公开(公告)号：US10858541B2

公开(公告)日：2020-12-08

申请号：US16208983

申请日：2018-12-04

Applicant: Rohm and Haas Electronic Materials LLC

Inventor： Michael Mulzer ,  Yusuke Matsuda

IPC: C09D183/12 ,  C09D7/63 ,  C09D7/40 ,  C08J7/04 ,  C08K5/00 ,  C08G77/06 ,  C08J3/24 ,  C09D183/06 ,  C08G77/00 ,  C08G77/14 ,  C08G77/18 ,  C08G77/46

Abstract: A curable composition comprising an epoxy-siloxane oligomer comprising as polymerized units one or more difunctional silane monomers of formula (1) and one or more trifunctional silane monomers of formula (2) in a mole ratio of 95:5 to 10:30 Si(R1)(R2)(Y1)2  (1) SiR3(Y2)3  (2) wherein R1, R2, and R3 are independently chosen from a C5-20-aliphatic group comprising an oxirane ring fused to an alicyclic ring, C1-20-alkyl, C6-30-aryl group, and a C5-20-aliphatic group having one or more heteroatoms; each Y1 and Y2 is independently chosen from halogen, C1-4-alkoxy, and —O—C1-4-acyl group; wherein at least one of R1, R2, and R3 is a C5-20-aliphatic group comprising an oxirane ring fused to an alicyclic ring; (b) organic particles having an average diameter of 50 to 250 nm; (c) a reactive carrier having one or more epoxy moieties or oxetane moieties; (d) a curing agent; and (e) one or more organic solvents, and methods of forming cured coatings using such compositions are described.

公开(公告)号：US20210115289A1

公开(公告)日：2021-04-22

申请号：US17134578

申请日：2020-12-28

Applicant: Rohm and Haas Electronic Materials LLC

Inventor： Lujia Bu ,  Yusuke Matsuda ,  Michael Mulzer ,  Yinjie Cen

IPC: C09D133/14 ,  C08G63/688 ,  C08F220/18 ,  C08F2/50 ,  C08F220/34 ,  C08K5/3492

Abstract: The present invention provides a thermoformable and optically clear hard coat comprising a polyacrylate resin and 5 wt. % or less of inorganic nanoparticles with an average particle size of 100 nm or less in diameter based on total weight of resin solid. The polyacrylate resin is derived from polymerizing and curing ultraviolet (UV) curing acrylic compositions for use in making thermoformable hard coats for curved optical displays comprising (a) from 9 to 70 wt. %, based on the total weight of monomer solids, of an aliphatic tetrafunctional (meth)acrylate monomer or an aliphatic pentafunctional (meth)acrylate monomer; (b) from 3 to 30 wt. %, based on the total weight of monomer solids, of one or more one (meth)acrylate monomer containing an isocyanurate group; (c) from 5 to 55 wt. %, based on the total weight of monomer solids, of one or more aliphatic urethane (meth)acrylate functional oligomer having from 6 to 24 (meth)acrylate groups; (d) from 2 to 10 wt. %, based on total monomer solids, of one or more UV radical initiators; (e) from 10 to 30 wt. %, based on the total weight of (a), (b), (c), and (d), of one or more sulfur-containing polyol (meth)acrylates; and (f) one or more organic solvents for the monomer composition.

公开(公告)号：US20170369654A1

公开(公告)日：2017-12-28

申请号：US15602196

申请日：2017-05-23

Applicant: Dow Global Technologies LLC ,  Rohm and Haas Electronic Materials LLC

Inventor： Joseph Kao ,  Weijun Zhou ,  Yusuke Matsuda ,  Yuanqiao Rao ,  Michael Mulzer ,  Jieqian Zhang

IPC: C08G77/04 ,  C09D7/12 ,  C08K3/20 ,  C03C17/00 ,  C08G77/18 ,  C08F2/04 ,  C09D7/14 ,  C08K3/22

CPC classification number: C08G77/04 ,  C03C17/001 ,  C08F2/04 ,  C08G77/14 ,  C08G77/18 ,  C08K3/20 ,  C08K3/22 ,  C08K3/36 ,  C08K2201/003 ,  C08K2201/005 ,  C08K2201/006 ,  C08K2201/011 ,  C08L83/06 ,  C09D5/00 ,  C09D7/67 ,  C09D7/80 ,  C09D183/06

Abstract: A curable resin composition comprising: (a) 27 to 60 wt % of a liquid siloxane oligomer comprising polymerized units of formula R1mR2nSi(OR3)4-m-n, wherein R1 is a C5-C20 aliphatic group comprising an oxirane ring fused to an alicyclic ring, R2 is a C1-C20 alkyl, C6-C30 aryl group, or a C5-C20 aliphatic group having one or more heteroatoms, R3 is a C1-C4 alkyl group or a C1-C4 acyl group, m is 0.1 to 2.0 and n is 0 to 2.0; (b) 35 to 66 wt % non-porous nanoparticles of silica, a metal oxide, or a mixture thereof, having an average particle diameter from 5 to 50 nm; and (c) 0.5 to 7 wt % of a cationic photoinitiator.

公开(公告)号：US11084914B2

公开(公告)日：2021-08-10

申请号：US16208693

申请日：2018-12-04

Applicant: Rohm and Haas Electronic Materials LLC

Inventor： Michael Mulzer ,  Jieqian Zhang ,  Joseph Kao

IPC: B05D1/00 ,  C08J7/046 ,  C09D7/20 ,  C09D7/47 ,  C09D7/63 ,  C09D7/40 ,  C09D4/00 ,  C09D143/04 ,  C08J7/16 ,  C08L33/12 ,  C08L75/16 ,  C08L83/04 ,  C08K5/1515

Abstract: Display substrates having a hard coat layer on a colorless polyimide substrate are formed from hard coat compositions having certain organic solvents that do not substantially impact the optical and mechanical properties of the colorless polyimide substrate.

公开(公告)号：US20190185710A1

公开(公告)日：2019-06-20

申请号：US16208983

申请日：2018-12-04

Applicant: Rohm and Haas Electronic Materials LLC

Inventor： Michael Mulzer ,  Yusuke Matsuda

IPC: C09D183/12 ,  C09D7/63 ,  C09D7/40 ,  C08K5/00 ,  C08J7/04

CPC classification number: C09D183/12 ,  C08G77/46 ,  C08J7/04 ,  C08J2367/02 ,  C08J2379/08 ,  C08K5/0025 ,  C09D7/63 ,  C09D7/67 ,  C09D7/68

Abstract: A curable composition comprising an epoxy-siloxane oligomer comprising as polymerized units one or more difunctional silane monomers of formula (1) and one or more trifunctional silane monomers of formula (2) in a mole ratio of 95:5 to 10:30 Si(R1)(R2)(Y1)2   (1) SiR3(Y2)3   (2) wherein R1, R2, and R3 are independently chosen from a C5-20-aliphatic group comprising an oxirane ring fused to an alicyclic ring, C1-20-alkyl, C6-30-aryl group, and a C5-20-aliphatic group having one or more heteroatoms; each Y1 and Y2 is independently chosen from halogen, C1-4-alkoxy, and —O—C1-4-acyl group; wherein at least one of R1, R2, and R3 is a C5-20-aliphatic group comprising an oxirane ring fused to an alicyclic ring; (b) organic particles having an average diameter of 50 to 250 nm; (c) a reactive carrier having one or more epoxy moieties or oxetane moieties; (d) a curing agent; and (e) one or more organic solvents, and methods of forming cured coatings using such compositions are described.

公开(公告)号：US12024640B2

公开(公告)日：2024-07-02

申请号：US17504019

申请日：2021-10-18

Applicant: Rohm and Haas Electronic Materials LLC ,  DuPont Electronics, Inc.

Inventor： Michael Mulzer ,  Kenneth Hernandez ,  Andrew Stella ,  Lujia Bu ,  Jieqian Zhang ,  Deyan Wang ,  Yinjie Cen

IPC: C08F2/46 ,  C08F2/50 ,  C08G61/04 ,  C09D133/08 ,  C08K3/22

CPC classification number: C09D133/08 ,  C08K3/22 ,  C08K2003/2227

Abstract: Disclosed is an actinic radiation curable (meth)acrylic composition for use in hardcoats for optical displays containing one or more multifunctional (meth)acrylate monomers, one or more Si-containing (meth)acrylate monomers, one or more UV radical initiators, one or more monomers to improve surface cure, nanoparticles, and one or more organic solvents. Coated hardcoat articles made from this composition exhibit improved properties for use in display applications.

公开(公告)号：US20190185602A1

公开(公告)日：2019-06-20

申请号：US15843317

申请日：2017-12-15

Applicant: Rohm and Haas Electronic Materials LLC

Inventor： Lujia Bu ,  Yusuke Matsuda ,  Michael Mulzer

IPC: C08F222/22 ,  C09D135/02

CPC classification number: C08F222/22 ,  C08F2800/20 ,  C09D135/02

Abstract: The present invention provides ultraviolet (UV) curing acrylic compositions for use in making thermoformable hard coats for curved optical displays comprising: (a) one or more multifunctional (meth)acrylate diluents chosen from (a1) an aliphatic trifunctional (meth)acrylate monomer; (a2) an aliphatic tetrafunctional (meth)acrylate monomer; or (a3) an aliphatic pentafunctional (meth)acrylate monomer; (b) from 3 to 30 wt. %, based on the total weight of monomer solids, of one or more one (meth)acrylate monomer containing an isocyanurate group; (c) from 5 to 40 wt. %, based on the total weight of monomer solids, of one or more aliphatic urethane (meth)acrylate functional oligomer having from 6 to 12 (meth)acrylate groups; (d) from 2 to 10 wt. %, based on total monomer solids, of one or more UV radical initiators; and (e) one or more organic solvents for the monomer composition. The composition has a viscosity measured by Anton Parr ASVM 3001 digital viscometer at 50 wt. % solids of from 10 to 200 centipoise (cPs).

公开(公告)号：US20190112400A1

公开(公告)日：2019-04-18

申请号：US15782291

申请日：2017-10-12

Applicant: Rohm and Haas Electronic Materials LLC

Inventor： Wesley Sattler ,  Michael K. Gallagher ,  Kevin Y. Wang ,  Peter Trefonas, III ,  Michael Mulzer ,  Christopher Gilmore ,  Gregory D. Prokopowicz

IPC: C08F32/06 ,  C08F12/32

Abstract: The present invention provides organic solvent soluble or aqueous alkali soluble polymer composition comprising, in copolymerized form, one or more bis-arylcyclobutene monomers and one or more olefin or dienophile group containing second monomers, wherein the polymer is substantially free of (unreacted) arylcyclobutene groups. The compositions cure by a separate from the B-staging reaction which consumes substantially all of the arylcyclobutene groups in the composition; and they cure at temperatures below the cure temperature of less than 210° C., preferably, less than 180° C. The polymer compositions find use in making films or coatings and are aqueous or organic solvent developable when used in photolithography. Methods for making the polymer compositions are also provided.