公开(公告)号：US20240010937A1

公开(公告)日：2024-01-11

申请号：US18296457

申请日：2023-04-06

Applicant: UOP LLC

Inventor： Anton N. Mlinar ,  Stanley J. Frey ,  Geoffrey W. Fichtl ,  Matthew C. Cole ,  Charles P. Luebke ,  Joe R. Haas

IPC: C10G53/06 ,  C10C5/00 ,  C10G21/28 ,  B01D3/14 ,  B01D3/34

CPC classification number: C10G53/06 ,  C10C5/00 ,  C10G21/28 ,  B01D3/143 ,  B01D3/34 ,  B01D3/148 ,  C10G2300/1011

Abstract: A solvent stripping process has been developed for separating the pyrolysis oil in an extracted phase feed stream from an organic solvent used for extraction. The process involves using a stripping solvent to strip the organic solvent from the pyrolysis oil in a stripping column. The stripping column bottom stream comprising the pyrolysis oil and part of the stripping solvent can be separated into a vapor stream comprising the stripping solvent and a liquid stream comprising the pyrolysis and a portion of the stripping solvent. The stripping column overhead stream comprising the stripping solvent and the organic solvent can be separated in a recovery column into a recovery column overhead stream comprising the stripping solvent and a recovery column bottom stream comprising the organic solvent.

公开(公告)号：US10682629B2

公开(公告)日：2020-06-16

申请号：US16177849

申请日：2018-11-01

Applicant: UOP LLC

Inventor： Manuela Serban ,  Matthew C. Cole ,  Ellen Arnold ,  Guanghui Zhu

IPC: B01J21/04 ,  B01J23/62 ,  B01J35/08 ,  B01J35/00 ,  B01J35/10 ,  C07C5/333 ,  B01J23/96 ,  B01J38/02

Abstract: A catalyst for a selective conversion of hydrocarbons. The catalyst includes a first component selected from the group consisting of Group VIII noble metals and mixtures thereof, a second component selected from the group consisting of alkali metals or alkaline-earth metals and mixtures thereof, and a third component selected from the group consisting of tin, germanium, lead, indium, gallium, thallium and mixtures thereof. The catalyst is a support formed as a spherical catalyst particle with an average pore diameter between 200 to 350 Angstroms, a porosity of at least 75% and an apparent bulk density between 0.60 and 0.3 g/cc. Also, a process of using such a catalyst for a selective hydrocarbon conversion reaction and a process for regenerating such a catalyst by removing coke from same.

公开(公告)号：US10682628B2

公开(公告)日：2020-06-16

申请号：US16177840

申请日：2018-11-01

Applicant: UOP LLC

Inventor： Manuela Serban ,  Matthew C. Cole ,  Ellen Arnold ,  Guanghui Zhu

IPC: B01J23/62 ,  B01J21/04 ,  B01J35/08 ,  B01J35/00 ,  B01J35/10 ,  C07C5/333 ,  B01J23/96 ,  B01J38/02

Abstract: A catalyst for a selective conversion of hydrocarbons. The catalyst includes a first component selected from the group consisting of Group VIII noble metals and mixtures thereof, a second component selected from the group consisting of alkali metals or alkaline-earth metals and mixtures thereof, and a third component selected from the group consisting of tin, germanium, lead, indium, gallium, thallium and mixtures thereof. The catalyst is a support formed as a spherical catalyst particle with a median diameter between 1.6 mm and 2.5 mm and an apparent bulk density between 0.6 and 0.3 g/cc. Also a process of using such a catalyst for a selective hydrocarbon conversion reaction and a process for regenerating such a catalyst by removing coke from same.

公开(公告)号：US20190126250A1

公开(公告)日：2019-05-02

申请号：US16177848

申请日：2018-11-01

Applicant: UOP LLC

Inventor： Manuela Serban ,  Matthew C. Cole ,  Ellen Arnold ,  Guanghui Zhu

IPC: B01J23/62 ,  B01J21/04 ,  B01J35/08 ,  B01J35/00 ,  B01J35/10 ,  C07C5/333

Abstract: A catalyst for a selective conversion of hydrocarbons. The catalyst includes a first component selected from the group consisting of Group VIII noble metals and mixtures thereof, a second component selected from the group consisting of alkali metals or alkaline-earth metals and mixtures thereof, and a third component selected from the group consisting of tin, germanium, lead, indium, gallium, thallium and mixtures thereof. The catalyst is a support formed as a spherical catalyst particle with an average pore diameter between 200 to 350 Angstroms, a porosity of at least 75% and an apparent bulk density between 0.60 and 0.3 g/cc. Also, a process of using such a catalyst for a selective hydrocarbon conversion reaction and a process for regenerating such a catalyst by removing coke from same.

公开(公告)号：US12270001B2

公开(公告)日：2025-04-08

申请号：US18417156

申请日：2024-01-19

Applicant: UOP LLC

Inventor： Andrew Piotrowski ,  Ernest J. Boehm ,  John J. Senetar ,  Matthew C. Cole ,  Jeannie Mee Blommel ,  Christopher Procopi ,  Ian G. Horn ,  Andrew B. Chin

IPC: C10G69/00 ,  C10G50/00 ,  C10G69/12

Abstract: A process for preparing an olefin stream for oligomerization comprises fractionating an olefin stream to provide a light gas stream and an olefin rich stream. Oxygenates are absorbed from the olefin rich stream into a water wash stream to provide an oxygenate rich water wash stream and a washed olefin stream. The washed olefin stream can then be oligomerized.

公开(公告)号：US20240246890A1

公开(公告)日：2024-07-25

申请号：US18417177

申请日：2024-01-19

Applicant: UOP LLC

Inventor： Andrew Piotrowski ,  Ernest J. Boehm ,  John J. Senetar ,  Matthew C. Cole ,  Jeannie Mee Blommel ,  Christopher Procopi ,  Ian G. Horn ,  Andrew B. Chin

IPC: C07C5/08

CPC classification number: C07C5/08 ,  C07C2523/72

Abstract: A process for preparing an olefin stream for oligomerization comprises fractionating an olefin stream to provide a light gas stream and a olefin rich stream. The olefin rich stream is selectively hydrogenated to convert diolefins to mono-olefins and provide a mono-olefin stream and oligomerizing the mono-olefin stream over an oligomerization catalyst to provide an oligomerized stream.

公开(公告)号：US10981149B2

公开(公告)日：2021-04-20

申请号：US16817184

申请日：2020-03-12

Applicant: UOP LLC

Inventor： Manuela Serban ,  Matthew C. Cole ,  Clayton C. Sadler

IPC: B01J23/00 ,  B01J23/62 ,  B01J35/08 ,  C07C5/333

Abstract: Catalysts and processes for a selective conversion of hydrocarbons. The catalyst comprises: a first component selected from the group consisting of Group VIII noble metals and mixtures thereof, a modifier selected from the group consisting of alkali metals or alkaline-earth metals and mixtures thereof, and a third component selected from the group consisting of tin, germanium, lead, indium, gallium, thallium and mixtures thereof; and a support forming a catalyst particle comprising a plurality of pores. The catalyst has a modifier profile index in a range of 1 to 1.4 across the catalyst particle.

公开(公告)号：US20200298213A1

公开(公告)日：2020-09-24

申请号：US16817184

申请日：2020-03-12

Applicant: UOP LLC

Inventor： Manuela Serban ,  Matthew C. Cole ,  Clayton C. Sadler

IPC: B01J23/62 ,  B01J35/08 ,  C07C5/333

Abstract: Catalysts and processes for a selective conversion of hydrocarbons. The catalyst comprises: a first component selected from the group consisting of Group VIII noble metals and mixtures thereof, a modifier selected from the group consisting of alkali metals or alkaline-earth metals and mixtures thereof, and a third component selected from the group consisting of tin, germanium, lead, indium, gallium, thallium and mixtures thereof; and a support forming a catalyst particle comprising a plurality of pores. The catalyst has a modifier profile index in a range of 1 to 1.4 across the catalyst particle.

公开(公告)号：US20240342697A1

公开(公告)日：2024-10-17

申请号：US18471782

申请日：2023-09-21

Applicant: UOP LLC

Inventor： Jan De Ren ,  Matthew C. Cole ,  Richard A. Johnson, II ,  Ian G. Horn ,  Gregory R. Werba ,  Ernest J. Boehm ,  Michael J. Tobin

IPC: B01J38/12 ,  B01J38/40

CPC classification number: B01J38/12 ,  B01J38/40

Abstract: A process for regenerating catalyst from an MTO process is disclosed. The process comprises providing an oxygen stream and a preheated carbon dioxide recycle stream and mixing the oxygen stream and the preheated carbon dioxide recycle stream to provide a carbon dioxide rich oxidation stream. The carbon dioxide rich oxidation stream is passed to a regenerator unit to provide a carbon dioxide rich flue gas stream. The carbon dioxide rich flue gas stream is filtered to remove the catalyst fines to produce a filtered flue gas stream. A carbon dioxide recycle stream is taken from the filtered flue gas stream.

公开(公告)号：US20240247197A1

公开(公告)日：2024-07-25

申请号：US18417188

申请日：2024-01-19

Applicant: UOP LLC

Inventor： Andrew Piotrowski ,  Ernest J. Boehm ,  John J. Senetar ,  Matthew C. Cole ,  Jeannie Mee Blommel ,  Christopher Procopi ,  Ian G. Horn ,  Andrew B. Chin

IPC: C10G69/12

CPC classification number: C10G69/126 ,  C10G2300/1092 ,  C10G2300/805 ,  C10G2400/20

Abstract: A process is provided for preparing a hydrocarbon stream for oligomerization. The process strips dimethyl ether from an olefin stream using a stripping column. Lighter olefins such as C3− olefins are also removed. The C4+ olefins can then be sent for further processing including selective hydrogenation followed by oligomerization.