公开(公告)号：US10400182B2

公开(公告)日：2019-09-03

申请号：US15871614

申请日：2018-01-15

Applicant: PHILLIPS 66 COMPANY

Inventor： Jianhua Yao ,  Hong Xie ,  Bruce B. Randolph ,  Steven E. Lusk ,  Dhananjay B. Ghonasgi ,  Jonathan R. Marda

IPC: C10G50/00 ,  C07C2/12 ,  B01J29/40 ,  B01D3/14

Abstract: The present disclosure relates generally processes and systems for converting a mixture of light hydrocarbons to liquid transportation fuels by first cracking the light hydrocarbons to an intermediate comprising olefins, which is converted by contacting with a catalyst comprising at least one zeolite in two separate conversion stages with an intervening recovery of liquid product. The first stage conversion favors oligomerization of larger olefins to form diesel range products that are collected prior to directing unconverted smaller olefins to be oligomerized in a second stage conversion conducted at a higher temperature and lower pressure.

公开(公告)号：US20210220788A1

公开(公告)日：2021-07-22

申请号：US17153390

申请日：2021-01-20

Applicant: PHILLIPS 66 COMPANY

Inventor： Jianhua Yao ,  Anthony O. Baldridge ,  Neal D. McDaniel ,  James A. Suttil ,  Chengtian Wu ,  Dhananjay B. Ghonasgi ,  Maziar Sardashti ,  Bruce B. Randolph

IPC: B01J8/04 ,  C07C29/88 ,  B01J31/06 ,  C10L1/02

Abstract: Systems for the catalytic activation and/or dehydrogenation of a paraffin feed stream that is enriched in C5 alkanes to produce olefins that are then hydrated in the presence of water to produce C5 alcohols. Optionally, paraffin isomers are separated and the n-paraffins isomerized prior to catalytic activation and/or dehydrogenation.

公开(公告)号：US20210222079A1

公开(公告)日：2021-07-22

申请号：US17153374

申请日：2021-01-20

Applicant: PHILLIPS 66 COMPANY

Inventor： Jianhua Yao ,  Anthony O. Baldridge ,  Neal D. McDaniel ,  James A. Suttil ,  Chengtian Wu ,  Dhananjay B. Ghonasgi ,  Maziar Sardashti ,  Bruce B. Randolph

IPC: C10L1/182 ,  C07C29/04 ,  C07C5/333 ,  C07C5/27

Abstract: Processes for the catalytic activation and/or dehydrogenation of a paraffin feed stream that is enriched in C5 alkanes to produce olefins that are then hydrated in the presence of water to produce C5 alcohols. Optionally, paraffin isomers are separated and the n-paraffins isomerized prior to catalytic activation and/or dehydrogenation.

公开(公告)号：US10252955B2

公开(公告)日：2019-04-09

申请号：US15871630

申请日：2018-01-15

Applicant: PHILLIPS 66 COMPANY

Inventor： Jianhua Yao ,  Hong Xie ,  Bruce B. Randolph ,  Steven E. Lusk ,  Dhananjay B. Ghonasgi ,  Jonathan R. Marda

IPC: C07C2/12 ,  C07C4/04 ,  B01J29/40 ,  C07C4/06 ,  C07C5/03 ,  B01J19/24

Abstract: The present disclosure relates generally processes and systems for converting a mixture of light hydrocarbons to liquid transportation fuels by first cracking the light hydrocarbons to an intermediate comprising olefins, which is converted by contacting with a catalyst comprising at least one zeolite in two separate conversion stages with an intervening recovery of liquid product. The first stage conversion favors oligomerization of larger olefins to form diesel range products that are collected prior to directing unconverted smaller olefins to be oligomerized in a second stage conversion conducted at a higher temperature and lower pressure.

公开(公告)号：US11648519B2

公开(公告)日：2023-05-16

申请号：US17153390

申请日：2021-01-20

Applicant: PHILLIPS 66 COMPANY

Inventor： Jianhua Yao ,  Anthony O. Baldridge ,  Neal D. McDaniel ,  James A. Suttil ,  Chengtian Wu ,  Dhananjay B. Ghonasgi ,  Maziar Sardashti ,  Bruce B. Randolph

IPC: B01J8/04 ,  C07C29/88 ,  C10L1/02 ,  B01J31/06

CPC classification number: B01J8/0492 ,  B01J31/06 ,  C07C29/88 ,  C10L1/02 ,  B01J2231/645 ,  B01J2531/002

Abstract: Systems for the catalytic activation and/or dehydrogenation of a paraffin feed stream that is enriched in C5 alkanes to produce olefins that are then hydrated in the presence of water to produce C5 alcohols. Optionally, paraffin isomers are separated and the n-paraffins isomerized prior to catalytic activation and/or dehydrogenation.