公开(公告)号：US20170306068A1

公开(公告)日：2017-10-26

申请号：US15526524

申请日：2015-12-11

Applicant: ExxonMobil Research and Engineering Company

Inventor： Matthew W. HOLTCAMP ,  Charles J. HARLAN ,  Quanchang LI ,  Machteld M.W. MERTENS

IPC: C08F210/02 ,  C08F210/06 ,  C08F210/08 ,  C08F210/14

CPC classification number: C08F210/02 ,  B01D15/00 ,  B01D53/02 ,  B01D53/0462 ,  B01D53/047 ,  B01D67/0088 ,  B01D69/10 ,  B01D71/70 ,  B01D2253/20 ,  B01D2253/25 ,  B01D2256/245 ,  B01D2257/302 ,  B01D2257/304 ,  B01D2257/40 ,  B01D2257/504 ,  B01D2257/80 ,  B01J20/0229 ,  B01J20/0237 ,  B01J20/06 ,  B01J20/08 ,  B01J20/10 ,  B01J20/103 ,  B01J20/16 ,  B01J20/18 ,  B01J20/22 ,  B01J20/262 ,  B01J20/264 ,  B01J20/28011 ,  B01J20/28057 ,  B01J20/28061 ,  B01J20/28064 ,  B01J20/28066 ,  B01J20/28069 ,  B01J20/28071 ,  B01J20/28073 ,  B01J20/28076 ,  B01J20/28078 ,  B01J20/28083 ,  B01J20/286 ,  B01J20/3042 ,  B01J20/3204 ,  B01J20/3212 ,  B01J20/3236 ,  B01J20/3238 ,  B01J20/3272 ,  B01J23/44 ,  B01J31/0274 ,  B01J35/1019 ,  B01J35/1023 ,  B01J35/1028 ,  B01J35/1061 ,  B01J37/0213 ,  B01J37/0236 ,  B01J2220/86 ,  C01B37/00 ,  C07F7/0807 ,  C07F7/081 ,  C07F7/0818 ,  C08F4/659 ,  C08F4/65912 ,  C08F4/65916 ,  C08F4/65925 ,  C08F4/65927 ,  C08F210/06 ,  C08F210/08 ,  C08F210/14 ,  C08G77/26 ,  C08G77/60 ,  C10G25/003 ,  C10G31/09 ,  C10G35/06 ,  C10G45/00 ,  C10G45/04 ,  C10G45/34 ,  C10G45/44 ,  C10G45/46 ,  C10G45/52 ,  C10G45/60 ,  C10G45/64 ,  C10G47/02 ,  C10G50/00 ,  C10K1/32 ,  C10M101/02 ,  C23C16/56 ,  C08F4/027 ,  C08F4/64193 ,  C08F4/64189 ,  C08F4/64013 ,  C08F4/64158 ,  C08F4/64048 ,  C08F4/64148 ,  C08F4/64089

Abstract: A catalyst system comprising a combination of: 1) one or more catalyst compounds comprising at least one oxygen linkage, such as a phenoxide transition metal compound; 2) a support comprising an organosilica material, which may be a mesoporous organosilica material; and 3) an optional activator. Useful catalysts include biphenyl phenol catalysts (BPP). The organosilica material may be a polymer of at least one monomer of Formula [Z1OZ2SiCH2]3 (I), where Z1 represents a hydrogen atom, a C1-C4 alkyl group, or a bond to a silicon atom of another monomer and Z2 represents a hydroxyl group, a C1-C4 alkoxy group, a C1-C6 alkyl group, or an oxygen atom bonded to a silicon atom of another monomer. This invention further relates to processes to polymerize olefins comprising contacting one or more olefins with the above catalyst system.

公开(公告)号：US20170320977A1

公开(公告)日：2017-11-09

申请号：US15526512

申请日：2015-12-11

Applicant: ExxonMobil Research and Engineering Company

Inventor： Matthew W. HOLTCAMP ,  Matthew S. BEDOYA ,  Charles J. HARLAN ,  Quanchang LI ,  Machteld M.W. MERTENS

IPC: C08F10/02

CPC classification number: C08F10/02 ,  B01D15/00 ,  B01D53/02 ,  B01D53/0462 ,  B01D53/047 ,  B01D53/228 ,  B01D2253/106 ,  B01D2253/204 ,  B01D2253/306 ,  B01D2253/308 ,  B01D2253/311 ,  B01D2256/245 ,  B01D2257/102 ,  B01D2257/302 ,  B01D2257/304 ,  B01D2257/306 ,  B01D2257/404 ,  B01D2257/504 ,  B01D2257/702 ,  B01D2257/80 ,  B01J20/06 ,  B01J20/08 ,  B01J20/10 ,  B01J20/103 ,  B01J20/264 ,  B01J20/28011 ,  B01J20/28057 ,  B01J20/28069 ,  B01J20/28078 ,  B01J20/286 ,  B01J20/3042 ,  B01J20/3236 ,  B01J20/3238 ,  B01J23/42 ,  B01J23/44 ,  B01J29/0325 ,  B01J31/06 ,  B01J31/125 ,  B01J31/127 ,  B01J35/1019 ,  B01J35/1023 ,  B01J35/1028 ,  B01J35/1038 ,  B01J35/1042 ,  B01J35/1047 ,  B01J35/1057 ,  B01J35/1061 ,  B01J37/036 ,  B01J2220/86 ,  B01J2231/641 ,  B01J2231/646 ,  C01B37/00 ,  C01B39/00 ,  C07F7/00 ,  C08F2/00 ,  C08F2/10 ,  C08F2/42 ,  C08F4/65916 ,  C08F4/65925 ,  C08G77/50 ,  C08G77/58 ,  C08G77/60 ,  C10G25/003 ,  C10G35/06 ,  C10G45/00 ,  C10G45/04 ,  C10G45/34 ,  C10G45/44 ,  C10G45/46 ,  C10G45/60 ,  C10G45/64 ,  C10G47/02 ,  C10G50/00 ,  C10K1/32 ,  C10M101/02 ,  C10M177/00 ,  C10M2203/1006 ,  C10N2270/00

Abstract: A catalyst system comprising a combination of: 1) one or more catalyst compounds comprising at least one nitrogen linkage; 2) a support comprising an organosilica material, which is a mesoporous organosilica material; and 3) an optional activator. Useful catalysts include pyridyldiamido transition metal complexes, HN5 compounds, and bis(imino)pyridyl complexes. The organosilica material is a polymer of at least one monomer of Formula [Z1OZ2SiCH2]3(1), where Z1 represents a hydrogen atom, a C1-C4alkyl group, or a bond to a silicon atom of another monomer and Z2 represents a hydroxyl group, a C1-C4alkoxy group, a C1-C6 alkyl group, or an oxygen atom bonded to a silicon atom of another monomer. This invention further relates to processes to polymerize olefins comprising contacting one or more olefins with the above catalyst system.

公开(公告)号：US20170320971A1

公开(公告)日：2017-11-09

申请号：US15526529

申请日：2015-12-11

Applicant: ExxonMobil Research and Engineering Company

Inventor： Matthew W. HOLTCAMP ,  Matthew S. BEDOYA ,  Charles J. HARLAN ,  Quanchang LI ,  Machteld M.W. MERTENS

IPC: C08F4/659 ,  C08F4/6592 ,  C07F7/00

CPC classification number: C08F10/02 ,  B01D15/00 ,  B01D53/02 ,  B01D53/0462 ,  B01D53/047 ,  B01D53/228 ,  B01D2253/106 ,  B01D2253/204 ,  B01D2253/306 ,  B01D2253/308 ,  B01D2253/311 ,  B01D2256/245 ,  B01D2257/102 ,  B01D2257/302 ,  B01D2257/304 ,  B01D2257/306 ,  B01D2257/404 ,  B01D2257/504 ,  B01D2257/702 ,  B01D2257/80 ,  B01J20/06 ,  B01J20/08 ,  B01J20/10 ,  B01J20/103 ,  B01J20/264 ,  B01J20/28011 ,  B01J20/28057 ,  B01J20/28069 ,  B01J20/28078 ,  B01J20/286 ,  B01J20/3042 ,  B01J20/3236 ,  B01J20/3238 ,  B01J23/42 ,  B01J23/44 ,  B01J29/0325 ,  B01J31/06 ,  B01J31/125 ,  B01J31/127 ,  B01J35/1019 ,  B01J35/1023 ,  B01J35/1028 ,  B01J35/1038 ,  B01J35/1042 ,  B01J35/1047 ,  B01J35/1057 ,  B01J35/1061 ,  B01J37/036 ,  B01J2220/86 ,  B01J2231/641 ,  B01J2231/646 ,  C01B37/00 ,  C01B39/00 ,  C07F7/00 ,  C08F2/00 ,  C08F2/10 ,  C08F2/42 ,  C08F4/65916 ,  C08F4/65925 ,  C08G77/50 ,  C08G77/58 ,  C08G77/60 ,  C10G25/003 ,  C10G35/06 ,  C10G45/00 ,  C10G45/04 ,  C10G45/34 ,  C10G45/44 ,  C10G45/46 ,  C10G45/60 ,  C10G45/64 ,  C10G47/02 ,  C10G50/00 ,  C10K1/32 ,  C10M101/02 ,  C10M177/00 ,  C10M2203/1006 ,  C10N2270/00

Abstract: A catalyst system comprising a combination of: 1) one or more catalyst compounds having at least one nitrogen linkage and at least one oxygen linkage to a transition metal; 2) a support comprising an organosilica material, which is a mesoporous organosilica material; and 3) an optional activator. Useful catalysts include ONNO-type transition metal catalysts, ONYO-Type transition metal catalysts, and/or oxadiazole transition metal catalysts. The organosilica material is a polymer of at least one monomer of Formula [z′0Z2 SiCH2]3(1), where Z1 represents a hydrogen atom, a C1-C4alkyl group, or a bond to a silicon atom of another monomer and Z2 represents a hydroxyl group, a C1-C4alkoxy group, a C1-C6alkyl group, or an oxygen atom bonded to a silicon atom of another monomer. This invention further relates to processes to polymerize olefins comprising contacting one or more olefins with the above catalyst system.