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1.发明授权Transition metal complexes for enantioselective catalysis of carbon-carbon, carbon-heteroatom, and carbon-hydrogen bond forming reactions 有权用于碳 - 碳，碳 - 杂原子和碳 - 氢键形成反应的对映选择性催化的过渡金属络合物公开(公告)号：US09446393B2
公开(公告)日：2016-09-20
申请号：US14417655
申请日：2013-07-29
Applicant: The Texas A&M University System
Inventor： Kyle G. Lewis , John A. Gladysz , Subrata K. Ghosh
CPC classification number: C07F15/065 , B01J31/0255 , B01J31/146 , B01J31/1805 , B01J31/22 , B01J31/2295 , B01J2231/32 , B01J2231/323 , B01J2231/341 , B01J2531/845 , C07B53/00 , C07C211/65 , C07F5/027
Abstract: In some embodiments, the present disclosure pertains to a compound, comprising a transition metal complex having the formula Φ-[M(x,y)-L1(w,v)-L2(t,u)-L3]p+An−mZ−p_m. In an embodiment of the present disclosure Φ may be A. In another embodiment Φ may be Δ. In some embodiments of the present disclosure, M is a transition metal. In a related embodiment, p is an integer corresponding to the oxidation state of M. In some embodiments of the present disclosure, each of x, y, w, v, t, and u independently comprise R. In other embodiments, each of x, y, w, v, t, and u independently comprise S. In an embodiment of the present disclosure, each of L1, L2, and L3 independently is a ligand comprising a substituted diamine. In some embodiments, An″ comprises a lipophilic anion, where m is from 1 to 3, and where Z− comprises an optional second anion.
Abstract translation: 在一些实施方案中，本公开涉及包含具有式Φ-[M（x，y）-L1（w，v）-L2（t，u）-L3] p + An- mZ-p_m。 在本公开的实施例中，Φ可以是A.在另一个实施例中，Φ可以是Δ。 在本公开的一些实施方案中，M是过渡金属。 在相关实施方案中，p是对应于M的氧化态的整数。在本公开的一些实施方案中，x，y，w，v，t和u中的每一个独立地包含R.在其它实施方案中，x ，y，w，v，t和u独立地包括S.在本公开的实施方案中，L1，L2和L3中的每一个独立地为包含取代的二胺的配体。 在一些实施方案中，An“包含亲脂性阴离子，其中m为1至3，并且其中Z-包含任选的第二阴离子。
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2.发明申请TRANSITION METAL COMPLEXES FOR ENANTIOSELECTIVE CATALYSIS OF CARBON-CARBON, CARBON-HETEROATOM, AND CARBON-HYDROGEN BOND FORMING REACTIONS 有权过渡金属络合物，用于碳碳，碳 - 杂交和碳氢键形成反应的选择性催化公开(公告)号：US20150165429A1
公开(公告)日：2015-06-18
申请号：US14417655
申请日：2013-07-29
Applicant: THE TEXAS A&M UNIVERSITY SYSTEM
Inventor： Kyle G. Lewis , John A. Gladysz , Subrata K. Ghosh
CPC classification number: C07F15/065 , B01J31/0255 , B01J31/146 , B01J31/1805 , B01J31/22 , B01J31/2295 , B01J2231/32 , B01J2231/323 , B01J2231/341 , B01J2531/845 , C07B53/00 , C07C211/65 , C07F5/027
Abstract: In some embodiments, the present disclosure pertains to a compound, comprising a transition metal complex having the formula Φ-[M(x,y)-L1(w,v)-L2(t,u)-L3]p+An−mZ−p—m. In an embodiment of the present disclosure Φ may be A. In another embodiment Φ may be Δ. In some embodiments of the present disclosure, M is a transition metal. In a related embodiment, p is an integer corresponding to the oxidation state of M. In some embodiments of the present disclosure, each of x, y, w, v, t, and u independently comprise R. In other embodiments, each of x, y, w, v, t, and u independently comprise S. In an embodiment of the present disclosure, each of L1, L2, and L3 independently is a ligand comprising a substituted diamine. In some embodiments, An″ comprises a lipophilic anion, where m is from 1 to 3, and where Z− comprises an optional second anion.
Abstract translation: 在一些实施方案中，本公开涉及包含具有式Φ-[M（x，y）-L1（w，v）-L2（t，u）-L3] p + An- mZ-p-m。 在本公开的实施例中，Φ可以是A.在另一个实施例中，Φ可以是＆Dgr。 在本公开的一些实施方案中，M是过渡金属。 在相关实施方案中，p是对应于M的氧化态的整数。在本公开的一些实施方案中，x，y，w，v，t和u中的每一个独立地包含R.在其它实施方案中，x ，y，w，v，t和u独立地包括S.在本公开的实施方案中，L1，L2和L3中的每一个独立地是包含取代的二胺的配体。 在一些实施方案中，An“包含亲脂性阴离子，其中m为1至3，并且其中Z-包含任选的第二阴离子。
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