公开(公告)号：US20140275650A1

公开(公告)日：2014-09-18

申请号：US14203714

申请日：2014-03-11

Applicant: HONEYWELL INTERNATIONAL INC.

Inventor： Haluk KOPKALLI ,  Haiyou WANG ,  Hsueh SUNG TUNG ,  Daniel C. MERKEL

IPC: C07C17/20 ,  C07C17/42

CPC classification number: C09K15/30 ,  C07C17/087 ,  C07C17/202 ,  C07C17/206 ,  C07C17/25 ,  C07C17/42 ,  C07C21/04 ,  C07C19/10

Abstract: The present invention relates in part to a method of stabilizing chloropropenes, such as 1,1,2,3-tetrachloropropene, otherwise known to decompose and degrade, and to the resulting stabilized chloropropene, using a morpholine compound and/or a trialkyl phosphate compound as defined herein. Such stabilized chloropropenes are useful in the manufacture of hydrofluoroolefins such as 2,3,3,3-tetrafluoroprop-1-ene (1234yf).

Abstract translation: 本发明部分地涉及使用吗啉化合物和/或三烷基磷酸酯化合物稳定氯丙烯如1,1,2,3-四氯丙烯或另外已知分解和降解的方法和所得稳定的氯丙烯的方法 如本文所定义。 这种稳定的氯丙烯可用于制备氢氟烯烃，例如2,3,3,3-四氟丙-1-烯（1234yf）。

公开(公告)号：US20130225881A1

公开(公告)日：2013-08-29

申请号：US13863670

申请日：2013-04-16

Applicant: HONEYWELL INTERNATIONAL INC.

Inventor： George R. COOK ,  Haluk KOPKALLI ,  Stephen A. COTTRELL ,  Yuon CHIU ,  Peter SCHEIDLE ,  Daniel C. MERKEL

IPC: C07C17/23

CPC classification number: C07C17/23 ,  C07C17/25 ,  C07C21/18

Abstract: A process for the manufacture of halogenated olefins in semi-batch mode by dehydrohalogenation of halogenated alkanes in the presence of an aqueous base such as KOH which simultaneously neutralizes the resulting hydrogen halide. During the process, aqueous base is continuously added to the haloalkane which results in better yields, lower by-product formation and safer/more controllable operation.

Abstract translation: 一种通过卤化烷烃在碱性水溶液（如KOH）的存在下脱卤化氢同时中和所得卤化氢，以半间歇模式制造卤代烯烃的方法。 在此过程中，将水性碱连续加入到卤代烷烃中，产生更好的产率，更低的副产物形成和更安全/更可控的操作。

公开(公告)号：US20180318788A1

公开(公告)日：2018-11-08

申请号：US15773769

申请日：2016-11-04

Applicant: HONEYWELL INTERNATIONAL INC.

Inventor： Richard Durick HORWATH ,  Yuon CHIU ,  Haluk KOPKALLI ,  Robert A. SMITH ,  Haiyou WANG ,  Michael GATTER ,  Hsueh Sung TUNG ,  Daniel C. MERKEL

IPC: B01J20/10 ,  B01J20/20 ,  B01J20/18 ,  C02F1/28

CPC classification number: B01J20/103 ,  B01J20/18 ,  B01J20/20 ,  B01J20/3408 ,  B01J20/3416 ,  B01J20/3458 ,  B01J2220/42 ,  C02F1/281 ,  C02F1/283 ,  C02F2101/14 ,  C02F2101/36

Abstract: Disclosed is a process to separate halogenated organic contaminants such as 2-chloro-3,3,3-trifluoropropene (HCFO-1233xf), 2,3,3,3-tetrafluoropropene (HFO-1234yf), trifluoropropyne (TFPY) from hydrochloric acid (HCl) with an adsorbent selected from an activated carbon, an MFI molecular sieve, a carbon molecular sieve, silica, and combinations thereof.

公开(公告)号：US20170253545A1

公开(公告)日：2017-09-07

申请号：US15464461

申请日：2017-03-21

Applicant: HONEYWELL INTERNATIONAL INC.

Inventor： Selma BEKTESEVIC ,  Daniel C. MERKEL ,  Mario Joseph NAPPA ,  Xuehui SUN ,  Hsueh Sung TUNG ,  Haiyou WANG

IPC: C07C17/42 ,  C07C21/18 ,  C07C17/25 ,  C07C19/10 ,  C07C17/087 ,  C07C17/20

CPC classification number: C07C17/42 ,  C07C17/087 ,  C07C17/206 ,  C07C17/25 ,  C07C19/10 ,  C07C21/18

Abstract: The present invention relates, in part, to the discovery that, during the fluorination of certain fluoroolefm starting reagents, particularly, 1,1,2,3-tetrachloropropene (1230xa), oligomerization/polymerization of such starting reagents reduces the conversion process and leads to increased catalyst deactivation. The present invention also illustrates that providing one or more organic co-feed to the fluooolefin starting stream reduces such oligomerization/polymerization and improves catalystic stability.

公开(公告)号：US20170113987A1

公开(公告)日：2017-04-27

申请号：US15038254

申请日：2016-04-22

Applicant: HONEYWELL INTERNATIONAL INC

Inventor： Haiyou WANG ,  Daniel C. MERKEL ,  Hsueh Sung TUNG ,  Michael GATTER

IPC: C07C17/389

CPC classification number: C07C17/389 ,  C07C17/087 ,  C07C17/25 ,  C07C19/10 ,  C07C21/18

Abstract: The present disclosure provides a method for separating 244bb from 1233xf by using solid adsorbent selected from molecular sieves having an average pore size of 5A or greater.

公开(公告)号：US20150225315A1

公开(公告)日：2015-08-13

申请号：US14618450

申请日：2015-02-10

Applicant: HONEYWELL INTERNATIONAL INC.

Inventor： Haluk KOPKALLI ,  Yuon CHIU ,  Daniel C. MERKEL ,  Ron Joseph ROOF ,  Robert A. SMITH ,  Austin V. PRANKE

IPC: C07C17/087 ,  B01J19/24 ,  B01J19/18 ,  C07C17/25

CPC classification number: C07C17/087 ,  B01F7/00041 ,  B01F15/00837 ,  B01F2015/00097 ,  B01J4/001 ,  B01J8/22 ,  B01J10/00 ,  B01J12/00 ,  B01J19/006 ,  B01J19/0066 ,  B01J19/02 ,  B01J19/18 ,  B01J19/248 ,  B01J2208/00212 ,  B01J2219/00094 ,  B01J2219/00768 ,  B01J2219/0218 ,  B01J2219/0245 ,  B01J2219/2404 ,  B01J2219/2406 ,  B01J2219/2408 ,  B01J2219/2419 ,  B01J2219/2481 ,  B01J2219/2487 ,  C07C17/206 ,  C07C17/25 ,  C07C19/10 ,  C07C21/18

Abstract: A reactor apparatus is provided having a reaction chamber; a compartmentalizing apparatus including a plurality of compartments, each compartment being open at a top end and bottom end, the compartmentalizing apparatus being disposed within the reaction chamber; and an inlet disposed at an area of the reactor and in fluid communication between the reaction chamber and a feed source. Also provided is a reactor apparatus having an assembly having a reaction chamber; at least one agitator assembly configured to generate mixing within the reaction chamber, the agitator assembly including: a shaft partially lined or coated with a fluoropolymer or other non-metallic corrosion-resistant material, and an impeller lined or coated with the fluoropolymer or other non-metallic corrosion-resistant material; and an inlet disposed at an area of the reactor and in fluid communication between the reaction chamber and a feed source. The provided reactor apparatus can be utilized in hydrofluorination processes.

Abstract translation: 提供具有反应室的反应器装置; 一个分隔设备，包括多个隔间，每个隔室在顶端和底端开口，隔间设备设置在反应室内; 以及设置在反应器的区域并且在反应室和进料源之间流体连通的入口。 还提供了具有具有反应室的组件的反应器装置; 至少一个搅拌器组件被配置为在反应室内产生混合，所述搅拌器组件包括：轴部分地衬有或涂覆有氟聚合物或其它非金属耐腐蚀材料的轴，以及内衬或涂覆有氟聚合物或其它非 - 金属耐腐蚀材料; 以及设置在反应器的区域并且在反应室和进料源之间流体连通的入口。 提供的反应器装置可用于氢氟化方法。

公开(公告)号：US20150034523A1

公开(公告)日：2015-02-05

申请号：US14456514

申请日：2014-08-11

Applicant: HONEYWELL INTERNATIONAL INC.

Inventor： Haluk KOPKALLI ,  Haiyou WANG ,  Hsueh SUNG TUNG ,  Daniel C. MERKEL

IPC: C09K15/30

CPC classification number: C09K15/30 ,  C07C17/087 ,  C07C17/202 ,  C07C17/206 ,  C07C17/25 ,  C07C17/42 ,  C07C21/04 ,  C07C19/10

Abstract: The present invention relates in part to a container for stabilized chloropropenes, such as 1,1,2,3-tetrachloropropene, otherwise known to decompose and degrade, and to the resulting stabilized chloropropene, using a morpholine compound and/or a trialkyl phosphate compound as defined herein. Such stabilized chloropropenes are useful in the manufacture of hydrofluoroolefins such as 2,3,3,3-tetrafluoroprop-1-ene (1234yf).

Abstract translation: 本发明部分地涉及使用吗啉化合物和/或三烷基磷酸酯化合物的用于稳定的氯丙烯的容器，例如已知分解和降解的1,1,2,3-四氯丙烯和所得稳定的氯丙烯 如本文所定义。 这种稳定的氯丙烯可用于制备氢氟烯烃，例如2,3,3,3-四氟丙-1-烯（1234yf）。

公开(公告)号：US20210188744A1

公开(公告)日：2021-06-24

申请号：US16757825

申请日：2018-10-25

Applicant: HONEYWELL INTERNATIONAL INC.

Inventor： Christian JUNGONG ,  Daniel C. MERKEL

IPC: C07C17/358 ,  C07C17/383 ,  C07C17/25

Abstract: A method for conversion of a composition containing HCFO-1233zd(Z) and HCFC-244fa to form HCFO-1233zd(E) by reacting a mixture including HCFO-1233zd(Z) and HCFC-244fa in a vapor phase in the presence of a catalyst to simultaneously isomerize HCFO-1233zd(Z) to form HCFO-1233zd(E) and dehydrohalogenate HCFC-244fa to form HCFO-1233zd(E). The catalyst may be a chromium-based catalyst such as chromium trifluoride, chromium oxyfluoride, or chromium oxide, for example.

公开(公告)号：US20190084906A1

公开(公告)日：2019-03-21

申请号：US16196746

申请日：2018-11-20

Applicant: HONEYWELL INTERNATIONAL INC.

Inventor： Haiyou WANG ,  Hsueh Sung TUNG ,  Selma BEKTESEVIC ,  Daniel C. MERKEL ,  Haluk KOPKALLI ,  Yuon CHIU

IPC: C07C17/20 ,  C07C17/087 ,  C07C17/42 ,  C07C17/25 ,  B01J27/12 ,  B01J23/26 ,  B01J27/138 ,  B01J21/04 ,  B01J23/34 ,  B01J23/745 ,  B01J23/755 ,  B01J27/10 ,  B01J23/75

Abstract: The present invention relates, in part, to the discovery that, during the fluorination of certain fluoroolefin starting reagents, oligomerization/polymerization of such reagents reduces the conversion process and leads to increased catalyst deactivation. The present invention also illustrates that vaporizing such starting reagents in the presence of one or more organic co-feed reduces such oligomerization/polymerization and improves catalytic stability.

公开(公告)号：US20170313639A1

公开(公告)日：2017-11-02

申请号：US15654907

申请日：2017-07-20

Applicant: HONEYWELL INTERNATIONAL INC.

Inventor： Haiyou WANG ,  Selma BEKTESEVIC ,  Daniel C. MERKEL ,  Hsueh SUNG TUNG ,  Konstantin A. POKROVSKI

IPC: C07C17/20 ,  C07C17/386 ,  C07C17/087 ,  C07C17/38 ,  C07C19/10 ,  C07C21/18 ,  C07C17/25 ,  C07C21/04 ,  C07C19/01 ,  C07C19/08

CPC classification number: C07C17/206 ,  C07C17/087 ,  C07C17/25 ,  C07C17/38 ,  C07C17/386 ,  C07C19/01 ,  C07C19/08 ,  C07C19/10 ,  C07C21/04 ,  C07C21/18 ,  Y02P20/125 ,  Y02P20/582

Abstract: The invention relates to a separation process whereby 2-chloro-3,3,3-trifluoropropene (1233xf) is separated from a mixture containing other fluorinated organics and high boiling materials such as dimers using azeotropes of HF formed by adding appropriate amounts to the mixture which facilitate separation by, e.g. distillation.