公开(公告)号：US09737883B2

公开(公告)日：2017-08-22

申请号：US14349105

申请日：2012-10-22

Applicant: JGC CATALYSTS AND CHEMICALS LTD.

Inventor： Kenji Yamane ,  Kouichi Ohama ,  Shogo Tagawa

IPC: B01J27/16 ,  B01J27/19 ,  B01J31/12 ,  B01J35/10 ,  C10G45/04 ,  B01J37/02 ,  B01J37/03 ,  B01J37/28

CPC classification number: B01J27/19 ,  B01J27/16 ,  B01J31/121 ,  B01J35/1019 ,  B01J35/1042 ,  B01J35/1047 ,  B01J35/1061 ,  B01J35/1085 ,  B01J35/109 ,  B01J37/0203 ,  B01J37/024 ,  B01J37/033 ,  B01J37/28 ,  C10G45/04 ,  C10G2300/201

Abstract: A hydrotreating catalyst includes a hydrogenation active metal supported on a alumina-phosphorus support and satisfies: a specific surface area being 100 m2/g or more; a total pore volume measured by mercury intrusion being in a range 0.80-1.50 ml/g; a maximum value of pore distribution being present in a pore diameter range 10-30 nm; a ratio of a pore volume of pores with a pore diameter within a range of ±2 nm of a pore diameter at the maximum value to a pore volume of pores with a pore diameter in a range 5-100 nm being 0.40 or less; a pressure capacity being 10 N/mm or more; 0.4-10.0 mass % of phosphorus being contained in the catalyst in terms of P2O5 concentration based on a total amount of the catalyst; and a hydrogenation active metal being at least one metal selected from metals of VIA and VIII groups of the periodic table.

公开(公告)号：US20140243192A1

公开(公告)日：2014-08-28

申请号：US14349105

申请日：2012-10-22

Applicant: JGC CATALYSTS AND CHEMICALS LTD.

Inventor： Kenji Yamane ,  Kouichi Ohama ,  Shogo Tagawa

IPC: B01J27/19

CPC classification number: B01J27/19 ,  B01J27/16 ,  B01J31/121 ,  B01J35/1019 ,  B01J35/1042 ,  B01J35/1047 ,  B01J35/1061 ,  B01J35/1085 ,  B01J35/109 ,  B01J37/0203 ,  B01J37/024 ,  B01J37/033 ,  B01J37/28 ,  C10G45/04 ,  C10G2300/201

Abstract: A hydrotreating catalyst includes a hydrogenation active metal supported on a alumina-phosphorus support and satisfies: a specific surface area being 100 m2/g or more; a total pore volume measured by mercury intrusion being in a range 0.80-1.50 ml/g; a maximum value of pore distribution being present in a pore diameter range 10-30 nm; a ratio of a pore volume of pores with a pore diameter within a range of ±2 nm of a pore diameter at the maximum value to a pore volume of pores with a pore diameter in a range 5-100 nm being 0.40 or less; a pressure capacity being 10 N/mm or more; 0.4-10.0 mass % of phosphorus being contained in the catalyst in terms of P2O5 concentration based on a total amount of the catalyst; and a hydrogenation active metal being at least one metal selected from metals of VIA and VIII groups of the periodic table.

Abstract translation: 加氢处理催化剂包括负载在氧化铝 - 磷载体上的氢化活性金属，并且满足：比表面积为100m 2 / g以上; 通过水银侵入测量的总孔体积在0.80-1.50ml / g的范围内; 孔分布的最大值存在于10-30nm的孔径范围内; 孔直径在最大值的孔径±2nm范围内的孔的孔体积与孔径在5-100nm范围内的孔的孔体积的比为0.40以下; 压力容量为10N / mm以上; 以催化剂总量计，P2O5浓度中催化剂中含有0.4-10.0质量％的磷; 和加氢活性金属是选自元素周期表的VIA和VIII族金属中的至少一种金属。