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    Chemical synthesis of chiral conducting polymers
    3.
    发明授权
    Chemical synthesis of chiral conducting polymers 失效
    手性导电聚合物的化学合成

    公开(公告)号：US07074887B2

    公开(公告)日：2006-07-11

    申请号：US10321155

    申请日：2002-12-17

    Applicant: Hsing-Lin Wang ,  Wenguang Li

    Inventor： Hsing-Lin Wang ,  Wenguang Li

    IPC: C08G73/00

    CPC classification number: C08G73/0266 ,  C08L79/02

    Abstract: An process of forming a chiral conducting polymer, e.g., polyaniline, is provided including reacting a monomer, e.g., an aniline monomer, in the presence of a chiral dopant acid to produce a first reaction mixture by addition of a solution including a first portion of an oxidizing agent, the first portion of oxidizing agent characterized as insufficient to allow complete reaction of the monomer, and further reacting the first reaction mixture in the presence of the chiral dopant acid by addition of a solution including a second portion of the oxidizing agent, the second portion of oxidizing agent characterized as insufficient to allow complete reaction of the monomer, and repeating the reaction by addition of further portions of the oxidizing agent until the monomer reaction is complete to produce a chiral conducting polymer, e.g., polyaniline. A preferred process includes addition of a catalyst during the reaction, the catalyst selected from among the group consisting of phenylene diamine, aniline oligomers and amino-capped aniline oligomers and metal salts.The processes of the present invention further provide a resultant polyaniline product having a chirality level defined by a molar ellipticity of from about 40×103 degree-cm2/decimole to about 700×103 degree-cm2/decimole. The processes of the present invention further provide a resultant polyaniline product having a nanofiber structure with a diameter of from about 30 nanometers to about 120 nanometers and from about 1 micron to about 5 microns in length.

    Abstract translation: 提供形成手性导电聚合物例如聚苯胺的方法，包括在手性掺杂剂酸的存在下使单体（例如苯胺单体）反应以通过加入包含第一部分的溶液的溶液产生第一反应混合物 氧化剂的第一部分，其特征在于不足以使单体完全反应，并且在手性掺杂剂酸的存在下，通过加入包含第二部分氧化剂的溶液进一步使第一反应混合物反应， 第二部分氧化剂的特征在于不足以使单体完全反应，并且通过加入另外部分的氧化剂重复反应，直到单体反应完成以产生手性导电聚合物，例如聚苯胺。 优选的方法包括在反应期间加入催化剂，所述催化剂选自苯二胺，苯胺低聚物和氨基封端的苯胺低聚物和金属盐。 本发明的方法进一步提供了所得的聚苯胺产物，其具有由摩尔椭圆度约为40×10 -3 cm -2 / 10mM至约700×10 3 / SUP> 3 本发明的方法还提供了具有直径为约30纳米至约120纳米且约1微米至约5微米长度的纳米纤维结构的所得聚苯胺产品。

    Catalytic synthesis of metal crystals using conductive polymers
    6.
    发明申请
    Catalytic synthesis of metal crystals using conductive polymers 失效
    使用导电聚合物催化合成金属晶体

    公开(公告)号：US20060231805A1

    公开(公告)日：2006-10-19

    申请号：US11110343

    申请日：2005-04-19

    Applicant: Hsing-Lin Wang ,  Wenguang Li

    Inventor： Hsing-Lin Wang ,  Wenguang Li

    IPC: H01B1/12

    CPC classification number: H01B1/125 ,  B01J13/00 ,  B22F1/0022 ,  B22F9/24 ,  B82Y30/00 ,  H01B1/127 ,  H01B1/128

    Abstract: A method of forming metal nanoparticles using a polymer colloid that includes at least one conductive polymer and at least one polyelectrolyte. Metal ions are reduced in water by the conductive polymer to produce the nanoparticles, which may be then incorporated in the colloidal structure to form a colloid composite. The method can also be used to separate selected metal ions from aqueous solutions.

    Abstract translation: 使用包含至少一种导电聚合物和至少一种聚电解质的聚合物胶体形成金属纳米颗粒的方法。 金属离子在水中被导电聚合物还原以产生纳米颗粒，然后将其纳入胶体结构以形成胶体复合物。 该方法也可用于从水溶液中分离所选择的金属离子。

    Method for preparing polyaniline fibers
    7.
    发明授权
    Method for preparing polyaniline fibers 失效
    聚苯胺纤维的制备方法

    公开(公告)号：US06123883A

    公开(公告)日：2000-09-26

    申请号：US334719

    申请日：1999-06-16

    Applicant: Benjamin R. Mattes ,  Hsing-Lin Wang

    Inventor： Benjamin R. Mattes ,  Hsing-Lin Wang

    IPC: C08J5/18 ,  C08G73/00 ,  C08G73/02 ,  D01F6/26 ,  D01F6/76 ,  H01B1/12 ,  D01D5/06 ,  D01F1/09 ,  D01F6/96

    CPC classification number: C08G73/0266 ,  D01F6/76 ,  H01B1/128

    Abstract: Stable, concentrated solutions of high molecular weight polyaniline. In order to process high quality fibers and other articles possessing good mechanical properties, it is known that solution concentrations of the chosen polymer should be in the range from 15-30% (w/w). Moreover, it is desirable to use the highest molecular weight consistent with the solubility properties of the polymer. However, such solutions are inherently unstable, forming gels before processing can be achieved. The present invention describes the addition gel inhibitors (GIs) to the polymer solution, thereby permitting high concentrations (>15% (w/w)) of high molecular weight ((M.sub.w)>120,000, and (M.sub.n)>30,000) emeraldine base (EB) polyaniline to be dissolved. Secondary amines have been used for this purpose in concentrations which are small compared to those which might otherwise be used in a cosolvent role therefor. The resulting solutions are useful for generating excellent fibers, films, coatings and other objects, since the solutions are stable for significant time periods, and the GIs are present in too small concentrations to cause polymer deterioration. It is demonstrated that the GIs found to be useful do not act as cosolvents, and that gelation times of the solutions are directly proportional to the concentration of GI. In particular, there is a preferred concentration of GI, which if exceeded causes structural and electrical conductivity degradation of resulting articles. Heating of the solutions significantly improves solubility.

    Abstract translation: 稳定的高分子量聚苯胺浓缩溶液。 为了处理具有良好机械性能的高品质纤维和其它制品，已知所选聚合物的溶液浓度应在15-30％（w / w）的范围内。 此外，期望使用与聚合物的溶解性质一致的最高分子量。 然而，这种溶液固有地不稳定，可以在加工前形成凝胶。 本发明描述了对聚合物溶液的加成凝胶抑制剂（GI），从而允许高分子量（（Mw）> 120,000和（Mn）> 30,000）翠绿亚胺碱的高浓度（> 15％（w / w） （EB）聚苯胺溶解。 为了这个目的已经使用了仲胺，其浓度与可能用于其共溶剂作用的那些相比，其用量较小。 所得到的溶液可用于产生优异的纤维，膜，涂层和其它物体，因为溶液在相当长的时间内是稳定的，并且GI以太小的浓度存在以引起聚合物劣化。 证明发现有用的GI不能作为共溶剂，溶液的凝胶化时间与GI的浓度成正比。 特别地，存在优选的GI浓度，如果超过，则导致所得制品的结构和电导率降低。 溶液的加热显着提高了溶解度。

    Stable, concentrated solutions of high molecular weight polyaniline and articles therefrom
    8.
    发明授权
    Stable, concentrated solutions of high molecular weight polyaniline and articles therefrom 失效
    稳定的高分子量聚苯胺浓缩溶液及其制品

    公开(公告)号：US5981695A

    公开(公告)日：1999-11-09

    申请号：US926338

    申请日：1997-09-05

    Applicant: Benjamin R. Mattes ,  Hsing-Lin Wang

    Inventor： Benjamin R. Mattes ,  Hsing-Lin Wang

    IPC: C08J5/18 ,  C08G73/00 ,  C08G73/02 ,  D01F6/26 ,  D01F6/76 ,  H01B1/12 ,  C08J3/00

    CPC classification number: C08G73/0266 ,  D01F6/76 ,  H01B1/128

    Abstract: Stable, concentrated solutions of high molecular weight polyaniline. In order to process high quality fibers and other articles possessing good mechanical properties, it is known that solution concentrations of the chosen polymer should be in the range from 15-30% (w/w). Moreover, it is desirable to use the highest molecular weight consistent with the solubility properties of the polymer. However, such solutions are inherently unstable, forming gels before processing can be achieved. The present invention describes the addition gel inhibitors (GIs) to the polymer solution, thereby permitting high concentrations (between 15% and 30% (w/w)) of high molecular weight ((M.sub.w)>120,000, and (M.sub.n)>30,000) emeraldine base (EB) polyaniline to be dissolved. Secondary amines have been used for this purpose in concentrations which are small compared to those which might otherwise be used in a cosolvent role therefor. The resulting solutions are useful for generating excellent fibers, films, coatings and other objects, since the solutions are stable for significant time periods, and the GIs are present in too small concentrations to cause polymer deterioration. It is demonstrated that the GIs found to be useful do not act as cosolvents, and that gelation times of the solutions are directly proportional to the concentration of GI. In particular, there is a preferred concentration of GI, which if exceeded causes structural and electrical conductivity degradation of resulting articles. Heating of the solutions significantly improves solubility.

    Abstract translation: 稳定的高分子量聚苯胺浓缩溶液。 为了处理具有良好机械性能的高质量纤维和其它制品，已知所选聚合物的溶液浓度应在15-30％（w / w）的范围内。 此外，期望使用与聚合物的溶解性质一致的最高分子量。 然而，这种溶液固有地不稳定，可以在加工前形成凝胶。 本发明描述了对聚合物溶液的添加凝胶抑制剂（GI），从而允许高分子量（（Mw）> 120,000和（Mn）> 30,000的高浓度（15％至30％（w / w） ）翠绿碱（EB）聚苯胺溶解。 为了这个目的已经使用了仲胺，其浓度与可能用于其共溶剂作用的那些相比，其用量较小。 所得到的溶液可用于产生优异的纤维，膜，涂层和其它物体，因为溶液在相当长的时间内是稳定的，并且GI以太小的浓度存在以引起聚合物劣化。 证明发现有用的GI不能作为共溶剂，溶液的凝胶化时间与GI的浓度成正比。 特别地，存在优选的GI浓度，如果超过，则导致所得制品的结构和电导率降低。 溶液的加热显着提高了溶解度。

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