04 ,  B01J23/96 ,  B01J38/30 ,  B01J38/02

CPC classification number: C07C5/3337 ,  B01J23/62 ,  B01J21/04 ,  B01J23/96 ,  B01J38/30 ,  B01J38/02 ,  C07C2523/62

Abstract: According to one or more embodiments of the present disclosure, a method for producing olefins includes contacting a hydrocarbon-containing feed with a catalyst in a reactor portion of a reactor system to form an olefin-containing effluent, separating at least a portion of the olefin-containing effluent from the catalyst, passing the catalyst to a catalyst-processing portion of the reactor system and processing the catalyst to produce a processed catalyst and a combustion gas, passing the processed catalyst from the catalyst-processing portion to the reactor portion, and introducing a combustion additive to the reactor system when the combustion gas comprises one or more hydrocarbons in an amount greater than 5% of an LFL of the combustion gas at a temperature and pressure of the catalyst processing portion. The catalyst may include from 1 ppmw to 150 ppmw platinum. The combustion additive may include from 150 ppmw to 1,000 ppmw platinum.

公开(公告)号：US20240050927A1

公开(公告)日：2024-02-15

申请号：US18257908

申请日：2021-12-15

Applicant: Dow Global Technologies LLC

Inventor： Lin Luo ,  Yang Yang ,  Adrianus Koeken ,  Brien Stears ,  Luis Bollmann ,  Andrzej Malek ,  Brian W. Goodfellow

IPC: B01J23/62 ,  B01J21/04 ,  C07C5/333

CPC classification number: B01J23/62 ,  B01J21/04 ,  C07C5/3337 ,  C07C2523/42 ,  C07C2523/08

Abstract: According to one or more embodiments of the present disclosure, a catalyst system useful for dehydrogenation includes from 98 vol. % to 99.95 vol. % of a catalyst and from 0.05 vol. % to 2 vol. % of a combustion additive. The catalyst may include from 1 ppmw to 150 ppmw platinum, gallium, and a support material. The combustion additive may include from 150 ppmw to 1,000 ppmw platinum, gallium, and a support material. The combustion additive may include at least 1.1 times greater platinum than the catalyst.

公开(公告)号：US20240343663A1

公开(公告)日：2024-10-17

申请号：US18683693

申请日：2022-08-29

Applicant: Dow Global Technologies LLC

Inventor： Lin Luo ,  Adrianus Koeken ,  Mingzhe Yu ,  Andrzej Malek ,  Hangyao Wang ,  Luis Bollmann

IPC: C07C5/333 ,  B01J8/24 ,  B01J23/62 ,  B01J23/96

CPC classification number: C07C5/3337 ,  B01J8/24 ,  B01J23/62 ,  B01J23/96 ,  C07C2523/62

Abstract: A method for dehydrogenation of one or more hydrocarbons and regeneration and reactivation of a catalyst composition includes contacting a first gaseous stream comprising a first hydrocarbon, such as propane, with a catalyst composition in a dehydrogenation reactor at a first temperature, thereby producing a first dehydrogenated hydrocarbon, such as propylene, and a deactivated catalyst composition; combusting at least one fuel gas and coke on the deactivated catalyst in the presence of oxygen at a second temperature, thereby producing a heated catalyst composition; and reactivating the catalyst in the presence of oxygen. The second temperature is from 50° C. to 200° C. greater than the first temperature. The catalyst composition is also described and comprises gallium, platinum and a further noble metal, such as palladium.

公开(公告)号：US20170173565A1

公开(公告)日：2017-06-22

申请号：US15300139

申请日：2015-05-14

Applicant: DOW GLOBAL TECHNOLOGIES LLC

Inventor： Vera P. Santos Castro ,  Adam Chojecki ,  Garmt R. Meima ,  Adrianus Koeken ,  Matthijs Ruitenbeek ,  Thomas Davidian ,  Gascon Jorge ,  Michiel Makkee ,  Freek Kapteijn ,  Tim A. Wezendonk

IPC: B01J23/78 ,  B01J37/02 ,  B01J35/02 ,  B01J37/08

CPC classification number: B01J23/78 ,  B01J27/22 ,  B01J31/1691 ,  B01J31/223 ,  B01J35/002 ,  B01J35/006 ,  B01J35/023 ,  B01J37/0201 ,  B01J37/0203 ,  B01J37/086 ,  B01J37/18 ,  B01J2231/648 ,  B01J2531/0216 ,  B01J2531/842 ,  C10G2/332 ,  C10G2300/70

Abstract: Preparation of a catalyst suitable for use in Fischer-Tropsch Synthesis reactions using a two step process in which the steps may be performed in either order. In step a), impregnate an iron carboxylate metal organic framework selected from a group consisting of iron-1,3,5-benzenetricarboxylate (Fe-(BTC), Basolite™ F-300 and/or MIL-100 (Fe)), iron-1,4 benzenedicarboxylate (MIL-101(Fe)), iron fumarate (MIL-88 A (Fe)), iron-1,4 benzenedicarboxylate (MIL-53 (Fe)), iron-1,4 benzenedicarboxylate (MIL-68 (Fe)) or iron azobenzenetetracarboxylate (MIL-127 (Fe)) with a solution of a promoter element selected from alkali metals and alkaline earth metals. In step b) thermally decompose the iron carboxylate metal organic framework under an inert gaseous atmosphere to yield a catalyst that is a porous carbon matrix having embedded therein a plurality of discrete aliquots of iron carbide. If desired, add a step intermediate between steps a) and b) or preceding step b) wherein the metal organic framework is impregnated with an oxygenated solvent solution of a polymerizable additional carbon source and the polymerizable additional carbon source is thereafter polymerized.

公开(公告)号：US09643164B2

公开(公告)日：2017-05-09

申请号：US14894561

申请日：2014-06-25

Applicant: Dow Global Technologies LLC

Inventor： Thomas Davidian ,  Matthijs Ruitenbeek ,  Adrianus Koeken ,  Marjolein Vos ,  Marco F. Wielemaker

IPC: B01J37/18 ,  B01J27/22 ,  B01J23/78 ,  C07C1/04 ,  C10G2/00 ,  B01J37/08 ,  B01J37/02 ,  B01J35/00 ,  B01J35/02

CPC classification number: B01J27/22 ,  B01J23/78 ,  B01J35/0013 ,  B01J35/002 ,  B01J35/006 ,  B01J35/023 ,  B01J37/0205 ,  B01J37/084 ,  B01J37/18 ,  C07C1/0445 ,  C07C2521/04 ,  C07C2523/745 ,  C10G2/332 ,  Y02P20/52 ,  C07C11/02 ,  C07C11/04 ,  C07C11/06

Abstract: A Fischer-Tropsch catalyst, useful for conversion of synthesis gas to olefins, is prepared from a catalyst precursor composition including iron oxide and an alkali metal on a substantially inert support, and then treated by a process including as ordered steps (1) reduction in a hydrogen-containing atmosphere at a pressure of 0.1 to 1 M Pa and a temperature from 280° C. to 450° C.; (2) carburization in a carbon monoxide-containing atmosphere at a pressure from 0.1 to 1 M Pa and a temperature from 200° C. to less than 340° C.; and (3) conditioning in a hydrogen- and carbon monoxide-containing atmosphere at a pressure from 0.1 to 2 MPa and a temperature from 280° C. to 340° C. The resulting catalyst exhibits at least one improvement selected from (1) increased overall activity; (2) reduced break-in time; (3) slowed rate of deactivation; and (4) increased time to onset of deactivation; when compared to an otherwise identical catalyst precursor composition treated by one or some, but not all, of the given steps and/or under different conditions.

公开(公告)号：US20160121311A1

公开(公告)日：2016-05-05

申请号：US14894561

申请日：2014-06-25

Applicant: Dow Global Technologies LLC

Inventor： Thomas Davidian ,  Matthijs Ruitenbeek ,  Adrianus Koeken ,  Marjolein Vos ,  Marco F. Wielemaker

IPC: B01J27/22 ,  B01J35/02 ,  B01J37/08 ,  B01J35/00 ,  C10G2/00 ,  B01J37/18

CPC classification number: B01J27/22 ,  B01J23/78 ,  B01J35/0013 ,  B01J35/002 ,  B01J35/006 ,  B01J35/023 ,  B01J37/0205 ,  B01J37/084 ,  B01J37/18 ,  C07C1/0445 ,  C07C2521/04 ,  C07C2523/745 ,  C10G2/332 ,  Y02P20/52 ,  C07C11/02 ,  C07C11/04 ,  C07C11/06

Abstract: A Fischer-Tropsch catalyst, useful for conversion of synthesis gas to olefins, is prepared from a catalyst precursor composition including iron oxide and an alkali metal on a substantially inert support, and then treated by a process including as ordered steps (1) reduction in a hydrogen-containing atmosphere at a pressure of 0.1 to 1 M Pa and a temperature from 280° C. to 450° C.; (2) carburization in a carbon monoxide-containing atmosphere at a pressure from 0.1 to 1 M Pa and a temperature from 200° C. to less than 340° C.; and (3) conditioning in a hydrogen- and carbon monoxide-containing atmosphere at a pressure from 0.1 to 2 MPa and a temperature from 280° C. to 340° C. The resulting catalyst exhibits at least one improvement selected from (1) increased overall activity; (2) reduced break-in time; (3) slowed rate of deactivation; and (4) increased time to onset of deactivation; when compared to an otherwise identical catalyst precursor composition treated by one or some, but not all, of the given steps and/or under different conditions.

Abstract translation: 用于将合成气转化为烯烃的费 - 托催化剂由包含氧化铁和碱金属的催化剂前体组合物在基本惰性的载体上制备，然后通过包括如下步骤（1）的方法进行处理： 在0.1至1MPa的压力和280℃至450℃的温度下的含氢气氛; （2）在一氧化碳的气氛中在0.1〜1Mpa的压力和200℃〜340℃的温度下进行渗碳。 和（3）在含氢和一氧化碳的气氛中在0.1至2MPa的压力和280℃至340℃的温度下调节。所得催化剂显示出至少一种改进，其选自（1）增加 整体活动; （2）减少入场时间; （3）减速失效率; 和（4）增加失活开始的时间; 当与通过一个或一些但不是全部的给定步骤和/或在不同条件下处理的另外相同的催化剂前体组合物进行比较时。