公开(公告)号：US20150247095A1

公开(公告)日：2015-09-03

申请号：US14168796

申请日：2014-01-30

Applicant: KiOR, Inc.

Inventor： Maria Magdalena Ramirez Corredores ,  Ling Zhou ,  Rocio Banda

IPC: C10G1/08

CPC classification number: C10G1/086 ,  B01J21/04 ,  B01J21/10 ,  B01J23/28 ,  B01J27/22 ,  B01J29/084 ,  B01J29/40 ,  B01J29/80 ,  C10G1/08 ,  C10G2300/1011 ,  Y02P30/20

Abstract: Solid biomass may be converted to hydrocarbons for use in renewable fuels uses by feeding biomass into a biomass conversion unit and pyrolyzing the biomass in the presence of a regenerated multi-functional catalyst. The regenerated multi-functional catalyst contains an acidic component, a basic component and a metallic component. The biomass is treated within the biomass conversion unit in at least two stages wherein at least one component of the regenerated multi-functional catalyst is fed into each of the stages.

Abstract translation: 固体生物质可以通过将生物质投入到生物质转化单元中并在再生的多功能催化剂的存在下热解生物质而转化为用于可再生燃料用途的烃。 再生多功能催化剂含有酸性成分，碱性成分和金属成分。 在至少两个阶段内在生物质转化单元内处理生物质，其中再生的多功能催化剂的至少一种组分进料到每个级中。

公开(公告)号：US20150045208A1

公开(公告)日：2015-02-12

申请号：US13963493

申请日：2013-08-09

Applicant: KIOR, Inc.

Inventor： Bruce Adkins ,  Jerry Jon Springs ,  Ling Zhou

IPC: B01J29/85

CPC classification number: B01J29/85 ,  B01J29/18 ,  B01J29/40 ,  B01J29/65 ,  B01J29/7007 ,  B01J35/002 ,  B01J35/0026 ,  B01J35/1019 ,  B01J35/1038 ,  B01J35/1061 ,  B01J37/0045 ,  B01J37/28 ,  B01J2229/186 ,  B01J2229/42 ,  C10G3/49 ,  C10G2300/1011 ,  C10G2300/1014 ,  Y02P30/20

Abstract: Disclosed are catalyst compositions including zeolite and silica components, methods of making, and processes of using in the thermo-catalytic conversion of biomass. Such disclosed methods of making include treating the zeolite with phosphorous during formation of the catalyst rather than prior to or after catalyst formation.

Abstract translation: 公开了包括沸石和二氧化硅组分的催化剂组合物，制备方法和在生物质的热催化转化中使用的方法。 这种公开的制备方法包括在形成催化剂期间而不是在催化剂形成之前或之后用磷处理沸石。

公开(公告)号：US20150202615A1

公开(公告)日：2015-07-23

申请号：US14596902

申请日：2015-01-14

Applicant: KiOR, Inc.

Inventor： Ling Zhou ,  Victoria Samples ,  Gopal Juttu ,  Hollie Craig ,  Bruce Adkins

IPC: B01J38/66 ,  B01J29/06 ,  B01J29/90

CPC classification number: B01J38/66 ,  B01J29/06 ,  B01J29/90 ,  B01J38/60 ,  B01J38/62 ,  B01J38/74 ,  C10G3/44 ,  C10G3/62 ,  C10G2300/1011 ,  C10G2300/1014 ,  C10G2300/70 ,  C10G2400/02 ,  C10G2400/04 ,  C10G2400/06 ,  C10G2400/08 ,  Y02P30/20

Abstract: A metal contaminated spent catalyst or regenerated catalyst from a biomass conversion unit may be subjected to an ammonium wash in order to remove potassium. The ammonium wash may include ammonium sulfate, ammonium nitrate, ammonium hydroxide, ammonium acetate, ammonium phosphates, and mixtures thereof. Acidity and catalytic activity of the biomass conversion catalyst is restored by the removal of potassium contaminants.

Abstract translation: 可以将来自生物质转化单元的金属污染的废催化剂或再生催化剂进行铵洗涤以除去钾。 铵洗涤可以包括硫酸铵，硝酸铵，氢氧化铵，乙酸铵，磷酸铵和它们的混合物。 通过去除钾污染物来恢复生物质转化催化剂的酸度和催化活性。

公开(公告)号：US20150004093A1

公开(公告)日：2015-01-01

申请号：US13932794

申请日：2013-07-01

Applicant: KiOR, Inc.

Inventor： Ling Zhou ,  Amanda Bryant ,  Maria Magdalena Ramirez ,  Leslie May ,  Richard A. Engelman ,  Bruce Adkins ,  Darrell Rainer

IPC: B01J29/90

CPC classification number: B01J29/90 ,  B01J35/1014 ,  B01J35/1019 ,  B01J35/1033 ,  B01J35/1038 ,  B01J35/1057 ,  B01J38/12 ,  B01J38/60 ,  B01J38/62 ,  B01J38/68 ,  B01J38/72 ,  C10G3/46 ,  C10G3/47 ,  C10G3/49 ,  C10G3/50 ,  C10G2300/1011 ,  C10G2300/1014 ,  Y02P30/20

Abstract: Spent catalyst or regenerated catalyst from a biomass conversion unit may be rejuvenated by treating at least a portion of the spent catalyst or regenerated catalyst with a treatment acid, the treatment acid comprising an inorganic acid or an organic acid or a mixture thereof.

Abstract translation: 可以通过用处理酸处理至少一部分废催化剂或再生催化剂，该处理酸包含无机酸或有机酸或其混合物，来从生物质转化单元得到的废催化剂或再生催化剂可以再生。

公开(公告)号：US09561501B2

公开(公告)日：2017-02-07

申请号：US14596902

申请日：2015-01-14

Applicant: KiOR, Inc.

Inventor： Ling Zhou ,  Victoria Samples ,  Gopal Juttu ,  Hollie Craig ,  Bruce Adkins

IPC: B01J29/90 ,  B01J38/66 ,  B01J38/60 ,  B01J38/62 ,  C10G3/00 ,  B01J29/06

CPC classification number: B01J38/66 ,  B01J29/06 ,  B01J29/90 ,  B01J38/60 ,  B01J38/62 ,  B01J38/74 ,  C10G3/44 ,  C10G3/62 ,  C10G2300/1011 ,  C10G2300/1014 ,  C10G2300/70 ,  C10G2400/02 ,  C10G2400/04 ,  C10G2400/06 ,  C10G2400/08 ,  Y02P30/20

Abstract: A metal contaminated spent catalyst or regenerated catalyst from a biomass conversion unit may be subjected to an ammonium wash in order to remove potassium. The ammonium wash may include ammonium sulfate, ammonium nitrate, ammonium hydroxide, ammonium acetate, ammonium phosphates, and mixtures thereof. Acidity and catalytic activity of the biomass conversion catalyst is restored by the removal of potassium contaminants.

Abstract translation: 可以将来自生物质转化单元的金属污染的废催化剂或再生催化剂进行铵洗涤以除去钾。 铵洗涤可以包括硫酸铵，硝酸铵，氢氧化铵，乙酸铵，磷酸铵和它们的混合物。 通过去除钾污染物来恢复生物质转化催化剂的酸度和催化活性。

公开(公告)号：US20150209770A1

公开(公告)日：2015-07-30

申请号：US14168787

申请日：2014-01-30

Applicant: KiOR, Inc.

Inventor： Maria Magdalena Ramirez Corredores ,  Ling Zhou ,  Xiaowei Tong ,  Rocio Banda ,  Hollie Craig

IPC: B01J29/80 ,  C10G1/00

CPC classification number: B01J29/80 ,  B01J27/22 ,  B01J29/084 ,  B01J29/146 ,  B01J29/166 ,  B01J29/40 ,  B01J29/46 ,  B01J29/48 ,  B01J29/60 ,  B01J29/63 ,  B01J29/64 ,  B01J29/90 ,  B01J37/28 ,  B01J38/12 ,  B01J2029/062 ,  B01J2229/42 ,  C10G1/086

Abstract: A multi-functional catalyst for the conversion of biomass contains zeolite ZSM-5, zeolite USY, a metallic component, a basic material and a binder. The metallic component may be Cu, Ni, Cr, W, Mo, a metal carbide, a metal nitride, a metal sulfide or a mixture thereof. The basic material may be an alkaline-exchanged zeolite or an alkaline earth-exchanged zeolite having from about 40 to about 75% of exchanged cationic sites.

Abstract translation: 用于转化生物质的多功能催化剂包含沸石ZSM-5，沸石USY，金属组分，碱性材料和粘合剂。 金属成分可以是Cu，Ni，Cr，W，Mo，金属碳化物，金属氮化物，金属硫化物或它们的混合物。 碱性材料可以是具有约40至约75％交换的阳离子位点的碱交换的沸石或碱土交换沸石。