公开(公告)号：US20140249344A1

公开(公告)日：2014-09-04

申请号：US14347159

申请日：2012-10-24

Applicant: TOTAL RAFFINAGE FRANCE

Inventor： Delphine Minoux ,  Nadiya Danilina

IPC: B01J29/12 ,  C07C4/06 ,  B01J29/08

CPC classification number: B01J29/126 ,  B01J29/06 ,  B01J29/068 ,  B01J29/072 ,  B01J29/076 ,  B01J29/084 ,  B01J29/146 ,  B01J29/166 ,  B01J29/90 ,  B01J35/002 ,  B01J35/108 ,  B01J35/109 ,  B01J35/1095 ,  B01J37/06 ,  B01J38/08 ,  B01J2229/14 ,  B01J2229/16 ,  B01J2229/186 ,  B01J2229/22 ,  B01J2229/36 ,  B01J2229/37 ,  B01J2229/38 ,  B01J2229/42 ,  C01B39/026 ,  C01B39/06 ,  C01B39/24 ,  C07C4/06 ,  C07C2529/068 ,  C10G49/08 ,  Y02P20/584

Abstract: The invention relates to a process for preparing a catalyst comprising a mesoporized zeolite, comprising the steps of: preparation of a protonic mesoporized zeolite, which contains at least one network of micropores and at least one network of mesopores, and treatment in a gas or liquid phase containing ammonia or ammonium ions. The invention also related to the obtained catalyst and the use of this catalyst in hydroconversion processes.

Abstract translation: 本发明涉及一种制备包含介孔沸石的催化剂的方法，包括以下步骤：制备质子介孔沸石，其包含至少一个微孔网络和至少一个中孔网络，以及在气体或液体中的处理 相含有氨或铵离子。 本发明还涉及所获得的催化剂和该催化剂在加氢转化方法中的用途。

公开(公告)号：US10343150B2

公开(公告)日：2019-07-09

申请号：US14347159

申请日：2012-10-24

Applicant: TOTAL RAFFINAGE FRANCE

Inventor： Delphine Minoux ,  Nadiya Danilina

IPC: B01J29/12 ,  B01J37/06 ,  B01J38/08 ,  B01J29/06 ,  B01J29/068 ,  B01J29/072 ,  B01J29/076 ,  B01J29/08 ,  B01J29/14 ,  B01J29/16 ,  B01J35/00 ,  B01J35/10 ,  C01B39/02 ,  C01B39/06 ,  C01B39/24 ,  C10G49/08 ,  B01J29/90 ,  C07C4/06

Abstract: The invention relates to a process for preparing a catalyst comprising a mesoporized zeolite, comprising the steps of: preparation of a protonic mesoporized zeolite, which contains at least one network of micropores and at least one network of mesopores, and treatment in a gas or liquid phase containing ammonia or ammonium ions. The invention also related to the obtained catalyst and the use of this catalyst in hydroconversion processes.

公开(公告)号：US20140339134A1

公开(公告)日：2014-11-20

申请号：US14241667

申请日：2012-10-23

Applicant: TOTAL RAFFINAGE FRANCE

Inventor： Delphine Minoux ,  Nadiya Danilina

IPC: B01J29/16 ,  C10G47/20 ,  C10G47/18

CPC classification number: B01J29/166 ,  B01J29/10 ,  B01J29/106 ,  B01J29/14 ,  B01J29/146 ,  B01J29/16 ,  B01J35/002 ,  B01J35/1057 ,  B01J35/1061 ,  B01J35/1095 ,  B01J37/0018 ,  B01J37/28 ,  B01J2229/186 ,  B01J2229/36 ,  B01J2229/37 ,  B01J2229/40 ,  B01J2229/42 ,  C10G47/18 ,  C10G47/20 ,  C10G49/08

Abstract: The invention relates to a process for preparing a hydroconversion catalyst based on a modified zeolite of the FAU framework type with preserved crystallinity and microporosity, comprising the steps of: A—preparation of a modified zeolite of the FAU framework type, whose intracrystalline structure presents at least one network of micropores, at least one network of small mesopores with a mean diameter of 2 to 5 nm and at least one network of large mesopores with a mean diameter of 10 to 50 nm; these various networks being interconnected; B—mixing the zeolite with a binder, shaping the mixture, and then calcining; C—impregnation of the shaped zeolite with at least one compound of a catalytic metal chosen from compounds of a metal from group VIII and/or from group VIB, in acidic medium, provided that at least one compound of a catalytic metal is soluble within said acidic medium and that the acid acts as a complexing or chelating agent for at least one compound of a catalytic metal. The invention also relates to a catalyst obtained via this process and also to the use thereof.

Abstract translation: 本发明涉及一种基于具有保留的结晶度和微孔性的FAU骨架型改性沸石制备加氢转化催化剂的方法，包括以下步骤：制备FAU骨架类型的改性沸石，其结晶结构呈现在 至少一个微孔网络，平均直径为2至5nm的至少一个小介孔网络和至少一个平均直径为10至50nm的大介孔网络; 这些各种网络是相互联系的; B将沸石与粘合剂混合，成型混合物，然后煅烧; 使用至少一种选自VIII族金属和/或VIB族的化合物的催化金属的化合物在酸性介质中浸渍成型沸石，条件是至少一种催化金属化合物可溶于所述 并且酸作为至少一种催化金属化合物的络合剂或螯合剂。 本发明还涉及通过该方法获得的催化剂以及其用途。

公开(公告)号：US10105688B2

公开(公告)日：2018-10-23

申请号：US14352573

申请日：2012-10-24

Applicant: TOTAL RAFFINAGE FRANCE

Inventor： Delphine Minoux ,  Nadiya Danilina

IPC: B01J29/08 ,  B01J37/06 ,  B01J29/12 ,  C10G47/16 ,  B01J35/00 ,  B01J35/10 ,  C07C1/22

Abstract: The invention relates to a process for preparing a hydroconverzation catalyst consisting of a modified zeolite Y, comprising the steps of a treatment of a modified zeolite Y by suspension thereof in a basic pH solution, stopping the previous treatment by neutralization of the modified zeolite Y containing solution with an acid-containing solution; filtering and washing the recovered modified zeolite Y solid, drying and optionally calcining the modified zeolite Y solid, placing the modified zeolite Y solid of step d) in contact, with stirring, in an ion exchange solution and optional steaming and/or calcining the modified zeolite Y type compound for obtaining the catalyst containing a modified zeolite Y.

公开(公告)号：US09821298B2

公开(公告)日：2017-11-21

申请号：US14241667

申请日：2012-10-23

Applicant: TOTAL RAFFINAGE FRANCE

Inventor： Delphine Minoux ,  Nadiya Danilina

IPC: B01J29/06 ,  B01J29/16 ,  B01J29/10 ,  B01J29/14 ,  C10G49/08 ,  B01J35/00 ,  B01J35/10 ,  C10G47/18 ,  C10G47/20 ,  B01J37/00 ,  B01J37/28

CPC classification number: B01J29/166 ,  B01J29/10 ,  B01J29/106 ,  B01J29/14 ,  B01J29/146 ,  B01J29/16 ,  B01J35/002 ,  B01J35/1057 ,  B01J35/1061 ,  B01J35/1095 ,  B01J37/0018 ,  B01J37/28 ,  B01J2229/186 ,  B01J2229/36 ,  B01J2229/37 ,  B01J2229/40 ,  B01J2229/42 ,  C10G47/18 ,  C10G47/20 ,  C10G49/08

Abstract: A process for preparing a hydroconversion catalyst comprising the steps of: preparing a modified zeolite of the FAU framework type, whose intracrystalline structure presents at least one network of micropores, at least one network of small mesopores with a mean diameter of 2 to 5 nm and at least one network of large mesopores with a mean diameter of 10 to 50 nm; these various networks being interconnected; mixing the zeolite with a binder, shaping the mixture, and then calcining; impregnating the shaped zeolite with at least one compound of a catalytic metal chosen from compounds of a metal from group VIII and/or from group VIB, in acidic medium, provided that at least one compound of a catalytic metal is soluble within said acidic medium and that the acid acts as a complexing or chelating agent for at least one compound of a catalytic metal.

公开(公告)号：US20140357909A1

公开(公告)日：2014-12-04

申请号：US14352573

申请日：2012-10-24

Applicant: TOTAL RAFFINAGE FRANCE

Inventor： Delphine Minoux ,  Nadiya Danilina

IPC: B01J29/08 ,  C07C1/22 ,  C10G47/16

CPC classification number: B01J29/084 ,  B01J29/126 ,  B01J35/002 ,  B01J35/1085 ,  B01J37/06 ,  B01J2229/14 ,  B01J2229/16 ,  B01J2229/186 ,  B01J2229/22 ,  B01J2229/24 ,  B01J2229/36 ,  B01J2229/37 ,  B01J2229/38 ,  C07C1/22 ,  C07C2529/06 ,  C10G47/16

Abstract: The invention relates to a process for preparing a hydroconversation catalyst consisting of a modified zeolite Y, comprising the steps of a treatment of a modified zeolite Y by suspension thereof in a basic pH solution, stopping the previous treatment by neutralization of the modified zeolite Y containing solution with an acid-containing solution; filtering and washing the recovered modified zeolite Y solid, drying and optionally calcining the modified zeolite Y solid, placing the modified zeolite Y solid of step d) in contact, with stirring, in an ion exchange solution and optional steaming and/or calcining the modified zeolite Y type compound for obtaining the catalyst containing a modified zeolite Y.

Abstract translation: 本发明涉及一种制备由改性沸石Y组成的加氢转化催化剂的方法，该方法包括以下步骤：通过将其在碱性pH溶液中的悬浮液处理改性沸石Y，通过中和含有 溶液与含酸溶液; 过滤和洗涤回收的改性沸石Y固体，干燥并任选地煅烧改性沸石Y固体，将步骤d）的改性沸石Y固体在离子交换溶液中搅拌接触，任选蒸汽和/或煅烧改性的 沸石Y型化合物，用于获得含有改性沸石Y的催化剂。