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1.发明申请公开(公告)号：US20130232855A1
公开(公告)日：2013-09-12
申请号：US13734627
申请日：2013-01-04
Applicant: KIOR INC.
Inventor： Peter Loezos , Brian Bibens , Ronald Cordle , Bruce Adkins , John Hacskaylo
IPC: C10G1/00
CPC classification number: C10G1/006 , C10G1/002 , C10G1/02 , C10G3/42 , C10G11/00 , C10G2300/1011 , F23K1/00 , F23K2301/10 , Y02E50/14 , Y02P30/20
Abstract: A two-stage reactor/process is disclosed for the conversion of solid particulate biomass material and includes: a first stage, in which solid particulate biomass material is pyrolyzed to primary reaction products, and a second stage in which the primary reaction products are catalytically converted in a second stage which is operated at a temperature higher than that of the first stage.
Abstract translation: 公开了用于固体颗粒生物质材料转化的两阶段反应器/方法，包括：其中固体颗粒生物质材料被热解为初级反应产物的第一阶段，以及其中初级反应产物被催化转化的第二阶段 在比第一级高的温度下工作的第二级。
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2.发明申请公开(公告)号：US20150202615A1
公开(公告)日：2015-07-23
申请号：US14596902
申请日：2015-01-14
Applicant: KiOR, Inc.
Inventor： Ling Zhou , Victoria Samples , Gopal Juttu , Hollie Craig , Bruce Adkins
CPC classification number: B01J38/66 , B01J29/06 , B01J29/90 , B01J38/60 , B01J38/62 , B01J38/74 , C10G3/44 , C10G3/62 , C10G2300/1011 , C10G2300/1014 , C10G2300/70 , C10G2400/02 , C10G2400/04 , C10G2400/06 , C10G2400/08 , Y02P30/20
Abstract: A metal contaminated spent catalyst or regenerated catalyst from a biomass conversion unit may be subjected to an ammonium wash in order to remove potassium. The ammonium wash may include ammonium sulfate, ammonium nitrate, ammonium hydroxide, ammonium acetate, ammonium phosphates, and mixtures thereof. Acidity and catalytic activity of the biomass conversion catalyst is restored by the removal of potassium contaminants.
Abstract translation: 可以将来自生物质转化单元的金属污染的废催化剂或再生催化剂进行铵洗涤以除去钾。 铵洗涤可以包括硫酸铵，硝酸铵，氢氧化铵，乙酸铵，磷酸铵和它们的混合物。 通过去除钾污染物来恢复生物质转化催化剂的酸度和催化活性。
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3.发明授权公开(公告)号：US09561501B2
公开(公告)日：2017-02-07
申请号：US14596902
申请日：2015-01-14
Applicant: KiOR, Inc.
Inventor： Ling Zhou , Victoria Samples , Gopal Juttu , Hollie Craig , Bruce Adkins
CPC classification number: B01J38/66 , B01J29/06 , B01J29/90 , B01J38/60 , B01J38/62 , B01J38/74 , C10G3/44 , C10G3/62 , C10G2300/1011 , C10G2300/1014 , C10G2300/70 , C10G2400/02 , C10G2400/04 , C10G2400/06 , C10G2400/08 , Y02P30/20
Abstract: A metal contaminated spent catalyst or regenerated catalyst from a biomass conversion unit may be subjected to an ammonium wash in order to remove potassium. The ammonium wash may include ammonium sulfate, ammonium nitrate, ammonium hydroxide, ammonium acetate, ammonium phosphates, and mixtures thereof. Acidity and catalytic activity of the biomass conversion catalyst is restored by the removal of potassium contaminants.
Abstract translation: 可以将来自生物质转化单元的金属污染的废催化剂或再生催化剂进行铵洗涤以除去钾。 铵洗涤可以包括硫酸铵，硝酸铵，氢氧化铵，乙酸铵，磷酸铵和它们的混合物。 通过去除钾污染物来恢复生物质转化催化剂的酸度和催化活性。
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4.发明申请Catalysts For Thermo-Catalytic Conversion Of Biomass, And Methods Of Making and Using 审中-公开催化剂用于生物质的热催化转化，以及制备和使用方法公开(公告)号：US20150045208A1
公开(公告)日：2015-02-12
申请号：US13963493
申请日：2013-08-09
Applicant: KIOR, Inc.
Inventor： Bruce Adkins , Jerry Jon Springs , Ling Zhou
IPC: B01J29/85
CPC classification number: B01J29/85 , B01J29/18 , B01J29/40 , B01J29/65 , B01J29/7007 , B01J35/002 , B01J35/0026 , B01J35/1019 , B01J35/1038 , B01J35/1061 , B01J37/0045 , B01J37/28 , B01J2229/186 , B01J2229/42 , C10G3/49 , C10G2300/1011 , C10G2300/1014 , Y02P30/20
Abstract: Disclosed are catalyst compositions including zeolite and silica components, methods of making, and processes of using in the thermo-catalytic conversion of biomass. Such disclosed methods of making include treating the zeolite with phosphorous during formation of the catalyst rather than prior to or after catalyst formation.
Abstract translation: 公开了包括沸石和二氧化硅组分的催化剂组合物，制备方法和在生物质的热催化转化中使用的方法。 这种公开的制备方法包括在形成催化剂期间而不是在催化剂形成之前或之后用磷处理沸石。
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Patent Agency Ranking
5.发明申请Catalysts for Thermo-Catalytic Conversion of Biomass, and Methods of Making and Using 有权用于生物质热催化转化的催化剂，以及制备和使用方法公开(公告)号：US20140024866A1
公开(公告)日：2014-01-23
申请号：US13838706
申请日：2013-03-15
Applicant: KiOR, Inc.
Inventor： Jerry Jon Springs , Bruce Adkins , Stephen Schuyten , Gopal Juttu , Christine M. Henry , Kelsey Shogren
CPC classification number: C10G1/086 , B01J29/084 , B01J29/18 , B01J29/40 , B01J29/65 , B01J29/7007 , B01J35/0026 , B01J35/1019 , B01J35/1033 , B01J35/1038 , B01J35/1061 , B01J35/108 , B01J35/1085 , B01J37/0018 , B01J37/0045 , B01J37/28 , B01J2229/42 , C10G1/08 , C10G2300/1011 , C10G2300/1014 , Y02P30/20
Abstract: Disclosed are catalyst compositions including zeolite and silica components, methods of making, and processes of using in the thermo-catalytic conversion of biomass. Such disclosed methods of making include: i) spray drying of the catalyst precursor slurry at a pH below 1, or ii) the removal of ions such as sodium from the binder material prior to spray drying the catalyst precursor slurry at a pH below 2.7, or iii) spray drying the catalyst precursor including a pore regulating agent followed by steam treating, or iv) some combination of i), ii) and iii).
Abstract translation: 公开了包括沸石和二氧化硅组分的催化剂组合物，制备方法和在生物质的热催化转化中使用的方法。 这种公开的制备方法包括：i）在低于1的pH下喷雾干燥催化剂前体浆料，或ii）在pH低于2.7的喷雾干燥催化剂前体浆料之前，从粘合剂材料中除去离子如钠， 或iii）喷雾干燥催化剂前体，包括孔调节剂，然后进行蒸汽处理，或iv）i），ii）和iii）的某些组合。
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公开(公告)号：US09649624B2
公开(公告)日：2017-05-16
申请号：US14705800
申请日：2015-05-06
Applicant: KiOR, Inc.
Inventor： Bruce Adkins , Dennis Stamires , Robert Bartek , Michael Brady , John Hacskaylo
CPC classification number: B01J29/40 , B01J37/0009 , B01J37/28 , B01J2229/18 , B01J2229/42 , C10G3/49 , C10G3/57 , C10G2300/1014 , C10G2400/02 , C10G2400/04 , C10G2400/08 , C10L1/04 , C10L2200/0469 , C10L2290/02 , Y02P30/20
Abstract: Catalyst compositions comprising a phosphorous-promoted ZSM-5 component and a silica-containing binder, and methods for making and using same, are disclosed. More, specifically, processes for making a catalyst for biomass conversion are provided. The process includes: treating a ZSM-5 zeolite with a phosphorous-containing compound to form a phosphorous-promoted ZSM-5 component; preparing a slurry comprising the phosphorous-promoted ZSM-5 component and a silica-containing binder; and shaping the slurry into shaped bodes. Such catalysts can be used for the Thermocatalytic conversion of particulate biomass to liquid products such as bio-oil, resulting in higher bio-oil yields and lower coke than conventional catalysts.
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7.发明申请CATALYST FOR THERMOCATALYTIC CONVERSION OF BIOMASS TO LIQUID FUELS AND CHEMICALS 有权生物质热液转化为液体燃料和化学品的催化剂公开(公告)号：US20150231613A1
公开(公告)日：2015-08-20
申请号：US14705800
申请日：2015-05-06
Applicant: KiOR, Inc.
Inventor： Bruce Adkins , Dennis Stamires , Robert Bartek , Michael Brady , John Hackskaylo
CPC classification number: B01J29/40 , B01J37/0009 , B01J37/28 , B01J2229/18 , B01J2229/42 , C10G3/49 , C10G3/57 , C10G2300/1014 , C10G2400/02 , C10G2400/04 , C10G2400/08 , C10L1/04 , C10L2200/0469 , C10L2290/02 , Y02P30/20
Abstract: Catalyst compositions comprising a phosphorous-promoted ZSM-5 component and a silica-containing binder, and methods for making and using same, are disclosed. More, specifically, processes for making a catalyst for biomass conversion are provided. The process includes: treating a ZSM-5 zeolite with a phosphorous-containing compound to form a phosphorous-promoted ZSM-5 component; preparing a slurry comprising the phosphorous-promoted ZSM-5 component and a silica-containing binder; and shaping the slurry into shaped bodes. Such catalysts can be used for the Thermocatalytic conversion of particulate biomass to liquid products such as bio-oil, resulting in higher bio-oil yields and lower coke than conventional catalysts.
Abstract translation: 公开了包含磷促进的ZSM-5组分和含二氧化硅的粘合剂的催化剂组合物及其制备和使用方法。 更具体地，提供了用于生产转化催化剂的方法。 该方法包括：用含磷化合物处理ZSM-5沸石以形成磷促进的ZSM-5组分; 制备包含磷促进的ZSM-5组分和含二氧化硅的粘合剂的浆料; 并将浆料成型成成形的状态。 这种催化剂可用于将颗粒生物质转化为液体产物如生物油的热催化转化，导致比常规催化剂更高的生物油产率和更低的焦炭。
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公开(公告)号：US20150004093A1
公开(公告)日：2015-01-01
申请号：US13932794
申请日：2013-07-01
Applicant: KiOR, Inc.
Inventor： Ling Zhou , Amanda Bryant , Maria Magdalena Ramirez , Leslie May , Richard A. Engelman , Bruce Adkins , Darrell Rainer
IPC: B01J29/90
CPC classification number: B01J29/90 , B01J35/1014 , B01J35/1019 , B01J35/1033 , B01J35/1038 , B01J35/1057 , B01J38/12 , B01J38/60 , B01J38/62 , B01J38/68 , B01J38/72 , C10G3/46 , C10G3/47 , C10G3/49 , C10G3/50 , C10G2300/1011 , C10G2300/1014 , Y02P30/20
Abstract: Spent catalyst or regenerated catalyst from a biomass conversion unit may be rejuvenated by treating at least a portion of the spent catalyst or regenerated catalyst with a treatment acid, the treatment acid comprising an inorganic acid or an organic acid or a mixture thereof.
Abstract translation: 可以通过用处理酸处理至少一部分废催化剂或再生催化剂，该处理酸包含无机酸或有机酸或其混合物，来从生物质转化单元得到的废催化剂或再生催化剂可以再生。
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公开(公告)号：US20140275588A1
公开(公告)日：2014-09-18
申请号：US14211776
申请日：2014-03-14
Applicant: KiOR, Inc.
Inventor： Gopal Juttu , Kelsey Shogren , Bruce Adkins
CPC classification number: B01J29/85 , B01J29/06 , B01J29/40 , B01J37/0045 , B01J37/28 , B01J2229/20 , B01J2229/42 , C10G3/49 , C10G45/12 , C10G2300/1011 , C11B3/02 , C11B13/00 , C11B13/005 , Y02P30/20 , Y02W30/74
Abstract: Disclosed are methods of making, and processes of using phosphorous-promoted zeolite-containing catalysts in the conversion of hydrocarbonaceous materials such as hydrocarbons and biomass. Such disclosed methods of making include: spray drying of the catalyst precursor slurry followed by phosphorous promotion of the resulting spray dried material.
Abstract translation: 公开了在含烃材料如烃和生物质的转化中制备方法和使用含磷促进的含沸石的催化剂的方法。 这样公开的制备方法包括：喷雾干燥催化剂前体浆液，随后磷酸促进所得喷雾干燥的材料。
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