公开(公告)号：US08932454B2

公开(公告)日：2015-01-13

申请号：US13719634

申请日：2012-12-19

Applicant: ExxonMobil Research and Engineering Company

Inventor： Jianxin Jason Wu ,  Ajit B. Dandekar ,  Christopher G. Oliveri

IPC: C10G47/18 ,  C10G47/20 ,  B01J29/16 ,  B01J29/12 ,  B01J37/10 ,  B01J29/08 ,  B01J35/10 ,  C01B39/24 ,  B01J29/14 ,  C01B39/02

CPC classification number: B01J29/126 ,  B01J29/084 ,  B01J29/088 ,  B01J29/146 ,  B01J29/166 ,  B01J35/109 ,  B01J37/10 ,  B01J2229/16 ,  B01J2229/20 ,  B01J2229/22 ,  B01J2229/36 ,  B01J2229/42 ,  C01B39/026 ,  C01B39/24 ,  C10G47/18 ,  C10G47/20

Abstract: This invention relates to the composition, method of making and use of a hydrocracking catalyst that is comprised of a new Y zeolite which exhibits an exceptionally low small mesoporous peak around the 40 Å (angstrom) range as determined by nitrogen adsorption measurements. The hydrocracking catalysts of invention exhibit improved distillate yield and selectivity as well as improved conversions at lower temperatures than conventional hydrocracking catalysts containing Y zeolites. The hydrocracking catalysts herein are particularly useful in the hydrocracking processes as disclosed herein, particularly for conversion of heavy hydrocarbon feedstocks such as gas oils and vacuum tower bottoms and an associated maximization and/or improved selectivity of the distillate yield obtained from such hydrocracking processes.

Abstract translation: 本发明涉及由新型Y沸石组成的加氢裂化催化剂的组合物，制备和使用方法，其通过氮吸附测量测定显示在大约40埃（埃）范围内具有极低的小介孔峰。 本发明的加氢裂化催化剂在比含有Y沸石的常规加氢裂化催化剂更低的温度下显示出提高的馏出物产率和选择性以及改进的转化率。 本文所述的加氢裂化催化剂特别适用于本文公开的加氢裂化方法，特别是用于转化重质烃原料如瓦斯油和真空塔底物，以及相应的最大化和/或从这些加氢裂化方法获得的馏出物产率的选择性提高。

公开(公告)号：US20130130893A1

公开(公告)日：2013-05-23

申请号：US13677564

申请日：2012-11-15

Applicant: ExxonMobil Research and Engineering Company

Inventor： Terry E. Helton ,  Benjamin S. Umansky ,  William J. Tracy, III ,  Stephen J. McCarthy ,  Timothy L. Hilbert ,  Mohan Kalyanaraman ,  Christopher G. Oliveri

IPC: B01J37/20 ,  B01J23/89

CPC classification number: B01J37/20 ,  B01J23/89 ,  B01J23/8993 ,  B01J29/0325 ,  B01J29/0333 ,  B01J29/126 ,  B01J29/143 ,  B01J29/44 ,  B01J29/46 ,  B01J29/67 ,  B01J29/68 ,  B01J29/7415 ,  B01J29/7461 ,  B01J29/7492 ,  B01J29/7615 ,  B01J29/7661 ,  B01J29/7692 ,  B01J29/85 ,  B01J29/90 ,  B01J38/10 ,  B01J38/58 ,  B01J38/74 ,  B01J2229/42 ,  C10G45/10 ,  C10G45/12 ,  C10G65/043 ,  C10G2300/4031 ,  C10G2300/703

Abstract: Methods are provided for liquid phase activation of dewaxing and/or hydrofinishing catalysts that include a molecular sieve or other acidic crystalline support. The methods are compatible with activating the catalysts as part of a catalyst system that also includes a hydrotreating catalyst.

Abstract translation: 提供了用于液相活化脱蜡和/或加氢精制催化剂的方法，其包括分子筛或其它酸性结晶载体。 该方法与催化剂的活化相容，催化剂体系的一部分还包括加氢处理催化剂。

公开(公告)号：US09415385B2

公开(公告)日：2016-08-16

申请号：US13677564

申请日：2012-11-15

Applicant: ExxonMobil Research and Engineering Company

Inventor： Terry E. Helton ,  Benjamin S. Umansky ,  William J. Tracy, III ,  Stephen J. McCarthy ,  Timothy L. Hilbert ,  Mohan Kalyanaraman ,  Christopher G. Oliveri

IPC: B01J37/20 ,  B01J23/89 ,  C10G65/04 ,  C10G45/10 ,  C10G45/12 ,  B01J38/10 ,  B01J38/58 ,  B01J38/74 ,  B01J29/03 ,  B01J29/85 ,  B01J29/90 ,  B01J29/12 ,  B01J29/14 ,  B01J29/44 ,  B01J29/46 ,  B01J29/67 ,  B01J29/68 ,  B01J29/74 ,  B01J29/76

CPC classification number: B01J37/20 ,  B01J23/89 ,  B01J23/8993 ,  B01J29/0325 ,  B01J29/0333 ,  B01J29/126 ,  B01J29/143 ,  B01J29/44 ,  B01J29/46 ,  B01J29/67 ,  B01J29/68 ,  B01J29/7415 ,  B01J29/7461 ,  B01J29/7492 ,  B01J29/7615 ,  B01J29/7661 ,  B01J29/7692 ,  B01J29/85 ,  B01J29/90 ,  B01J38/10 ,  B01J38/58 ,  B01J38/74 ,  B01J2229/42 ,  C10G45/10 ,  C10G45/12 ,  C10G65/043 ,  C10G2300/4031 ,  C10G2300/703

Abstract: Methods are provided for liquid phase activation of dewaxing and/or hydrofinishing catalysts that include a molecular sieve or other acidic crystalline support. The methods are compatible with activating the catalysts as part of a catalyst system that also includes a hydrotreating catalyst.

Abstract translation: 提供了用于液相活化脱蜡和/或加氢精制催化剂的方法，其包括分子筛或其它酸性结晶载体。 该方法与催化剂的活化相容，催化剂体系的一部分还包括加氢处理催化剂。

公开(公告)号：US20130118954A1

公开(公告)日：2013-05-16

申请号：US13719634

申请日：2012-12-19

Applicant: Exxonmobil Research and Engineering Company

Inventor： Jianxin Jason Wu ,  Ajit B. Dandekar ,  Christopher G. Oliveri

IPC: B01J29/12 ,  C10G47/18

CPC classification number: B01J29/126 ,  B01J29/084 ,  B01J29/088 ,  B01J29/146 ,  B01J29/166 ,  B01J35/109 ,  B01J37/10 ,  B01J2229/16 ,  B01J2229/20 ,  B01J2229/22 ,  B01J2229/36 ,  B01J2229/42 ,  C01B39/026 ,  C01B39/24 ,  C10G47/18 ,  C10G47/20

Abstract: This invention relates to the composition, method of making and use of a hydrocracking catalyst that is comprised of a new Y zeolite which exhibits an exceptionally low small mesoporous peak around the 40 Å (angstrom) range as determined by nitrogen adsorption measurements. The hydrocracking catalysts of invention exhibit improved distillate yield and selectivity as well as improved conversions at lower temperatures than conventional hydrocracking catalysts containing Y zeolites. The hydrocracking catalysts herein are particularly useful in the hydrocracking processes as disclosed herein, particularly for conversion of heavy hydrocarbon feedstocks such as gas oils and vacuum tower bottoms and an associated maximization and/or improved selectivity of the distillate yield obtained from such hydrocracking processes.

Abstract translation: 本发明涉及由新型Y沸石组成的加氢裂化催化剂的组合物，制备和使用方法，其通过氮吸附测量测定显示在大约40埃（埃）范围内具有极低的小介孔峰。 本发明的加氢裂化催化剂在比含有Y沸石的常规加氢裂化催化剂更低的温度下显示出提高的馏出物产率和选择性以及改进的转化率。 本文所述的加氢裂化催化剂特别适用于本文公开的加氢裂化方法，特别是用于转化重质烃原料如瓦斯油和真空塔底物，以及相应的最大化和/或从这些加氢裂化方法获得的馏出物产率的选择性提高。