Abstract:
The present invention deals with activation and start-up procedures of catalysts for the deep HDS of middle distillates for producing ultra low sulfur diesel (ULSD), consisting of two in situ activation stages: at stage 1, TGA is applied, and at stage 2, DMDS is used; kerosene is the transport means at these stages, which are carried out under given temperature and pressure conditions, and feedstock and hydrogen flows at established times. After the activation of the catalyst in situ, the stabilization stage takes place under selected temperature and pressure conditions, feedstock and hydrogen flow at established times, with which the stabilization of the highly dispersed metallic sulfides is achieved and, in this way, the activity of the catalysts removing contaminants for the production of ULSD is increased.
Abstract:
A reaction apparatus, comprising: a reaction kettle; a circulation loop, comprising a circulation pipeline and a circulator pump provided on the circulation pipeline, a discharging end of the circulator pump being communicated with the top of the reaction kettle by means of a circulation valve and a charging end of the circulator pump being communicated with the bottom of the reaction kettle by means of a block valve; a feeding loop, comprising a feeding pipeline and a bypass pipeline, the feeding pipeline being provided between the block valve and the circulator pump and being communicated with the circulation pipeline, the bypass pipeline being provided with a control valve, and one end of the bypass pipeline being communicated with the discharging end of the circulator pump and the other end thereof being communicated with the bottom of the reaction kettle; and a discharging loop, comprising a discharging pipeline provided between the circulator pump and the circulation valve and communicated with the circulation pipeline, the discharging pipeline being provided with a discharging valve.
Abstract:
The invention concerns a process for the continuous treatment of an emulsion and/or a micro-emulsion assisted by an “expanded liquid” for the production of micro- and/or nano-particles or micro- and/or nano-spheres containing one or more active ingredients. In particular, a liquid solvent expanded by compressed or supercritical CO2 is contacted with an O/W emulsion, or alternatively a W/O emulsion or multiple emulsions, formed by an external phase that is itself a liquid expanded by compressed CO2. The expanded liquid forms a solution with the dispersed phase of the emulsion and extracts it inducing the formation of the desired particles of the dissolved compounds.The process is carried out in a counter-current packed column wherein the expanded emulsion is fed from the top, while the expanded liquid is fed from the bottom. Thanks to the presence of the expanded liquid, any deposition of the solid particles produced on the packing elements is avoided, thus preventing any column blockage. A suspension of micro-structured particles of the desired product can be collected continuously at the bottom of the column.
Abstract:
The present invention deals with activation and start-up procedures of catalysts for the deep HDS of middle distillates for producing ultra low sulfur diesel (ULSD), consisting of two in situ activation stages: at stage 1, TGA is applied, and at stage 2, DMDS is used; kerosene is the transport means at these stages, which are carried out under given temperature and pressure conditions, and feedstock and hydrogen flows at established times. After the activation of the catalyst in situ, the stabilization stage takes place under selected temperature and pressure conditions, feedstock and hydrogen flow at established times, with which the stabilization of the highly dispersed metallic sulfides is achieved and, in this way, the activity of the catalysts removing contaminants for the production of ULSD is increased.
Abstract:
The invention relates to a method for controlling a chemical reaction which creates a product, wherein at least one reactant that is present in a liquid phase is subjected to a pressure change.
Abstract:
The present invention generally relates to a microwave-assisted pyrolysis system comprised of a microwave chamber body (102); a black carbon platform (104) disposed inside the microwave chamber body for irradiating microwave radiation and absorbing microwave energy; a quartz microwave reactor (106) placed on the black carbon platform for receiving chemical precursor(s) and applying microwave irradiation for absorption of microwave energy thereby heating the black carbon platform for microwave-assisted pyrolysis of the received chemical precursor(s); a cooling unit (108) employed for regulating and maintaining a user-defined temperature level upon detecting the temperature inside the microwave reactor using a temperature sensor (110), if the temperature exceeds the optimum level, wherein the optimum temperature is defined on the type of precursors undergoing pyrolysis; and wherein if the heating temperature is raised extremely high, the cooling unit inside the microwave machine gets activated to bring down the temperature to the user-defined level.
Abstract:
The present invention describes a process for quenching a hydrothermal, dilute acid hydrolysis reaction of a biomass feedstock, wherein degradation of an aqueous monomer and/or oligomer sugar mixture is slowed down or stopped by flash cooling of the aqueous monomer and/or oligomer sugar mixture, and wherein the flash cooling ensures that a fraction of dissolved and volatile degradation byproducts are removed by a forming vapor stream, and wherein a lignin component, if present, is solidified into a structure with good de-watering characteristics, allowing for subsequent removal of the lignin component by separation, said process resulting in a hydrolyzed solution of sugar monomers and/or oligomers.
Abstract:
The invention concerns a process for the continuous treatment of an emulsion and/or a micro-emulsion assisted by an “expanded liquid” for the production of micro- and/or nano-particles or micro- and/or nano-spheres containing one or more active ingredients. In particular, a liquid solvent expanded by compressed or supercritical CO2 is contacted with an O/W emulsion, or alternatively a W/O emulsion or multiple emulsions, formed by an external phase that is itself a liquid expanded by compressed CO2. The expanded liquid forms a solution with the dispersed phase of the emulsion and extracts it inducing the formation of the desired particles of the dissolved compounds.The process is carried out in a counter-current packed column wherein the expanded emulsion is fed from the top, while the expanded liquid is fed from the bottom. Thanks to the presence of the expanded liquid, any deposition of the solid particles produced on the packing elements is avoided, thus preventing any column blockage. A suspension of micro-structured particles of the desired product can be collected continuously at the bottom of the column.