公开(公告)号：US09695332B2

公开(公告)日：2017-07-04

申请号：US14389344

申请日：2013-03-14

Applicant: LINTEC CORPORATION

Inventor： Tomomi Fukaya ,  Shinya Ichikawa

IPC: C09D135/02 ,  B05D3/06 ,  G03F7/027 ,  G03F7/031 ,  G03F7/038 ,  G03F7/075 ,  C08F2/48 ,  C08F222/10

CPC classification number: C09D135/02 ,  B05D3/067 ,  C08F2/48 ,  C08F222/1006 ,  C08F2222/1046 ,  G03F7/027 ,  G03F7/031 ,  G03F7/0388 ,  G03F7/0757 ,  Y10T428/24355

Abstract: A release film for producing a green sheet of the present invention includes a base material and a release agent layer provided at a side of a first surface of the base material. The release agent layer includes an ultraviolet curable compound (A) having three or more reactive groups selected from the group consisting of a (meth)acryloyl group, an alkenyl group and a maleimide group in one molecule thereof, a polyorganosiloxane (B) and an α-aminoalkylphenone based photopolymerization initiator (C). An arithmetic average roughness Ra1 of an outer surface of the release agent layer may be different than an arithmetic average roughness Ra2 of a second surface of the base material. According to the present invention, it is possible to prevent pinholes and variation in partially thickness from occurring to the green sheet.

公开(公告)号：US20150064402A1

公开(公告)日：2015-03-05

申请号：US14389348

申请日：2013-03-14

Applicant: LINTEC CORPORATION

Inventor： Tomomi Fukaya ,  Shinya Ichikawa

IPC: B28B7/36

CPC classification number: B28B7/364 ,  B28B1/30 ,  Y10T428/24355

Abstract: A release film for producing a green sheet of the present invention includes a base material having a first surface and a second surface and a release agent layer formed at a side of the first surface of the base material. A maximum projection height Rp2 of the second surface of the base material is in the range of 60 to 500 nm. An area occupation ratio of projections having a height of 60 nm or higher in the second surface is 10% or less. According to the present invention, it is possible to prevent pinholes and variation in partially thickness from occurring to the green sheet.

Abstract translation: 用于制造本发明的生片的剥离膜包括具有第一表面和第二表面的基材和形成在基材的第一表面侧的脱模剂层。 基材的第二面的最大突起高度Rp2在60〜500nm的范围内。 第二面的高度为60nm以上的突起的面积占有率为10％以下。 根据本发明，可以防止针孔和部分厚度的变化发生在生片上。

公开(公告)号：US20150086749A1

公开(公告)日：2015-03-26

申请号：US14394587

申请日：2013-03-14

Applicant: LINTEC CORPORATION

Inventor： Tomomi Fukaya ,  Shinya Ichikawa

IPC: C09D135/02

CPC classification number: C09D135/02 ,  B28B1/30 ,  C08G77/442 ,  C08L2203/16 ,  C09D143/04 ,  C09D183/10 ,  Y10T428/24355

Abstract: A release film for producing a green sheet of the present invention includes a base material having a first surface and a second surface, a release agent layer formed by applying a material containing an active energy ray curable compound (a1) and a polyorganosiloxane (b1) onto a side of the first surface of the base material and curing the material, and a back coat layer formed by applying a material containing an active energy ray curable compound (a2) onto a side of the second surface of the base material and curing the material. An arithmetic average roughness Ra2 of an outer surface of the release agent layer is 8 nm or less and a maximum projection height Rp2 of the outer surface is 50 nm or lower. An arithmetic average roughness Ra3 of an outer surface of the back coat layer is in the range of 5 to 40 nm and a maximum projection height Rp3 of the outer surface of the back coat layer is in the range of 60 to 500 nm. According to the present invention, it is possible to prevent pinholes and variation in partial thickness from occurring to the green sheet.

Abstract translation: 本发明的生片用剥离膜包括具有第一表面和第二表面的基材，通过涂布含有活性能量射线固化性化合物（a1）和聚有机硅氧烷（b1）的材料形成的剥离剂层， 在所述基材的第一表面的一侧上固化所述材料，以及通过将包含活性能量射线固化性化合物（a2）的材料施加到所述基材的所述第二表面侧并形成所述背涂层而形成的背涂层 材料。 剥离剂层的外表面的算术平均粗糙度Ra2为8nm以下，外表面的最大突出高度Rp2为50nm以下。 背涂层的外表面的算术平均粗糙度Ra3在5〜40nm的范围内，背涂层的外表面的最大突出高度Rp3在60〜500nm的范围内。 根据本发明，可以防止针孔和局部厚度的变化发生在生片上。

公开(公告)号：US20150037536A1

公开(公告)日：2015-02-05

申请号：US14387559

申请日：2013-02-04

Applicant: LINTEC CORPORATION

Inventor： Tomomi Fukaya ,  Shinya Ichikawa

IPC: B32B27/28 ,  B32B27/30 ,  B32B3/00

CPC classification number: B32B27/283 ,  B28B1/30 ,  B32B3/00 ,  B32B27/308 ,  B32B2250/02 ,  B32B2270/00 ,  B32B2305/77 ,  B32B2307/732 ,  C08G77/20 ,  C08G77/46 ,  C08J7/047 ,  C08J2367/02 ,  C08J2433/08 ,  C09J7/401 ,  C09J2483/005 ,  Y10T428/24355

Abstract: A release film for a ceramic green sheet production process is provided. The release film comprises a base material and a release agent layer provided at one side of the base material. The release agent layer comprises a cured material of a release agent composition. The release agent composition contains an active energy ray curable component and a silicone-based component. A surface of the release agent layer at the opposite side to the base material has an arithmetic average roughness (Ra) of 8 nm or less and a maximum projection height (Rp) of 50 nm or less. According to the release film for a ceramic green sheet production process, it is possible to effectively prevent/suppress the occurrence of defects such as pinholes and thickness irregularity in a ceramic green sheet, and the releasability of a ceramic green sheet is also excellent.

Abstract translation: 提供了一种用于陶瓷生片生产方法的脱模膜。 剥离膜包括设置在基材的一侧的基材和脱模剂层。 脱模剂层包括脱模剂组合物的固化材料。 脱模剂组合物含有活性能量射线固化性成分和硅酮类成分。 脱模剂层的与基材相反侧的表面的算术平均粗糙度（Ra）为8nm以下，最大突出高度（Rp）为50nm以下。 根据用于陶瓷生片生产方法的脱模膜，可以有效地防止/抑制陶瓷生片中的针孔和厚度不均匀等缺陷的发生，并且陶瓷生片的脱模性也优异。

公开(公告)号：US20150072108A1

公开(公告)日：2015-03-12

申请号：US14389344

申请日：2013-03-14

Applicant: LINTEC CORPORATION

Inventor： Tomomi Fukaya ,  Shinya Ichikawa

IPC: C09D135/02 ,  B05D3/06

CPC classification number: C09D135/02 ,  B05D3/067 ,  C08F2/48 ,  C08F222/1006 ,  C08F2222/1046 ,  G03F7/027 ,  G03F7/031 ,  G03F7/0388 ,  G03F7/0757 ,  Y10T428/24355

Abstract: A release film for producing a green sheet of the present invention includes a base material and a release agent layer provided at a side of a first surface of the base material. The release agent layer includes an ultraviolet curable compound (A) having three or more reactive groups selected from the group consisting of a (meth)acryloyl group, an alkenyl group and a maleimide group in one molecule thereof, a polyorganosiloxane (B) and an α-aminoalkylphenone based photopolymerization initiator (C). An average thickness of the release agent layer is in the range of 0.3 to 2 μm. An arithmetic average roughness Ra1 of an outer surface of the release agent layer is 8 nm or less and a maximum projection height Rp1 of the outer surface is 50 nm or lower. An arithmetic average roughness Ra2 of a second surface of the base material is in the range of 5 to 40 nm and a maximum projection height Rp2 of the second surface is in the range of 60 to 500 nm. According to the present invention, it is possible to prevent pinholes and variation in partially thickness from occurring to the green sheet.

Abstract translation: 本发明的生片用剥离膜包括在基材的第一面的一侧设置的基材和脱模剂层。 脱模剂层包括其一分子中具有选自（甲基）丙烯酰基，烯基和马来酰亚胺基中的三个以上反应性基团的紫外线固化性化合物（A），聚有机硅氧烷（B）和 α-氨基烷基苯酮类光聚合引发剂（C）。 脱模剂层的平均厚度为0.3〜2μm的范围。 剥离剂层的外表面的算术平均粗糙度Ra1为8nm以下，外表面的最大突出高度Rp1为50nm以下。 基材的第二表面的算术平均粗糙度Ra2在5〜40nm的范围内，第二面的最大突出高度Rp2在60〜500nm的范围内。 根据本发明，可以防止针孔和部分厚度的变化发生在生片上。

公开(公告)号：US20150050457A1

公开(公告)日：2015-02-19

申请号：US14387566

申请日：2013-02-04

Applicant: LINTEC CORPORATION

Inventor： Tomomi Fukaya ,  Shinya Ichikawa

IPC: B28B1/30

CPC classification number: B28B1/30 ,  Y10T428/24355

Abstract: A release film comprises a base material and a release agent layer provided at one side of the base material. The release agent layer comprises a cured material of a release agent composition. The release agent composition contains an active energy ray curable component and a silicone-based component. A surface of the release agent layer at the opposite side to the base material has an arithmetic average roughness (Ra) of 8 nm or less and a maximum projection height (Rp) of 50 nm or less. An elastic modulus measured by a nanoindentation test of the release agent layer is 4.0 GPa or more. A surface of the base material at the opposite side to the release agent layer has an arithmetic average roughness (Ra) of 5 to 50 nm and a maximum projection height (Rp) of 30 to 500 nm.

Abstract translation: 剥离膜包括设置在基材的一侧的基材和脱模剂层。 脱模剂层包括脱模剂组合物的固化材料。 脱模剂组合物含有活性能量射线固化性成分和硅酮类成分。 脱模剂层的与基材相反侧的表面的算术平均粗糙度（Ra）为8nm以下，最大突出高度（Rp）为50nm以下。 通过脱模剂层的纳米压痕试验测定的弹性模量为4.0GPa以上。 与脱模剂层相反一侧的基材的表面的算术平均粗糙度（Ra）为5〜50nm，最大突出高度（Rp）为30〜500nm。