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公开(公告)号：US10995288B2
公开(公告)日：2021-05-04
申请号：US15260198
申请日：2016-09-08
Applicant: Sundrop Fuels, Inc.
Inventor： Douglas S. Jack , Renus C. Kelfkens , Wayne W. Simmons , Andrew Argo , Andrew W. Broerman
Abstract: An interconnected set of two or more stages of reactors to form a bio-reforming reactor that generates syngas for a number of different liquid fuel or chemical processes is discussed. A first stage includes a circulating fluidized bed reactor that is configured to cause a chemical devolatilization of the biomass into its reaction products of constituent gases, tars, chars, and other components, which exit through a reactor output from the first stage. A second stage of the bio-reforming reactor has an input configured to receive a stream of some of the reaction products that includes the constituent gases and at least some of the tars as raw syngas, and then chemically reacts the raw syngas within a vessel of the second stage to make the raw syngas from the first stage into a chemical grade syngas by further cracking the tars, excess methane, or both.
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公开(公告)号：US20180291279A1
公开(公告)日：2018-10-11
申请号：US15947024
申请日：2018-04-06
Applicant: Sundrop Fuels, Inc.
Inventor： Douglas S. Jack , Renus C. Kelfkens , Steve C. Lythgoe , Wayne W. Simmons
CPC classification number: C10G2/344 , C01B3/382 , C01B2203/0233 , C01B2203/062 , C10G3/00 , C10G45/00 , C10G2300/1011 , C10G2400/02 , C10G2400/04 , C10G2400/08 , C10J3/466 , C10J3/485 , C10J2300/0916 , C10J2300/0976 , C10J2300/1659 , C10J2300/1807 , Y02E50/13 , Y02E50/32 , Y02P30/20
Abstract: A bio-reforming reactor receives biomass to generate chemical grade syngas for a coupled downstream train of a low-temperature Fischer-Tropsch reactor train that uses this syngas derived from the biomass in the bio-reforming reactor. A renewable carbon content of the produced gasoline, jet fuel, and/or diesel derived from the coupled downstream train the low-temperature Fischer-Tropsch reactor train are optimized for recovery of renewable carbon content to produce fuel products with 100% biogenic carbon content and/or fuel products with 50-100% biogenic carbon content. The low-temperature Fischer-Tropsch reactor train produces syncrude, transportation fuels such as bio-gasoline or bio-diesel, or a combination thereof.
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公开(公告)号：US20150376518A1
公开(公告)日：2015-12-31
申请号：US14852077
申请日：2015-09-11
Applicant: Sundrop Fuels, Inc.
Inventor： Zoran Jovanovic , Bryan Schramm , Christopher Perkins , Courtland M. Hilton , Wayne W. Simmons
IPC: C10J3/72 , C10J3/50 , C10J3/58 , C10L1/04 , C10J3/46 , C10G2/00 , C10K1/02 , C10J3/84 , C10J3/48 , C10J3/60
CPC classification number: C01B3/384 , B01J19/0013 , B01J19/0033 , B01J19/2445 , B01J19/245 , B01J2219/00117 , B01J2219/00186 , C01B3/22 , C01B3/34 , C01B2203/0216 , C01B2203/0233 , C01B2203/061 , C01B2203/0811 , C01B2203/1241 , C01B2203/1685 , C01B2203/84 , C07C29/15 , C07C29/1518 , C10G2/30 , C10G2/32 , C10G3/00 , C10G2300/1014 , C10G2300/1025 , C10G2300/807 , C10J3/00 , C10J3/466 , C10J3/482 , C10J3/485 , C10J3/506 , C10J3/54 , C10J3/56 , C10J3/58 , C10J3/60 , C10J3/62 , C10J3/721 , C10J3/723 , C10J3/82 , C10J3/84 , C10J2200/09 , C10J2200/15 , C10J2200/158 , C10J2300/0906 , C10J2300/0909 , C10J2300/0916 , C10J2300/094 , C10J2300/0973 , C10J2300/0976 , C10J2300/0989 , C10J2300/0993 , C10J2300/1223 , C10J2300/123 , C10J2300/1284 , C10J2300/1292 , C10J2300/1621 , C10J2300/1659 , C10J2300/1665 , C10J2300/1693 , C10J2300/1853 , C10J2300/1861 , C10K1/024 , C10L1/04 , C10L2200/0492 , C10L2290/02 , C10L2290/04 , C10L2290/06 , C10L2290/08 , C10L2290/28 , C10L2290/42 , C10L2290/50 , C10L2290/52 , C10L2290/547 , F24S20/20 , Y02B40/18 , Y02E10/41 , Y02E50/18 , Y02E50/32 , Y02P20/129 , Y02P20/134 , Y02P20/136 , Y02P20/145 , Y02P30/20 , Y02T50/678 , C07C31/04
Abstract: A method, apparatus, and system for a solar-driven bio-refinery that may include a entrained-flow biomass feed system that is feedstock flexible via particle size control of the biomass. Some embodiments include a chemical reactor that receives concentrated solar thermal energy from an array of heliostats. The entrained-flow biomass feed system can use an entrainment carrier gas and supplies a variety of biomass sources fed as particles into the solar-driven chemical reactor. Biomass sources in a raw state or partially torrified state may be used, as long as parameters such as particle size of the biomass are controlled. Additionally, concentrated solar thermal energy can drive gasification of the particles. An on-site fuel synthesis reactor may receive the hydrogen and carbon monoxide products from the gasification reaction use the hydrogen and carbon monoxide products in a hydrocarbon fuel synthesis process to create a liquid hydrocarbon fuel.
Abstract translation: 一种用于太阳能驱动的生物炼油厂的方法，装置和系统，其可以包括通过生物量的粒度控制而原料柔性的夹带流生物质进料系统。 一些实施例包括从定日镜阵列接收集中的太阳能热能的化学反应器。 夹带流生物质进料系统可以使用夹带载气，并将多种作为颗粒进料的生物质源供应到太阳能驱动的化学反应器中。 只要能够控制诸如生物质的粒度的参数，就可以使用处于原始状态或部分受束缚状态的生物质源。 此外，集中的太阳能热能可以驱动颗粒的气化。 现场燃料合成反应器可以从气化反应中接收氢气和一氧化碳产物，在烃燃料合成过程中使用氢气和一氧化碳产物以产生液态烃燃料。
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公开(公告)号：US20140318013A1
公开(公告)日：2014-10-30
申请号：US14325701
申请日：2014-07-08
Applicant: Sundrop Fuels, Inc.
Inventor： Wayne W. Simmons , Christopher Perkins , Zoran Radojica Zovanovic
CPC classification number: C01B3/384 , B01J19/0013 , B01J19/0033 , B01J19/2445 , B01J19/245 , B01J2219/00117 , B01J2219/00186 , C01B3/22 , C01B3/34 , C01B2203/0216 , C01B2203/0233 , C01B2203/061 , C01B2203/0811 , C01B2203/1241 , C01B2203/1685 , C01B2203/84 , C07C29/15 , C07C29/1518 , C10G2/30 , C10G2/32 , C10G3/00 , C10G2300/1014 , C10G2300/1025 , C10G2300/807 , C10J3/00 , C10J3/466 , C10J3/482 , C10J3/485 , C10J3/506 , C10J3/54 , C10J3/56 , C10J3/58 , C10J3/60 , C10J3/62 , C10J3/721 , C10J3/723 , C10J3/82 , C10J3/84 , C10J2200/09 , C10J2200/15 , C10J2200/158 , C10J2300/0906 , C10J2300/0909 , C10J2300/0916 , C10J2300/094 , C10J2300/0973 , C10J2300/0976 , C10J2300/0989 , C10J2300/0993 , C10J2300/1223 , C10J2300/123 , C10J2300/1284 , C10J2300/1292 , C10J2300/1621 , C10J2300/1659 , C10J2300/1665 , C10J2300/1693 , C10J2300/1853 , C10J2300/1861 , C10K1/024 , C10L1/04 , C10L2200/0492 , C10L2290/02 , C10L2290/04 , C10L2290/06 , C10L2290/08 , C10L2290/28 , C10L2290/42 , C10L2290/50 , C10L2290/52 , C10L2290/547 , F24S20/20 , Y02B40/18 , Y02E10/41 , Y02E50/18 , Y02E50/32 , Y02P20/129 , Y02P20/134 , Y02P20/136 , Y02P20/145 , Y02P30/20 , Y02T50/678 , C07C31/04
Abstract: A method, apparatus, and system for a solar-driven chemical plant that may include a solar thermal receiver having a cavity with an inner wall, where the solar thermal receiver is aligned to absorb concentrated solar energy from one or more of 1) an array of heliostats, 2) solar concentrating dishes, and 3) any combination of the two. Some embodiments may include a solar-driven chemical reactor having multiple reactor tubes located inside the cavity of solar thermal receiver, wherein a chemical reaction driven by radiant heat occurs in the multiple reactor tubes, and wherein particles of biomass are gasified in the presence of a steam (H2O) carrier gas and methane (CH4) in a simultaneous steam reformation and steam biomass gasification reaction to produce reaction products that include hydrogen and carbon monoxide gas using the solar thermal energy from the absorbed concentrated solar energy in the multiple reactor tubes.
Abstract translation: 一种用于太阳能驱动的化学设备的方法，装置和系统，其可以包括具有内壁的空腔的太阳能热接收器，其中太阳能热接收器对准以从1）阵列中的一个或多个吸收集中的太阳能 的定日镜，2）太阳能集中盘，3）两者的任何组合。 一些实施例可以包括太阳能驱动的化学反应器，其具有位于太阳能热接收器的空腔内的多个反应器管，其中在多个反应器管中发生由辐射热驱动的化学反应，并且其中生物质颗粒在 蒸汽（H 2 O）载气和甲烷（CH4），同时进行蒸汽重整和蒸汽生物质气化反应，以产生包含氢气和一氧化碳气体的反应产物，使用来自多个反应器管中吸收的浓缩太阳能的太阳能热能。
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公开(公告)号：US10273415B2
公开(公告)日：2019-04-30
申请号：US15947024
申请日：2018-04-06
Applicant: Sundrop Fuels, Inc.
Inventor： Douglas S. Jack , Renus C. Kelfkens , Steve C. Lythgoe , Wayne W. Simmons
Abstract: A bio-reforming reactor receives biomass to generate chemical grade syngas for a coupled downstream train of a low-temperature Fischer-Tropsch reactor train that uses this syngas derived from the biomass in the bio-reforming reactor. A renewable carbon content of the produced gasoline, jet fuel, and/or diesel derived from the coupled downstream train the low-temperature Fischer-Tropsch reactor train are optimized for recovery of renewable carbon content to produce fuel products with 100% biogenic carbon content and/or fuel products with 50-100% biogenic carbon content. The low-temperature Fischer-Tropsch reactor train produces syncrude, transportation fuels such as bio-gasoline or bio-diesel, or a combination thereof.
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Patent Agency Ranking
公开(公告)号：US20170137284A1
公开(公告)日：2017-05-18
申请号：US15419826
申请日：2017-01-30
Applicant: Sundrop Fuels, Inc.
Inventor： Wayne W. Simmons , Sidney P. White , Christopher Perkins
CPC classification number: C01B3/384 , B01J19/0013 , B01J19/0033 , B01J19/2445 , B01J19/245 , B01J2219/00117 , B01J2219/00186 , C01B3/22 , C01B3/34 , C01B2203/0216 , C01B2203/0233 , C01B2203/061 , C01B2203/0811 , C01B2203/1241 , C01B2203/1685 , C01B2203/84 , C07C29/15 , C07C29/1518 , C10G2/30 , C10G2/32 , C10G3/00 , C10G2300/1014 , C10G2300/1025 , C10G2300/807 , C10J3/00 , C10J3/466 , C10J3/482 , C10J3/485 , C10J3/506 , C10J3/54 , C10J3/56 , C10J3/58 , C10J3/60 , C10J3/62 , C10J3/721 , C10J3/723 , C10J3/82 , C10J3/84 , C10J2200/09 , C10J2200/15 , C10J2200/158 , C10J2300/0906 , C10J2300/0909 , C10J2300/0916 , C10J2300/094 , C10J2300/0973 , C10J2300/0976 , C10J2300/0989 , C10J2300/0993 , C10J2300/1223 , C10J2300/123 , C10J2300/1284 , C10J2300/1292 , C10J2300/1621 , C10J2300/1659 , C10J2300/1665 , C10J2300/1693 , C10J2300/1853 , C10J2300/1861 , C10K1/024 , C10L1/04 , C10L2200/0492 , C10L2290/02 , C10L2290/04 , C10L2290/06 , C10L2290/08 , C10L2290/28 , C10L2290/42 , C10L2290/50 , C10L2290/52 , C10L2290/547 , F24S20/20 , Y02B40/18 , Y02E10/41 , Y02E50/18 , Y02E50/32 , Y02P20/129 , Y02P20/134 , Y02P20/136 , Y02P20/145 , Y02P30/20 , Y02T50/678 , C07C31/04
Abstract: A multiple stage synthesis gas generation system is disclosed including a high radiant heat flux reactor, a gasifier reactor control system, and a Steam Methane Reformer (SMR) reactor. The SMR reactor is in parallel and cooperates with the high radiant heat flux reactor to produce a high quality syngas mixture for MeOH synthesis. The resultant products from the two reactors may be used for the MeOH synthesis. The SMR provides hydrogen rich syngas to be mixed with the potentially carbon monoxide rich syngas from the high radiant heat flux reactor. The combination of syngas component streams from the two reactors can provide the required hydrogen to carbon monoxide ratio for methanol synthesis. The SMR reactor control system and a gasifier reactor control system interact to produce a high quality syngas mixture for the MeOH synthesis.
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7.发明申请Integrated Process Plant Having a Biomass Reforming Reactor Using a Fluidized Bed 审中-公开具有使用流化床的生物质重整反应器的综合工艺设备公开(公告)号：US20170066983A1
公开(公告)日：2017-03-09
申请号：US15260198
申请日：2016-09-08
Applicant: Sundrop Fuels, Inc.
Inventor： Douglas S. Jack , Renus C. Kelfkens , Wayne W. Simmons , Andrew Argo , Andrew W. Broerman
CPC classification number: C10J3/84 , B01J8/24 , C01B3/24 , C01B3/26 , C01B2203/0233 , C01B2203/0272 , C01B2203/0277 , C01B2203/04 , C01B2203/0465 , C01B2203/0475 , C01B2203/048 , C01B2203/0485 , C01B2203/0495 , C01B2203/061 , C01B2203/062 , C01B2203/0816 , C01B2203/1041 , C01B2203/1058 , C01B2203/1241 , C01B2203/1247 , C01B2203/1252 , C01B2203/1258 , C01B2203/1676 , C10J3/56 , C10J2200/15 , C10J2300/0906 , C10J2300/0909 , C10J2300/0916 , C10J2300/0976 , C10J2300/0993 , C10J2300/12 , C10J2300/1253 , C10J2300/1659 , C10J2300/1665 , C10J2300/1853 , Y02E50/32 , Y02P20/125 , Y02P20/145
Abstract: An interconnected set of two or more stages of reactors to form a bio-reforming reactor that generates syngas for a number of different liquid fuel or chemical processes is discussed. A first stage includes a circulating fluidized bed reactor that is configured to cause a chemical devolatilization of the biomass into its reaction products of constituent gases, tars, chars, and other components, which exit through a reactor output from the first stage. A second stage of the bio-reforming reactor has an input configured to receive a stream of some of the reaction products that includes the constituent gases and at least some of the tars as raw syngas, and then chemically reacts the raw syngas within a vessel of the second stage to make the raw syngas from the first stage into a chemical grade syngas by further cracking the tars, excess methane, or both.
Abstract translation: 讨论了两个或更多阶段的反应器的互连的组合，以形成生成用于多种不同液体燃料或化学过程的合成气的生物重整反应器。 第一阶段包括循环流化床反应器，其被配置为使生物质进入其组成气体，焦油，焦炭和其它组分的反应产物的化学脱挥发分，所述组分气体，焦油，焦炭和其它组分通过来自第一级的反应器输出而排出。 生物重整反应器的第二阶段具有被配置为接收包括构成气体的一些反应产物的流和至少一些焦油作为原始合成气的输入，然后使原料合成气在容器内的化学反应 第二阶段是通过进一步开裂焦油，多余的甲烷或两者将第一阶段的原始合成气进入化学级合成气。
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公开(公告)号：US10273422B2
公开(公告)日：2019-04-30
申请号：US15946952
申请日：2018-04-06
Applicant: Sundrop Fuels, Inc.
Inventor： Douglas S. Jack , Renus C. Kelfkens , Steve C. Lythgoe , Wayne W. Simmons
Abstract: A bio-reforming reactor receives biomass to generate chemical grade syngas for a coupled downstream train of any of 1) a methanol-synthesis-reactor train, 2) a methanol-to-gasoline reactor train, and 3) a high-temperature Fischer-Tropsch reactor train, that use this syngas derived from the biomass in the bio-reforming reactor. A renewable carbon content of the produced gasoline, jet fuel, and/or diesel derived from the coupled downstream trains of any of 1) the methanol-synthesis-reactor train, 2) the methanol-to-gasoline reactor train, or 3) the high-temperature Fischer-Tropsch reactor train are optimized for recovery of renewable carbon content to produce fuel products with 100% biogenic carbon content and/or fuel products with 50-100% biogenic carbon content. A carbon-dioxide gas feedback loop cooperates with a CO2 separation unit to supply a fraction of the CO2 gas that is removed from the chemical grade syngas produced from the reactor output of the BRR to supply extracted CO2 gas to the biomass feed system.
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公开(公告)号：US20180291295A1
公开(公告)日：2018-10-11
申请号：US15946952
申请日：2018-04-06
Applicant: Sundrop Fuels, Inc.
Inventor： Douglas S. Jack , Renus C. Kelfkens , Steve C. Lythgoe , Wayne W. Simmons
IPC: C10L3/08 , B01J8/18 , C10L5/44 , B01D53/047
CPC classification number: C10L3/08 , B01D53/047 , B01J8/1872 , C01B2203/1235 , C10L5/44 , C10L2200/0423 , C10L2200/043 , C10L2200/0476 , C10L2200/0492 , C10L2290/02 , C10L2290/04 , C10L2290/28 , C10L2290/42 , C10L2290/56 , Y02C10/08 , Y02E50/10 , Y02E50/30 , Y02E50/32 , Y02P20/145
Abstract: A bio-reforming reactor receives biomass to generate chemical grade syngas for a coupled downstream train of any of 1) a methanol-synthesis-reactor train, 2) a methanol-to-gasoline reactor train, and 3) a high-temperature Fischer-Tropsch reactor train, that use this syngas derived from the biomass in the bio-reforming reactor. A renewable carbon content of the produced gasoline, jet fuel, and/or diesel derived from the coupled downstream trains of any of 1) the methanol-synthesis-reactor train, 2) the methanol-to-gasoline reactor train, or 3) the high-temperature Fischer-Tropsch reactor train are optimized for recovery of renewable carbon content to produce fuel products with 100% biogenic carbon content and/or fuel products with 50-100% biogenic carbon content. A carbon-dioxide gas feedback loop cooperates with a CO2 separation unit to supply a fraction of the CO2 gas that is removed from the chemical grade syngas produced from the reactor output of the BRR to supply extracted CO2 gas to the biomass feed system.
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公开(公告)号：US20160152905A1
公开(公告)日：2016-06-02
申请号：US14952060
申请日：2015-11-25
Applicant: Sundrop Fuels, Inc.
Inventor： Renus C. Kelfkens , Wayne W. Simmons , Douglas S. Jack , Jerrod Wayne Hohman , Sidney P. White
CPC classification number: C10J3/466 , C01B3/38 , C01B2203/0233 , C01B2203/062 , C01B2203/1241 , C10G2/32 , C10G2/34 , C10G3/00 , C10G45/00 , C10G45/44 , C10G2300/1011 , C10G2400/02 , C10G2400/04 , C10G2400/08 , C10J3/485 , C10J3/506 , C10J3/84 , C10J2300/0916 , C10J2300/0976 , C10J2300/1659 , C10J2300/1807 , C10J2300/1853 , C10K1/08 , C10K1/32 , C10K3/008 , C10K3/023 , C10L1/04 , C10L2200/0492 , C10L2270/023 , C10L2270/026 , C10L2270/04 , C10L2290/04 , C10L2290/06 , C10L2290/10 , C10L2290/42 , C10L2290/541 , C10L2290/542 , C10L2290/543 , C10L2290/548 , Y02E50/32 , Y02P20/145 , Y02P20/582 , Y02P30/20
Abstract: An integrated plant to generate chemical grade syngas from a steam biomass reforming in a multiple stage bio reforming reactor for use with either a high temperature or low temperature Fischer-Tropsch synthesis process to produce fuel from biomass is discussed. The first stage has a reactor to cause a chemical devolatilization of a biomass feedstock from the biomass feedstock supply lines into its constituent gases of CO, H2, CO2, CH4, tars, chars, and other components into a raw syngas mixture. A second stage performs further reforming of the raw syngas from the first stage into the chemical grade syngas by further applying heat and pressure to chemically crack at least the tars, reform the CH4, or a combination of both, into their corresponding syngas molecules. The second stage feeds the chemical grade syngas derived from the biomass feedstock to the downstream Fischer-Tropsch train to produce the fuel from the biomass. One or more recycle loops supply tail gas or FT product back into the plant.
Abstract translation: 讨论了一种用于在多级生物重整反应器中从蒸汽生物质重整产生化学级合成气的综合工厂，用于与高温或低温费 - 托合成方法一起使用以从生物质产生燃料。 第一阶段具有反应器，以使生物质原料从生物质原料供应管线进入其CO，H 2，CO 2，CH 4，焦油，焦炭和其它组分的组成气体的化学脱挥发分成原始合成气混合物。 第二阶段通过进一步施加热和压力来将原料合成气从第一阶段进一步重整成化学级合成气，至少化学裂化焦油，将CH 4或两者的组合重整成相应的合成气分子。 第二阶段将来自生物质原料的化学级合成气进料到下游费 - 托列车，以从生物质产生燃料。 一个或多个回收循环将尾气或FT产物回送到工厂。
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