公开(公告)号：US09486785B2

公开(公告)日：2016-11-08

申请号：US14907854

申请日：2014-07-28

Applicant: SAUDI BASIC INDUSTRIES CORPORATION

Inventor： Khalid Karim ,  Asad Ahmad Khan ,  Mohammad Abdur Rakib ,  Mohammed Al-Semahi ,  Jayen Barochia

IPC: B01J23/889 ,  C10G2/00 ,  B01J37/04

CPC classification number: B01J23/8892 ,  B01J37/04 ,  B01J2523/00 ,  C10G2/332 ,  C10G2/333 ,  C10G2400/22 ,  B01J2523/17 ,  B01J2523/22 ,  B01J2523/41 ,  B01J2523/72 ,  B01J2523/845 ,  B01J2523/847 ,  B01J2523/27

Abstract: The present disclosures and inventions relate to a catalyst or catalyst composition and the methods of making and using the catalyst or catalyst composition. In one aspect, the present disclosure relates to a catalyst composition that includes a catalyst having the formula CA CB Ox and a catalyst support; a) CA is CoaMnbXd, wherein X comprises Si, Ti, Cu, Zns Pd, or La or a combination thereof; a ranges from 0.8 to 1.2; b ranges from 0.1 to 1; and d ranges from 0 to 0.5; and b) CB is NieCufMghSim, wherein e ranges from about 0.8 to 1.2; f ranges from 0 to 1; h ranges from 0 to 0.5; and m ranges from 0 to 0.5; wherein Ox is determined by the valence requirements of the other elements present, wherein in the catalyst support consists essentially of magnesia, alumina, silica, titanic, carbon, or zeolite, or a combination thereof; and wherein the catalyst composition converts synthesis gas to at least one olefin.

Abstract translation: 本公开和发明涉及催化剂或催化剂组合物以及制备和使用催化剂或催化剂组合物的方法。 一方面，本公开内容涉及一种催化剂组合物，其包含具有式CA CB Ox的催化剂和催化剂载体; a）CA是CoaMnbXd，其中X包括Si，Ti，Cu，Zns Pd或La或其组合; a范围为0.8〜1.2; b范围从0.1到1; d范围为0〜0.5; 和b）CB是NieCufMghSim，其中e在约0.8至1.2的范围内; f范围从0到1; h范围从0到0.5; m范围为0〜0.5; 其中Ox由存在的其它元素的化合价要求确定，其中在催化剂载体中主要由氧化镁，氧化铝，二氧化硅，钛，碳或沸石或其组合组成; 并且其中所述催化剂组合物将合成气转化为至少一种烯烃。

公开(公告)号：US20160175819A1

公开(公告)日：2016-06-23

申请号：US14907854

申请日：2014-07-28

Applicant: SAUDI BASIC INDUSTRIES CORPORATION

Inventor： Khalid Karim ,  Asad Ahmad ,  Mohammad Abdur Rakib ,  Mohammed Al-Semahi ,  Jayen Barochia

IPC: B01J23/889 ,  C10G2/00

CPC classification number: B01J23/8892 ,  B01J37/04 ,  B01J2523/00 ,  C10G2/332 ,  C10G2/333 ,  C10G2400/22 ,  B01J2523/17 ,  B01J2523/22 ,  B01J2523/41 ,  B01J2523/72 ,  B01J2523/845 ,  B01J2523/847 ,  B01J2523/27

Abstract: The present disclosures and inventions relate to a catalyst or catalyst composition and the methods of making and using the catalyst or catalyst composition. In one aspect, the present disclosure relates to a catalyst composition that includes a catalyst having the formula CA CB Ox and a catalyst support; a) CA is CoaMnbXd, wherein X comprises Si, Ti, Cu, Zns Pd, or La or a combination thereof; a ranges from 0.8 to 1.2; b ranges from 0.1 to 1; and d ranges from 0 to 0.5; and b) CB is NieCufMghSim, wherein e ranges from about 0.8 to 1.2; f ranges from 0 to 1; h ranges from 0 to 0.5; and m ranges from 0 to 0.5; wherein Ox is determined by the valence requirements of the other elements present, wherein in the catalyst support consists essentially of magnesia, alumina, silica, titanic, carbon, or zeolite, or a combination thereof; and wherein the catalyst composition converts synthesis gas to at least one olefin.

Abstract translation: 本公开和发明涉及催化剂或催化剂组合物以及制备和使用催化剂或催化剂组合物的方法。 一方面，本公开内容涉及一种催化剂组合物，其包含具有式CA CB Ox的催化剂和催化剂载体; a）CA是CoaMnbXd，其中X包括Si，Ti，Cu，Zns Pd或La或其组合; a范围为0.8〜1.2; b范围从0.1到1; d范围为0〜0.5; 和b）CB是NieCufMghSim，其中e在约0.8至1.2的范围内; f范围从0到1; h范围从0到0.5; m范围为0〜0.5; 其中Ox由存在的其它元素的化合价要求确定，其中在催化剂载体中主要由氧化镁，氧化铝，二氧化硅，钛，碳或沸石或其组合组成; 并且其中所述催化剂组合物将合成气转化为至少一种烯烃。

公开(公告)号：US20150218063A1

公开(公告)日：2015-08-06

申请号：US14422025

申请日：2013-08-13

Applicant: SAUDI BASIC INDUSTRIES CORPORATION

Inventor： Suman Kumar Jana ,  Jayen Barochia

IPC: C07C2/12 ,  B01J35/10 ,  B01J29/40 ,  B01J29/48 ,  B01J29/46

CPC classification number: C07C2/12 ,  B01J29/40 ,  B01J29/405 ,  B01J29/42 ,  B01J29/46 ,  B01J29/48 ,  B01J35/1057 ,  B01J37/10 ,  C07C2529/40 ,  C07C2529/44 ,  C07C2529/46 ,  C07C2529/48 ,  C07C2529/89 ,  C10G50/00 ,  C10G2300/1081 ,  C10G2300/1088 ,  C10G2300/70 ,  C10G2400/22 ,  C07C11/02

Abstract: The present invention relates to a process for the dimerization of branched olefins or a mixture of olefins and paraffins, wherein said olefins and paraffins have between 3 to 10 carbon atoms, comprising contacting a feedstream comprising said olefin or mixture of olefins and paraffins with a catalyst composition comprising a medium pore aluminosilicate zeolite having a pore size of between more than 5 Å but less than 6 Å and up to 5 wt-% of one or more elements selected from the group consisting of molybdenum (Mo), tungsten (W), seaborgium (Sg), cobalt (Co), rhodium (Rh), iridium (Ir) and meinerium (Mt).

Abstract translation: 本发明涉及一种使支化烯烃或烯烃和链烷烃的混合物二聚的方法，其中所述烯烃和链烷烃具有3-10个碳原子，包括使包含所述烯烃或烯烃和链烷烃的混合物的进料流与催化剂 组合物，其包含中孔微孔硅酸盐沸石，所述中孔铝硅酸盐沸石的孔径在大于或小于6埃至多至5重量％的一种或多种选自钼（Mo），钨（W）， 海藻（Sg），钴（Co），铑（Rh），铱（Ir）和矿物（Mt）。