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公开(公告)号：US20180369790A1
公开(公告)日：2018-12-27
申请号：US16063922
申请日：2016-12-20
Applicant: SHELL OIL COMPANY
Inventor： Andreas KLEMT , László DOMOKOS , Frank Peter FRIEDEL , Stefan BOETTCHER , Erwin Roderick STOBBE
Abstract: The invention relates to a method for preparing a hydrogenation catalyst or catalyst precursor comprising a catalytically active material and a carrier material. The method involves the mixing of an acidic solution comprising metal ions of a metal selected from the IUPAC group 8, 9 or 10 metals, preferably cobalt, a suspension comprising the carrier material and an alkaline solution. The invention also relates to a precursor of a hydrogenation catalyst wherein the precursor comprises crystallites of metal oxides having an average size of max. 8 nm.
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公开(公告)号：US20210354116A1
公开(公告)日：2021-11-18
申请号：US17284967
申请日：2019-10-15
Applicant: SHELL OIL COMPANY
Inventor： Erwin Roderick STOBBE , Hendrik Albertus COLIJN , Maria Elisabeth VAN ES-HOGENSTIJN , Johanna Jacoba BERG-SLOT
IPC: B01J27/057 , B01J23/00 , B01J37/04 , B01J37/08 , C07C5/48
Abstract: The invention relates to a process for preparing a catalyst for alkane oxidative dehydrogenation and/or alkene oxidation, which catalyst is a mixed metal oxide catalyst containing molybdenum, vanadium, niobium and optionally tellurium, wherein the process comprises: a) preparing a catalyst precursor containing molybdenum, vanadium, niobium and optionally tellurium; b) optionally contacting the catalyst precursor obtained in step a) with oxygen and/or an inert gas at an elevated temperature; c) contacting the catalyst precursor obtained in step a) or step b) with a gas mixture comprising ammonia and water, which gas mixture further comprises oxygen and/or an inert gas, at an elevated temperature; and d) optionally contacting the catalyst precursor obtained in step c) with an inert gas at an elevated temperature. Further, the invention relates to a catalyst obtainable by said process and to a process of the oxidative dehydrogenation of an alkane containing 2 to 6 carbon atoms and/or the oxidation of an alkene containing 2 to 6 carbon atoms wherein said catalyst is used.
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公开(公告)号：US20170283709A1
公开(公告)日：2017-10-05
申请号：US15628912
申请日：2017-06-21
Applicant: SHELL OIL COMPANY
Inventor： Erwin Roderick STOBBE , Gerrit Leendert BEZEMER , Peter John VAN DEN BRINK , Alexander Petrus VAN BAVEL
IPC: C10G2/00 , B01J37/24 , B01J23/889 , B01J27/128 , B01J27/135 , B01J37/02 , B01J37/18 , B01J21/06
CPC classification number: C10G2/332 , B01J21/063 , B01J23/8892 , B01J23/8896 , B01J27/128 , B01J27/135 , B01J37/0201 , B01J37/18 , B01J37/24 , C10G2/341 , C10G2300/4031
Abstract: The invention relates to a method to start up a Fischer-Tropsch process. A catalyst with a latent activity is used. The catalyst comprises titania, cobalt, promoter, and chlorine. The catalyst comprises more than 0.7 and less than 4 weight percent of the element chlorine, calculated on the total weight of the catalyst.
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公开(公告)号：US20210053045A1
公开(公告)日：2021-02-25
申请号：US16982436
申请日：2019-03-19
Applicant: SHELL OIL COMPANY
Inventor： Jurjen MEEUWISSEN , Erwin Roderick STOBBE
IPC: B01J37/03 , B01J37/04 , B01J37/06 , B01J6/00 , B01J35/02 , B01J37/08 , B01J35/10 , B01J23/75 , C10G2/00
Abstract: The present invention is directed to the preparation of a cobalt containing catalyst, a precipitate as an intermediate product, a Fischer-Tropsch catalyst and a process for producing normally gaseous, normally liquid and optionally normally solid hydrocarbons from synthesis gas. The precipitate and catalyst comprise crystalline Co(OH)(CO3)0.5, the crystals are needle shaped and have a surface area of at least 80 m2/g dry precipitate.
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Patent Agency Ranking
公开(公告)号：US20170297006A1
公开(公告)日：2017-10-19
申请号：US15643051
申请日：2017-07-06
Applicant: SHELL OIL COMPANY
Inventor： Alexander Petrus VAN BAVEL , Gerrit Leendert BEZEMER , Peter John VAN DEN BRINK , Erwin Roderick STOBBE
IPC: B01J27/135 , B01J27/10 , B01J27/138 , C10G2/00 , B01J37/04 , C07C1/04 , B01J37/24 , B01J37/08 , B01J37/00 , C07C11/10 , B01J37/02 , B01J23/889 , B01J35/02
CPC classification number: B01J27/135 , B01J23/8892 , B01J23/8896 , B01J27/10 , B01J27/138 , B01J35/023 , B01J37/0009 , B01J37/0201 , B01J37/04 , B01J37/08 , B01J37/24 , C07C1/0435 , C07C11/10 , C07C2521/06 , C07C2523/34 , C07C2523/75 , C07C2523/889 , C10G2/332 , C07C9/14
Abstract: The invention concerns a process for preparing a chlorine comprising catalyst by (a) providing a Fischer-Tropsch catalyst comprising titania and at least 5 weight percent cobalt; (b) impregnating the catalyst with a solution comprising chloride ions; and (c) heating the impregnated catalyst at a temperature in the range of between 100 and 500° C. for at least 5 minutes up to 2 days. The prepared catalyst preferably comprises 0.13-3 weight percent of the element chlorine. The invention further relates to the prepared catalyst and its use.
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6.发明申请PROCESS FOR PREPARING A CHLORINE COMPRISING CATALYST, THE PREPARED CATALYST, AND ITS USE 有权制备包含催化剂，制备的催化剂及其使用的氯仿的方法公开(公告)号：US20160175821A1
公开(公告)日：2016-06-23
申请号：US14906911
申请日：2014-07-14
Applicant: SHELL OIL COMPANY
Inventor： Alexander Petrus VAN BAVEL , Gerrit Leendert BEZEMER , Peter John VAN DEN BRINK , Erwin Roderick STOBBE
IPC: B01J27/135 , B01J37/02 , B01J37/08 , C10G2/00
CPC classification number: B01J27/135 , B01J23/8892 , B01J23/8896 , B01J27/10 , B01J27/138 , B01J35/023 , B01J37/0009 , B01J37/0201 , B01J37/04 , B01J37/08 , B01J37/24 , C07C1/0435 , C07C11/10 , C07C2521/06 , C07C2523/34 , C07C2523/75 , C07C2523/889 , C10G2/332 , C07C9/14
Abstract: The invention concerns a process for preparing a chlorine comprising catalyst by (a) providing a Fischer-Tropsch catalyst comprising titania and at least 5 weight percent cobalt; (b) impregnating the catalyst with a solution comprising chloride ions; and (c) heating the impregnated catalyst at a temperature in the range of between 100 and 500° C. for at least 5 minutes up to 2 days. The prepared catalyst preferably comprises 0.13-3 weight percent of the element chlorine. The invention further relates to the prepared catalyst and its use.
Abstract translation: 本发明涉及通过（a）提供包含二氧化钛和至少5重量％的钴的费 - 托催化剂来制备含氯催化剂的方法; （b）用包含氯离子的溶液浸渍催化剂; 和（c）将浸渍的催化剂在100-500℃的温度范围内加热至少5分钟至2天。 制备的催化剂优选含有0.13-3重量％的元素氯。 本发明还涉及制备的催化剂及其用途。
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公开(公告)号：US20170348677A1
公开(公告)日：2017-12-07
申请号：US15536231
申请日：2015-12-21
Applicant: SHELL OIL COMPANY
Inventor： Andreas KLEMT , László DOMOKOS , Frank Peter FRIEDEL , Stefan BOETTCHER , Erwin Roderick STOBBE
IPC: B01J23/889 , B01J37/08 , B01J37/06 , B01J37/04 , B01J37/03 , B01J37/02 , B01J37/00 , C10G2/00 , B01J35/02
CPC classification number: B01J23/8892 , B01J23/74 , B01J23/745 , B01J23/75 , B01J35/023 , B01J37/0072 , B01J37/009 , B01J37/0236 , B01J37/035 , B01J37/04 , B01J37/06 , B01J37/08 , B01J37/088 , B01J37/16 , C10G2/332
Abstract: The invention relates to a method for preparing a catalyst or catalyst precursor comprising a catalytically active material and a carrier material. The invention relates to a catalyst particle and catalyst precursor thereof obtainable by said method. The catalyst may be used in a process for synthesising hydrocarbons.
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8.发明申请PROCESS FOR PREPARING A CHLORINE COMPRISING CATALYST, THE PREPARED CATALYST, AND ITS USE 审中-公开制备包含催化剂，制备的催化剂及其使用的氯仿的方法公开(公告)号：US20160175820A1
公开(公告)日：2016-06-23
申请号：US14906909
申请日：2014-07-14
Applicant: SHELL OIL COMPANY
Inventor： Gerrit Leendert BEZEMER , Erwin Roderick STOBBE
IPC: B01J27/135 , B01J37/08 , B01J37/02 , C10G2/00
CPC classification number: B01J27/135 , B01J21/063 , B01J23/8892 , B01J27/128 , B01J27/13 , B01J35/023 , B01J37/0009 , B01J37/0018 , B01J37/0201 , B01J37/0236 , B01J37/08 , B01J37/18 , B01J37/24 , C10G2/332
Abstract: The invention concerns a process for preparing a chlorine comprising catalyst using one or more metal salts of chloride, hydrochloric acid (HCl), one or more organic chloride compounds, or a combination thereof. The prepared catalyst preferably comprises 0.13-3 weight percent of the element chlorine. The invention further relates to the prepared catalyst and its use.
Abstract translation: 本发明涉及使用一种或多种氯化物，盐酸（HCl），一种或多种有机氯化物化合物或其组合的金属盐制备含氯催化剂的方法。 制备的催化剂优选含有0.13-3重量％的元素氯。 本发明还涉及制备的催化剂及其用途。
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公开(公告)号：US20160160128A1
公开(公告)日：2016-06-09
申请号：US14906928
申请日：2013-07-14
Applicant: SHELL OIL COMPANY
Inventor： Erwin Roderick STOBBE , Gerrit Leendert BEZEMER , Peter John VAN DEN BRINK , Alexander Petrus VAN BAVEL
IPC: C10G2/00 , B01J27/135
CPC classification number: C10G2/332 , B01J21/063 , B01J23/8892 , B01J23/8896 , B01J27/128 , B01J27/135 , B01J37/0201 , B01J37/18 , B01J37/24 , C10G2/341 , C10G2300/4031
Abstract: The invention relates to a method to start up a Fischer-Tropsch process. A catalyst with a latent activity is used. The catalyst comprises titania, cobalt, promoter, and chlorine. The catalyst comprises more than 0.7 and less than 4 weight percent of the element chlorine, calculated on the total weight of the catalyst.
Abstract translation: 本发明涉及一种启动费 - 托方法。 使用具有潜在活性的催化剂。 催化剂包括二氧化钛，钴，促进剂和氯。 根据催化剂的总重量，催化剂含有大于0.7且小于4重量％的元素氯。
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