公开(公告)号：US08441250B2

公开(公告)日：2013-05-14

申请号：US12780088

申请日：2010-05-14

Applicant: Eric J. Markel ,  Timothy R. Lynn

Inventor： Eric J. Markel ,  Timothy R. Lynn

IPC: G01R1/06

CPC classification number: C08F10/00 ,  B01J8/1809 ,  B01J2208/00601 ,  B01J2219/0245 ,  C08F2400/02 ,  C08F2/34 ,  C08F2/002 ,  C08F2/00

Abstract: Disclosed is a method for using at least one static probe during polymerization in a fluid bed polymerization reactor system to monitor a coating on a surface of the reactor system and a distal portion of each static probe, wherein the coating is exposed to flowing fluid within the reactor system during the reaction. The surface may be a reactor bed wall (exposed to the reactor's fluid bed) and the coating is exposed to flowing, bubbling fluid within the fluid bed during the reaction. The method may include steps of: during the polymerization reaction, operating the static probe to generate a sequence of data values (“high speed data”) indicative of fluid flow variation (e.g., bubbling or turbulence), and determining from the high speed data at least one electrical property of the coating (e.g., of a portion of the coating on the distal portion of the static probe).

Abstract translation: 公开了一种在流化床聚合反应器系统中在聚合过程中使用至少一个静态探针以监测反应器系统的表面上的涂层和每个静态探针的远端部分的方法，其中涂层暴露于在 反应器系统。 表面可以是反应器床壁（暴露于反应器的流化床），并且涂层在反应期间暴露于流化床内的流动的起泡流体。 该方法可以包括以下步骤：在聚合反应期间，操作静态探针以产生指示流体流动变化（例如，起泡或湍流）的数据值序列（“高速数据”），并从高速数据 涂层的至少一个电性质（例如，静电探针的远端部分上的涂层的一部分）。

公开(公告)号：US06214757B1

公开(公告)日：2001-04-10

申请号：US09412997

申请日：1999-10-05

Applicant: Michael Schwartz ,  James H. White ,  Anthony F. Sammells

Inventor： Michael Schwartz ,  James H. White ,  Anthony F. Sammells

IPC: C07C204

CPC classification number: B01D69/145 ,  B01D53/228 ,  B01D53/326 ,  B01D67/0041 ,  B01D69/141 ,  B01D71/024 ,  B01D2323/08 ,  B01D2323/12 ,  B01D2325/10 ,  B01D2325/18 ,  B01J4/04 ,  B01J8/009 ,  B01J12/007 ,  B01J19/2475 ,  B01J23/002 ,  B01J23/83 ,  B01J35/0033 ,  B01J35/065 ,  B01J2208/00601 ,  B01J2219/00051 ,  B01J2219/00063 ,  B01J2219/0018 ,  B01J2219/00189 ,  B01J2523/00 ,  C01B3/36 ,  C01B3/386 ,  C01B13/0255 ,  C01B17/0465 ,  C01B2203/0261 ,  C01B2203/1011 ,  C01B2203/1035 ,  C01B2203/1041 ,  C01B2203/1052 ,  C01B2203/1064 ,  C01B2203/1082 ,  C01B2203/1241 ,  C01B2203/1258 ,  C01B2210/0046 ,  C01B2210/0051 ,  C01B2210/0062 ,  C01B2210/0071 ,  C01B2210/0075 ,  C01C3/0216 ,  H01M4/9033 ,  H01M4/9066 ,  H01M8/1231 ,  H01M8/1246 ,  Y02E60/525 ,  Y02P20/52 ,  Y02P70/56 ,  B01J2523/24 ,  B01J2523/32 ,  B01J2523/3706 ,  B01J2523/842 ,  B01J2523/72 ,  B01J2523/31 ,  B01J2523/822 ,  B01J2523/847 ,  B01J2523/845

Abstract: A process for production of synthesis gas employing a catalytic membrane reactor wherein the membrane comprises a mixed metal oxide material.

Abstract translation: 一种使用催化膜反应器生产合成气的方法，其中所述膜包括混合金属氧化物材料。

公开(公告)号：US20140076816A1

公开(公告)日：2014-03-20

申请号：US14116011

申请日：2012-05-03

Applicant: Christine Haas ,  David Andrew Prince ,  Amarjeet Bassi

Inventor： Christine Haas ,  David Andrew Prince ,  Amarjeet Bassi

IPC: B01J47/10 ,  B01J49/00

CPC classification number: B01J47/10 ,  B01J8/20 ,  B01J8/28 ,  B01J8/388 ,  B01J47/026 ,  B01J49/10 ,  B01J49/50 ,  B01J2208/00592 ,  B01J2208/00601 ,  C02F1/42

Abstract: A novel apparatus for an ion exchange system is provided. The apparatus comprises a first column for housing a first fluidized bed through which particles are flowed countercurrently to an ion-containing fluid to yield ion-loaded particles, a second column through which the ion-loaded particles are flowed countercurrently to an eluent fluid to yield regenerated particles, and a transport section which transfers the regenerated particles for re-introduction into the first column to repeat the ion exchange cycle in a continuous manner. A continuous method of ion exchange is also provided.

Abstract translation: 提供了一种用于离子交换系统的新型装置。 该装置包括用于容纳第一流化床的第一柱，通过该第一流化床，颗粒与含离子的流体逆流流动以产生离子负载的颗粒，第二塔，离子负载的颗粒通过该第二柱与洗脱液流动逆流以产生 再生粒子和输送部，其将再生粒子转移到第一塔中，以连续的方式重复离子交换循环。 还提供了连续的离子交换方法。

公开(公告)号：US07931870B2

公开(公告)日：2011-04-26

申请号：US12104055

申请日：2008-04-16

Applicant: Kazumasa Takada ,  Norihiko Toyonaga

Inventor： Kazumasa Takada ,  Norihiko Toyonaga

IPC: B32B27/04

CPC classification number: C01B3/384 ,  B01J8/025 ,  B01J8/0278 ,  B01J8/0285 ,  B01J2208/00061 ,  B01J2208/00168 ,  B01J2208/00309 ,  B01J2208/00504 ,  B01J2208/0053 ,  B01J2208/00601 ,  B01J2219/002 ,  B01J2219/00211 ,  B01J2219/00231 ,  C01B3/48 ,  C01B2203/0233 ,  C01B2203/0283 ,  C01B2203/044 ,  C01B2203/047 ,  C01B2203/066 ,  C01B2203/0816 ,  C01B2203/0822 ,  C01B2203/0827 ,  C01B2203/1619 ,  C01B2203/1685 ,  C01B2203/1695 ,  H01M8/0618 ,  H01M8/0662 ,  Y02P20/128

Abstract: A controller for a reformer that: changes the supply quantity of at least either one of combustible gas and combustion oxidizing gas supplied to a combustion section; detects a change which is caused in the combustion state of the combustion section as a result of a change of the supply quantity; and checks the combustion state which arose at the combustion section before the change based on the previously detected detection result. Thus, a gone-out state of the combustion section can be reliably judged with a low cost device, and the combustion state of the combustion section in the reformer of a fuel cell system can be adjusted to an optimum combustion state.

Abstract translation: 一种重整器的控制器，其特征在于：改变供给至燃烧部的可燃气体和燃烧氧化气体中的至少一方的供给量; 检测由于供给量的变化导致燃烧部的燃烧状态引起的变化; 并基于先前检测到的检测结果来检查在变化之前在燃烧部分产生的燃烧状态。 因此，能够以低成本的装置可靠地判断燃烧部的熄灭状态，能够将燃料电池系统的重整器中的燃烧部的燃烧状态调整为最佳燃烧状态。

公开(公告)号：US11717799B2

公开(公告)日：2023-08-08

申请号：US17593394

申请日：2020-03-20

Applicant: YMIR TECHNOLOGIES EHF.

Inventor： Oddur Ingolfsson ,  Asgeir Matthiasson ,  Eirikur Bjarnason ,  Sigurdur Ingolfsson

IPC: B01J8/02 ,  B01J8/00 ,  C11C3/00 ,  C10L1/02 ,  B01D17/02 ,  B01D15/36 ,  B01D3/06

CPC classification number: B01J8/02 ,  B01D3/06 ,  B01D15/361 ,  B01D17/0214 ,  B01J8/001 ,  B01J8/0278 ,  B01J8/0285 ,  C10L1/026 ,  C11C3/003 ,  B01J2208/00017 ,  B01J2208/00539 ,  B01J2208/00601 ,  C10L2200/0476 ,  C10L2270/026

Abstract: Provided is a system and method for producing and purifying biodiesel. In particular, the system comprises a tandem arrangement of at a modular biodiesel reactor and a continuous flow separation and purification unit. The system can further comprise an evaporation unit that is placed between the biodiesel reactor and the continuous flow separation and purification unit.

公开(公告)号：US09643175B2

公开(公告)日：2017-05-09

申请号：US14116011

申请日：2013-11-06

Applicant: Renix Inc.

Inventor： Christine Haas ,  David Andrew Prince ,  Amarjeet Bassi

IPC: B01J47/10 ,  B01J49/00 ,  B01J47/026 ,  C02F1/42 ,  B01J8/20 ,  B01J8/28 ,  B01J8/38 ,  B01J49/10 ,  B01J49/50

CPC classification number: B01J47/10 ,  B01J8/20 ,  B01J8/28 ,  B01J8/388 ,  B01J47/026 ,  B01J49/10 ,  B01J49/50 ,  B01J2208/00592 ,  B01J2208/00601 ,  C02F1/42

Abstract: A novel apparatus for an ion exchange system is provided. The apparatus comprises a first column for housing a first fluidized bed through which particles are flowed countercurrently to an ion-containing fluid to yield ion-loaded particles, a second column through which the ion-loaded particles are flowed countercurrently to an eluent fluid to yield regenerated particles, and a transport section which transfers the regenerated particles for re-introduction into the first column to repeat the ion exchange cycle in a continuous manner. A continuous method of ion exchange is also provided.

公开(公告)号：US06355093B1

公开(公告)日：2002-03-12

申请号：US08960182

申请日：1997-10-29

Applicant: Michael Schwartz ,  James H. White ,  Anthony F. Sammells

Inventor： Michael Schwartz ,  James H. White ,  Anthony F. Sammells

IPC: B01J3500

CPC classification number: C01B13/0255 ,  B01D53/228 ,  B01D53/326 ,  B01D67/0041 ,  B01D69/141 ,  B01D71/024 ,  B01D2323/08 ,  B01D2323/12 ,  B01D2325/10 ,  B01D2325/18 ,  B01J8/009 ,  B01J8/0278 ,  B01J12/007 ,  B01J19/2475 ,  B01J23/002 ,  B01J23/83 ,  B01J23/8946 ,  B01J35/0033 ,  B01J35/065 ,  B01J2208/00601 ,  B01J2219/00051 ,  B01J2219/00063 ,  B01J2219/0018 ,  B01J2219/00189 ,  B01J2523/00 ,  C01B3/36 ,  C01B3/386 ,  C01B17/0465 ,  C01B2203/0261 ,  C01B2203/1011 ,  C01B2203/1035 ,  C01B2203/1041 ,  C01B2203/1052 ,  C01B2203/1064 ,  C01B2203/1082 ,  C01B2203/1241 ,  C01B2203/1258 ,  C01B2210/0046 ,  C01C3/0216 ,  H01M4/9033 ,  H01M4/9066 ,  H01M8/1231 ,  H01M8/1246 ,  Y02E60/525 ,  Y02P20/52 ,  Y02P70/56 ,  B01J2523/24 ,  B01J2523/3706 ,  B01J2523/845 ,  B01J2523/32 ,  B01J2523/842 ,  B01J2523/72 ,  B01J2523/31

Abstract: This invention relates to catalytic reactor membranes having a gas-impermeable membrane for transport of oxygen anions. The membrane has an oxidation surface and a reduction surface. The membrane is coated on its oxidation surface with an adherent catalyst layer and is optionally coated on its reduction surface with a catalyst that promotes reduction of an oxygen-containing species (e.g., O2, NO2, SO2, etc.) to generate oxygen anions on the membrane. The reactor has an oxidation zone and a reduction zone separated by the membrane. A component of an oxygen containing gas in the reduction zone is reduced at the membrane and a reduced species in a reactant gas in the oxidation zone of the reactor is oxidized. The reactor optionally contains a three-dimensional catalyst in the oxidation zone. The adherent catalyst layer and the three-dimensional catalyst are selected to promote a desired oxidation reaction, particularly a partial oxidation of a hydrocarbon.

Abstract translation: 本发明涉及具有用于输送氧阴离子的不透气膜的催化反应器膜。 膜具有氧化表面和还原表面。 用粘附的催化剂层将膜涂覆在其氧化表面上，并且任选地在其还原表面上用促进含氧物质（例如，O 2，NO 2，SO 2等）还原以产生氧阴离子的催化剂 膜。 反应器具有由膜分离的氧化区和还原区。 还原区中的含氧气体的成分在膜处被还原，并且在反应器的氧化区中的反应气体中的还原物质被氧化。 反应器任选地在氧化区含有三维催化剂。 选择粘附催化剂层和三维催化剂以促进所需的氧化反应，特别是烃的部分氧化。

公开(公告)号：US08420023B2

公开(公告)日：2013-04-16

申请号：US12940792

申请日：2010-11-05

Applicant: Bruce Tatarchuk ,  Hongyun Yang ,  Ranjeeth Kalluri ,  Donald Cahela

Inventor： Bruce Tatarchuk ,  Hongyun Yang ,  Ranjeeth Kalluri ,  Donald Cahela

IPC: B01J8/02 ,  B01J19/00

CPC classification number: B01J19/2495 ,  B01J19/2405 ,  B01J19/30 ,  B01J20/28004 ,  B01J20/28028 ,  B01J2208/00017 ,  B01J2208/00601 ,  B01J2219/30475 ,  B01J2219/30483

Abstract: A vessel packed with a microfibrous media made of micron-sized highly conductive fibers, which are able (and may be used) to immobilize various reactive materials including catalysts, sorbents, electrocatalysts, and other chemically reactive solids. The vessel enables fine temperature control and a uniform temperature profile for a range of highly endothermic or exothermic chemical reactions, sorptions, separation processes, mixing operations, and heat transfer applications.

Abstract translation: 填充有由微米尺寸的高导电纤维制成的微纤维介质的容器，其能够（并且可以用于）固定各种反应性材料，包括催化剂，吸附剂，电催化剂和其它化学反应性固体。 该容器能够对一系列高度吸热或放热的化学反应，吸附，分离过程，混合操作和热传递应用进行精细的温度控制和均匀的温度分布。

公开(公告)号：US20080268309A1

公开(公告)日：2008-10-30

申请号：US12104055

申请日：2008-04-16

Applicant: Kazumasa TAKADA ,  Norihiko TOYONAGA

Inventor： Kazumasa TAKADA ,  Norihiko TOYONAGA

IPC: H01M8/06 ,  G05B11/00 ,  B01J8/00 ,  C01B3/24

CPC classification number: C01B3/384 ,  B01J8/025 ,  B01J8/0278 ,  B01J8/0285 ,  B01J2208/00061 ,  B01J2208/00168 ,  B01J2208/00309 ,  B01J2208/00504 ,  B01J2208/0053 ,  B01J2208/00601 ,  B01J2219/002 ,  B01J2219/00211 ,  B01J2219/00231 ,  C01B3/48 ,  C01B2203/0233 ,  C01B2203/0283 ,  C01B2203/044 ,  C01B2203/047 ,  C01B2203/066 ,  C01B2203/0816 ,  C01B2203/0822 ,  C01B2203/0827 ,  C01B2203/1619 ,  C01B2203/1685 ,  C01B2203/1695 ,  H01M8/0618 ,  H01M8/0662 ,  Y02P20/128

Abstract: A controller for a reformer includes supply quantity changing means for changing the supply quantity of at least either one of combustible gas and combustion oxidizing gas supplied to a combustion section, a combustion state change detecting means for detecting a change which is caused in the combustion state of the combustion section as a result that the change of the supply quantity is brought by the supply quantity changing means, based on a detection result from the combustion state detecting means, and combustion state checking means for checking the combustion state which arose at the combustion section before the change brought by the supply quantity changing means, based on a detection result from the combustion state change detecting means. Thus, the gone-out state of the combustion section can be reliably judged with the construction of a low cost, and the combustion state of the combustion section in the reformer of a fuel cell system can be adjusted to an optimum combustion state.

Abstract translation: 一种用于重整器的控制器包括用于改变供应到燃烧部分的可燃气体和燃烧氧化气体中的至少一个的供给量的供给量改变装置，用于检测在燃烧状态下引起的变化的燃烧状态变化检测装置 作为燃烧部的结果，通过供给量变更单元，根据来自燃烧状态检测单元的检测结果来提供供给量的变化，以及用于检查在燃烧时产生的燃烧状态的燃烧状态检查单元 基于来自燃烧状态变化检测装置的检测结果，在由供给量变更装置进行的变更之前的截面。 因此，能够以低成本的结构可靠地判断燃烧部的脱出状态，并且可以将燃料电池系统的重整器中的燃烧部的燃烧状态调整为最佳燃烧状态。

公开(公告)号：US6165431A

公开(公告)日：2000-12-26

申请号：US286829

申请日：1999-04-06

Applicant: Richard Mackay ,  Michael Schwartz ,  Anthony F. Sammells

Inventor： Richard Mackay ,  Michael Schwartz ,  Anthony F. Sammells

IPC: B01D53/22 ,  B01D53/32 ,  B01D71/02 ,  B01J4/04 ,  B01J8/00 ,  B01J12/00 ,  B01J19/00 ,  B01J19/24 ,  B01J23/00 ,  B01J23/83 ,  B01J35/00 ,  B01J35/06 ,  C01B3/36 ,  C01B3/38 ,  C01B13/02 ,  C01B17/04 ,  C01C3/02 ,  H01M8/12 ,  C01B13/00

CPC classification number: C01B13/0255 ,  B01D53/228 ,  B01D53/326 ,  B01D67/0041 ,  B01D69/141 ,  B01D71/024 ,  B01D2323/08 ,  B01D2323/12 ,  B01D2325/10 ,  B01D2325/18 ,  B01J8/009 ,  B01J12/007 ,  B01J19/2475 ,  B01J23/002 ,  B01J23/83 ,  B01J35/0033 ,  B01J35/065 ,  B01J2208/00601 ,  B01J2219/00051 ,  B01J2219/00063 ,  B01J2219/0018 ,  B01J2219/00189 ,  B01J2523/00 ,  C01B3/36 ,  C01B3/386 ,  C01B17/0465 ,  C01B2203/0261 ,  C01B2203/1011 ,  C01B2203/1035 ,  C01B2203/1041 ,  C01B2203/1052 ,  C01B2203/1064 ,  C01B2203/1082 ,  C01B2203/1241 ,  C01B2203/1258 ,  C01B2210/0046 ,  C01C3/0216 ,  H01M4/9033 ,  H01M4/9066 ,  H01M8/1231 ,  H01M8/1246 ,  Y02E60/525 ,  Y02P20/52 ,  Y02P70/56 ,  B01J2523/24 ,  B01J2523/32 ,  B01J2523/3706 ,  B01J2523/842 ,  B01J2523/845 ,  B01J2523/31

Abstract: This invention provides mixed conducting metal oxides particularly useful for the manufacture of catalytic membranes for gas-phase oxygen separation processes. The materials of this invention have the general formula:A.sub.x A'.sub.x A".sub.2-(x+x') B.sub.y B'.sub.y B".sub.2-(y+y') O.sub.5+z ;wherex and x' are greater than 0;y and y' are greater than 0;x+x' is less than or equal to 2;y+y' is less than or equal to 2;z is a number that makes the metal oxide charge neutral;A is an element selected from the f block lanthanide elements; A' is an element selected from Be, Mg, Ca, Sr, Ba and Ra;A" is an element selected from the f block lanthanides or Be, Mg, Ca, Sr, Ba and Ra; B is an element selected from the group consisting of Al, Ga, In or mixtures thereof; andB' and B" are different elements and are independently selected from the group of elements Mg or the d-block transition elements.The invention also provides methods for oxygen separation and oxygen enrichment of oxygen deficient gases which employ mixed conducting metal oxides of the above formula. Examples of the materials used for the preparation of the membrane includeA.sub.x Sr.sub.x' B.sub.y Fe.sub.y' Co.sub.2-(y+y') O.sub.5+z,wherex is about 0.3 to about 0.5,x' is about 1.5 to about 1.7,y is 0.6,y' is between about 1.0 and 1.4 andB is Ga or Al.

Abstract translation: 本发明提供了特别可用于制造用于气相氧分离方法的催化膜的混合导电金属氧化物。 本发明的材料具有以下通式：AxA'xA'2（x + x'）ByB''B'2-（y + y'）O5 + z; 其中x和x'大于0; y和y'大于0; x + x'小于或等于2; y + y'小于或等于2; z是使金属氧化物电荷中性的数字; A是选自f嵌段镧系元素的元素; A'是选自Be，Mg，Ca，Sr，Ba和Ra的元素; A“是选自f嵌段镧系元素或Be，Mg，Ca，Sr，Ba和Ra的元素; B是选自Al，Ga，In或其混合物的元素; 并且B'和B“是不同的元素，并且独立地选自元素组Mg或d嵌段过渡元素。 本发明还提供使用上述式的混合导电金属氧化物的氧气分离和缺氧气体的富氧方法。 用于制备膜的材料的实例包括AxSrx'ByFey'Co2-（y + y'）O5 + z，其中x为约0.3至约0.5，x'为约1.5至约1.7，y为0.6， y'在约1.0和1.4之间，B是Ga或Al。