PROCESS FOR THE CONVERSION OF METHANE TO C2+ HYDROCARBONS
    4.
    发明申请
    PROCESS FOR THE CONVERSION OF METHANE TO C2+ HYDROCARBONS 审中-公开
    甲烷转化为C2 +烃的方法

    公开(公告)号:US20160264497A1

    公开(公告)日:2016-09-15

    申请号:US15035970

    申请日:2014-11-06

    Abstract: A method of making ethane can comprise: introducing a chlorine stream and a methane stream to a first reaction zone comprising a metal oxide catalyst; converting the metal oxide to metal chloride and reacting the methane to form a product stream comprising the C2H4; introducing the metal chloride to a second reaction zone and introducing oxygen to convert the metal chloride to metal oxide and chlorine gas; and directing the metal oxide back to the first reaction zone. Also, a method of making ethane, comprising: introducing only a chlorine stream and a methane stream to a metal oxide catalyst to form the ethane and carbon dioxide, wherein the chlorine stream and the methane stream each comprise less than 1 vol % oxygen, and wherein metal oxide converts to metal chloride; and separately converting the metal chloride back to metal oxide with oxygen from an oxygen source, wherein chlorine gas is produced.

    Abstract translation: 制备乙烷的方法可以包括:将氯流和甲烷流引入到包含金属氧化物催化剂的第一反应区; 将金属氧化物转化为金属氯​​化物,并使甲烷反应形成包含C 2 H 4的产物流; 将金属氯化物引入第二反应区并引入氧气以将金属氯化物转化为金属氧化物和氯气; 并将金属氧化物引导回第一反应区。 此外,制备乙烷的方法包括:仅将氯气流和甲烷流引入金属氧化物催化剂以形成乙烷和二氧化碳,其中氯气流和甲烷流各自包含小于1体积%的氧气,以及 其中金属氧化物转化为金属氯​​化物; 并用氧气将金属氯化物分别回收成金属氧化物,其中产生氯气。

    PURIFICATION OF CARBON DIOXIDE STREAMS
    6.
    发明申请
    PURIFICATION OF CARBON DIOXIDE STREAMS 有权
    二氧化碳流体的净化

    公开(公告)号:US20160251226A1

    公开(公告)日:2016-09-01

    申请号:US15028976

    申请日:2014-10-15

    Abstract: In one embodiment, a process for the purification of CO2 from chlorinated and non-chlorinated hydrocarbons, comprising: contacting a CO2 stream with a metal oxide catalyst, wherein the stream comprises the CO2 and impurities comprising the non-chlorinated hydrocarbons and the chlorinated hydrocarbons; interacting the impurities with the catalyst to form additional CO2 and metal chloride; and regenerating the catalyst by contacting the metal chloride with an oxygen containing gas stream. In another embodiment, a process for the purification of CO2 from chlorinated hydrocarbons and non-chlorinated hydrocarbons, comprising: contacting a CO2 stream with a metal oxide catalyst, wherein the CO2 stream comprises the CO2 and impurities comprising the non-chlorinated hydrocarbons and the chlorinated hydrocarbons; oxidizing the impurities with catalyst oxygen to form additional CO2 and converting the chlorine to metal chloride; and regenerating the catalyst by contacting the metal chloride with an oxygen containing gas stream.

    Abstract translation: 在一个实施方案中,从氯化和非氯化烃中净化CO 2的方法,包括:使CO 2流与金属氧化物催化剂接触,其中所述物流包含CO 2和包含非氯化烃和氯化烃的杂质; 使杂质与催化剂相互作用以形成额外的CO 2和金属氯化物; 并通过使金属氯化物与含氧气流接触来再生催化剂。 在另一个实施方案中,用于从氯化烃和非氯化烃净化CO 2的方法包括:将CO 2流与金属氧化物催化剂接触,其中CO 2流包含CO 2和包含非氯化烃和氯化物的杂质 碳氢化合物 用催化剂氧氧化杂质以形成额外的CO 2并将氯转化为金属氯​​化物; 并通过使金属氯化物与含氧气流接触来再生催化剂。

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