公开(公告)号：US4362770A

公开(公告)日：1982-12-07

申请号：US250442

申请日：1981-04-02

Applicant: John Mathai ,  Larry J. Morrison

Inventor： John Mathai ,  Larry J. Morrison

IPC: B05D7/02 ,  B05D7/16 ,  C09D133/06 ,  B05D1/36 ,  B05D7/00

CPC classification number: C09D133/064 ,  B05D2201/00 ,  B05D2202/00 ,  B05D7/544

Abstract: Disclosed is a primer-surfacer composition comprising a vehicle of a balanced acrylic polymer of methyl methacrylate, butyl methacrylate and methacrylic acid, the resultant polymer having an acid value in the range of about 25 to 35, the polymer having a relative viscosity of about 16 to 32 poise measured at 40% polymer solids in a toluene and isopropyl alcohol solvent at 25.degree. C. The primer-surfacer may also contain dispersed pigments and/or fillers such as carbon blacks, talc, iron oxide, clay, etc. The primer-surfacer composition is primarily used over unprimed, primed or previously finished metal or plastic substrates to provide a surface to which an acrylic lacquer, an acrylic enamel, an alkyd enamel or a polyurethane enamel coating can be applied. The primer-surfacer of this invention may be easily sanded to provide a finish for vehicles of excellent intercoat adhesion, excellent chip and corrosion resistance and excellent fill.

Abstract translation: 本发明公开了一种底漆 - 前体组合物，其包含甲基丙烯酸甲酯，甲基丙烯酸丁酯和甲基丙烯酸的平衡丙烯酸聚合物的载体，所得聚合物的酸值在约25至35的范围内，所述聚合物的相对粘度为约16 在40℃下在甲苯和异丙醇溶剂中以40％聚合物固体测量至32泊。引物 - 二氧化物还可以含有分散的颜料和/或填料，例如炭黑，滑石，氧化铁，粘土等。 主要用于未涂层的，底漆的或先前成品的金属或塑料基材，以提供可以施用丙烯酸漆，丙烯酸搪瓷，醇酸搪瓷或聚氨酯搪瓷涂层的表面。 本发明的底漆二面漆可以容易地打磨，以提供优异的涂层间附着力，优异的切屑和耐腐蚀性以及优异的填充性的车辆的表面处理。

公开(公告)号：US4101527A

公开(公告)日：1978-07-18

申请号：US770245

申请日：1977-02-18

Applicant: Arthur L. Cunningham ,  John Mathai

Inventor： Arthur L. Cunningham ,  John Mathai

IPC: C08G18/32 ,  C08G18/38 ,  C08G18/62 ,  C08G18/00

CPC classification number: C08G18/6283 ,  C08G18/3296 ,  C08G18/3844

Abstract: Polymer forming reactions have been previously known comprising five and six member oxazoline ring oxazolidines and reaction products containing the basic structure with polyfunctional aromatic and aliphatic isocyanates and moisture. Five types of oxazolidines have been previously illustrated. Use of these polymeric products have been found to be limited as the class of oxazolidines described in the prior art result in objectionable dark colored products. This invention relates to an advance thereover in providing light colored end products by use of a novel and specific dioxazabicyclo octanes, a substituted specialized class of oxazolidine ring compounds.

Abstract translation: 先前已知聚合物形成反应包括五种和六种恶唑啉环恶唑烷和含有多官能芳族和脂族异氰酸酯和水分的碱性结构的反应产物。 以前已经说明了五种恶唑烷类。 发现使用这些聚合物产品受到限制，因为现有技术中描述的恶唑烷类产生不良的深色产品。 本发明涉及通过使用新的和特定的二氮杂双环辛烷，取代的特殊类别的恶唑烷环化合物提供浅色终产物的方法。

公开(公告)号：US5248717A

公开(公告)日：1993-09-28

申请号：US815658

申请日：1991-12-31

Applicant: John Mathai

Inventor： John Mathai

IPC: C07C69/56

CPC classification number: C07C69/56

Abstract: This invention relates to novel hydroxy-functional polyester diluents, and more particularly, to acrylic-modified hydroxy-functional polyester reactive diluents useful for blending with a variety of thermosetting or thermoplastic film-forming polymers. More specifically, the hydroxy-functional polyester reactive diluents are essentially low molecular weight polyesters derived from triols, and a combination of unsaturated monocarboxylic acids and saturated monocarboxylic acids. These hydroxy-functional polyester diluents may be copolymerized with one or more acrylic monomers, i.e. hydroxy-functional acrylic monomers, and blended with a variety of thermosetting or thermoplastic film-forming polymers. These blends of the film-forming polymers and the hydroxy-functional polyester diluents can be crosslinked with conventional crosslinking agents such as isocyanates and used in the formulation of low VOC paint compositions particularly useful as automotive topcoats.

Abstract translation: 本发明涉及新的羟基官能聚酯稀释剂，更具体地说，涉及可用于与各种热固性或热塑性成膜聚合物共混的丙烯酸改性的羟基官能聚酯反应性稀释剂。 更具体地，羟基官能聚酯反应性稀释剂基本上是衍生自三醇的低分子量聚酯，以及不饱和一元羧酸和饱和一元羧酸的组合。 这些羟基官能的聚酯稀释剂可以与一种或多种丙烯酸单体即羟基官能的丙烯酸单体共聚，并与各种热固性或热塑性成膜聚合物共混。 成膜聚合物和羟基官能的聚酯稀释剂的这些共混物可以用常规的交联剂如异氰酸酯进行交联，并用于特别用作汽车面漆的低VOC涂料组合物的配方中。

公开(公告)号：US5004828A

公开(公告)日：1991-04-02

申请号：US043051

申请日：1987-04-27

Applicant: John Mathai

Inventor： John Mathai

IPC: C07C69/56

CPC classification number: C07C69/56

Abstract: This invention relates to novel hydroxy-functional polyester diluents, and more particularly, to acrylic-modified hydroxy-functional polyester reactive diluents useful for blending with a variety of thermosetting or thermoplastic film-forming polymers. More specifically, the hydroxy-functional polyester reactive diluents are essentially low molecular weight polyesters derived from triols, and a combination of unsaturated monocarboxylic acids and saturated monocarboxylic acids. These hydroxy-functional polyester diluents may be compolymerized with one or more acrylic monomers, i.e. hydroxy-functional acrylic monomers, and blended with a variety of thermosetting or thermoplastic film-forming polymers. These blends of the film-forming polymers and the hydroxy-functional polyester diluents can be crosslinked with conventional crosslinking agents as isocyanates and used in the formulation of low VOC paint compositions particularly useful as automotive topcoats.

Abstract translation: 本发明涉及新的羟基官能聚酯稀释剂，更具体地说，涉及可用于与各种热固性或热塑性成膜聚合物共混的丙烯酸改性的羟基官能聚酯反应性稀释剂。 更具体地，羟基官能聚酯反应性稀释剂基本上是衍生自三醇的低分子量聚酯，以及不饱和一元羧酸和饱和一元羧酸的组合。 这些羟基官能的聚酯稀释剂可以与一种或多种丙烯酸单体（即羟基官能的丙烯酸单体）共聚，并与各种热固性或热塑性成膜聚合物共混。 成膜聚合物和羟基官能聚酯稀释剂的这些共混物可以用作为异氰酸酯的常规交联剂进行交联，并用于特别用作汽车面漆的低VOC涂料组合物的配方中。

公开(公告)号：US5399611A

公开(公告)日：1995-03-21

申请号：US127205

申请日：1993-09-27

Applicant: John Mathai

Inventor： John Mathai

IPC: C07C69/56 ,  C08J3/00 ,  C08K3/00 ,  C08K5/00

CPC classification number: C07C69/56

Abstract: This invention relates to novel hydroxy-functional polyester diluents, and more particularly, to acrylic-modified hydroxy-functional polyester reactive diluents useful for blending with a variety of thermosetting or thermoplastic film-forming polymers. More specifically, the hydroxy-functional polyester reactive diluents are essentially low molecular weight polyesters derived from triols, and a combination of unsaturated monocarboxylic acids and saturated monocarboxylic acids. These hydroxy-functional polyester diluents may be copolymerized with one or more acrylic monomers, i.e. hydroxy-functional acrylic monomers, and blended with a variety of thermosetting or thermoplastic film-forming polymers. These blends of the film-forming polymers and the hydroxy-functional polyester diluents can be crosslinked with conventional crosslinking agents such as isocyanates and used in the formulation of low VOC paint compositions particularly useful as automotive topcoats.

公开(公告)号：US5104955A

公开(公告)日：1992-04-14

申请号：US286431

申请日：1988-12-19

Applicant: John Mathai

Inventor： John Mathai

IPC: C07C69/56

CPC classification number: C07C69/56

Abstract: This invention relates to novel hydroxy-functional polyester diluents, and more particularly, to acrylic-modified hydroxy-functional polyester reactive diluents useful for blending with a variety of thermosetting or thermoplastic film-forming polymers. More specifically, the hydroxy-functional polyester reactive diluents are essentially low molecular weight polyesters derived from triols, and a combination of unsaturated monocarboxylic acids and saturated monocarboxylic acids. These hydroxy-functional polyester diluents may be copolymerized with one or more acrylic monomers, i.e. hydroxy-functional acrylic monomers, and blended with a variety of thermosetting or thermoplastic film-forming polymers. These blends of the film-forming polymers and the hydroxy-functional polyester diluents can be crosslinked with conventional crosslinking agents such as isocyanates and used in the formulation of low VOC paint compositions particularly useful as automotive topcoats.

Abstract translation: 本发明涉及新的羟基官能聚酯稀释剂，更具体地说，涉及可用于与各种热固性或热塑性成膜聚合物共混的丙烯酸改性的羟基官能聚酯反应性稀释剂。 更具体地，羟基官能聚酯反应性稀释剂基本上是衍生自三醇的低分子量聚酯，以及不饱和一元羧酸和饱和一元羧酸的组合。 这些羟基官能的聚酯稀释剂可以与一种或多种丙烯酸单体即羟基官能的丙烯酸单体共聚，并与各种热固性或热塑性成膜聚合物共混。 成膜聚合物和羟基官能的聚酯稀释剂的这些共混物可以用常规的交联剂如异氰酸酯进行交联，并用于特别用作汽车面漆的低VOC涂料组合物的配方中。

公开(公告)号：US4124551A

公开(公告)日：1978-11-07

申请号：US836336

申请日：1977-09-26

Applicant: John Mathai ,  Thomas W. Druetzler

Inventor： John Mathai ,  Thomas W. Druetzler

IPC: C09D133/04 ,  C09D151/00 ,  C09D3/74 ,  C09D3/80

CPC classification number: C09D133/04 ,  C09D151/003

Abstract: This invention relates to novel fast-drying aliphatic solvent soluble acrylic-styrene polymer vehicles of paramount value as the binder vehicle for enamels and particularly for automotive after-market refinishing.Improvement in the quality and durability of automotive enamels in general has been outstanding with the advent of acrylic polymers useful as the adhesive binder in coatings for cars. When applied in production lines to automobile bodies originally under factory conditions, the use of high solvency enamel solvents and reducers has been a relatively obscure problem until recognition of the contribution of aromatic hydrocarbons solvents to smog development. Priorly curing or drying automotive paint films at a rapid speed has been feasible with elevated temperatures with little or no concern for energy consumption or atmospheric pollution. Large capital expenditures for high production rates with concurrent energy consumption have been heretofore acceptable generally. Part of the high energy requirement is due to the characteristically poor solvent release of acrylic polymers of the prior art.Essentially the vehicle comprises a first polymer of acrylic monomers chemically modified with a drying oil fatty acid moiety and isobornyl methacrylate in a first step in which a monomer comprising styrene is polymerized in a second step to produce an aliphatic solvent soluble enamel vehicle binder.

Abstract translation: 本发明涉及新颖的快干脂溶性可溶性丙烯酸 - 苯乙烯聚合物载体，作为搪瓷的粘合剂载体，特别适用于汽车后市场修补。