公开(公告)号：JP2001021927A

公开(公告)日：2001-01-26

申请号：JP2000156226

申请日：2000-05-26

Applicant: BASF AG

Inventor： BAUER STEPHAN ,  BRONSTERT BERND ,  MOEHWALD HELMUT DR ,  NEUSS MICHAEL ,  BURKHARDT UWE

IPC: C08J5/18 ,  C08K3/00 ,  C08K5/00 ,  C08K7/16 ,  C08L101/12 ,  G02F1/15

Abstract: PROBLEM TO BE SOLVED: To obtain a polymer solid electrolyte which has satisfactory transparency, conductivity and mechanical characteristics and which can be made to possess into an easy aspect for an electrochromic device by incorporating a polymer binder, filler, conductive salt, plasticizer to convert ions into a solvent, and other additives as necessary, and specifying each of the transmittance for light, conductivity, and glass transition temperature. SOLUTION: This electrolyte contains a polymer binder, filler having 1 nm to 20 nm primary grain size, conductive salt, plasticizer to convert ions into a solvent and other selective additives and auxiliary agents, and has higher than 80% transmittance for light, higher than 10-6 S/cm conductivity at 20 deg.C and lower than -30 deg.C glass transition temperature Tg. As for the polymer binder, any polymer having proper transparency which can be subjected to thermoplastic treatment can be used, and a thermoplastic resin having higher than 80% trasmittance for light in the UV/VIS region is especially suitable. The filler is preferably an inorganic filler, having primary grain size in the range of 1 nm to 300 nm.

公开(公告)号：WO0127185A3

公开(公告)日：2001-12-06

申请号：PCT/EP0009628

申请日：2000-10-02

Applicant: BASF AG ,  BAUER STEPHAN ,  GROSCH GEORG HEINRICH ,  TISCHER GERLINDE ,  HARRE KATHRIN ,  BAUM EVA ,  OSTROWSKI THOMAS ,  LORENZ REINHARD ,  PRETZSCH REGINA ,  PCOLINSKI MICHAEL ,  DINSCH STEFAN ,  ROTERMUND INGE

Inventor： BAUER STEPHAN ,  GROSCH GEORG HEINRICH ,  TISCHER GERLINDE ,  HARRE KATHRIN ,  BAUM EVA ,  OSTROWSKI THOMAS ,  LORENZ REINHARD ,  PRETZSCH REGINA ,  PCOLINSKI MICHAEL ,  DINSCH STEFAN ,  ROTERMUND INGE

IPC: C08G65/12 ,  C08G18/40 ,  C08G18/42 ,  C08G18/48 ,  C08G65/26 ,  C08G81/00 ,  C08L71/02 ,  C08G63/66

CPC classification number: C08G81/00 ,  C08G18/4018 ,  C08G18/42 ,  C08G18/4261 ,  C08G65/2609 ,  C08G65/2663 ,  C08G2101/0008 ,  C08G2101/0083 ,  C08G2130/00 ,  C08L71/02 ,  C08L2666/18

Abstract: The invention relates to polyester-polyether block copolymers which can be produced by the catalytically induced attachment of alkylene oxides to H functional starting materials. Said copolymers are characterised in that polyester alcohols are used as the H functional starting materials and multi-metal cyanide compounds are used as the catalysts.

Abstract translation: 本发明涉及通过将烯化氧催化加成到H-官能起始物质上而制备的聚酯 - 聚醚嵌段共聚物，其特征在于用作H-官能起始物质聚酯醇和作为多金属氰化物催化剂的催化剂。

公开(公告)号：WO9915577B1

公开(公告)日：1999-05-20

申请号：PCT/EP9805538

申请日：1998-09-01

Applicant: BASF AG ,  BAUER STEPHAN ,  CZECH ERWIN ,  NEUSS MICHAEL

Inventor： BAUER STEPHAN ,  CZECH ERWIN ,  NEUSS MICHAEL

IPC: C08G63/02 ,  C08G81/02 ,  C08L25/02 ,  C08L77/00 ,  G03G9/087

CPC classification number: G03G9/08793 ,  C08G63/02 ,  C08G81/024 ,  C08L25/02 ,  C08L77/00 ,  G03G9/08708 ,  G03G9/08728 ,  C08L2666/14 ,  C08L25/00

Abstract: The invention relates to a method for producing a polymer composition in which at least 1) a polymerization of a mixture comprised of a) from 60 to 99.999 wt. % styrene or a styrene derivative of general formula (I), wherein R1, R2, R3 are each independent of one another, represent hydrogen, methyl or ethyl, and denote n 1 or 2 or a mixture of two or more thereof; b) 0 to 40 wt. % of a C1-C12 alkyl ester of acrylic or methacrylic acid, acrylonitrile or methacrylonitrile, acrylamide or methacrylamide which can be substituted on the amide nitrogen by one or two C1-C4 alkyl groups, maleinic acid anhydride or maleinic acid imide, which can be substituted on the imide nitrogen by one C1-C4 alkyl group or a mixture thereof; and c) 0 to 20 wt. % of one or more hydroxy containing acrylate or methacrylate derivatives; d) 0.001 to 20 wt. % of a monomer comprising two or more radical polymerizable functional groups as a cross-linker to obtain the prepolymer A, whereby, when the monomer component (c) is absent, hydroxyl groups in A are incorporated by using regulators containing hydroxyl groups. 2) A polycondensation of a mixture is carried out in which said mixture is comprised of alpha ) 5 to 95 wt. % of the prepolymer A, beta ) 0 to 95 wt. % of one polyol, one polyester or one polamide or a mixture thereof, and gamma ) 5 to 95 wt. % of at least one aliphatic or aromatic carboxylic acid with at least two carboxylic groups or esters of C1-C20 hydrocarbon alcohols in the molecule or at least one anhydride or a mixture thereof.

Abstract translation: 本发明涉及一种用于制备聚合物组合物，以及那些其中至少1）的苯乙烯或通式（I）的苯乙烯衍生物的）60至99.999重量.-％的混合物的聚合，其中R1，R2，R3 各自彼此独立地代表氢，甲基或乙基，n是1或2，或两种或更多种的混合物; B）0至40重量C1至丙烯酸或甲基丙烯酸，丙烯腈或甲基丙烯腈，丙烯酰胺或甲基丙烯酰胺的C 12烷基酯，其可以是在酰胺氮被1或2个C 1 -C 4取代的烷基的％，马来酸酐 或可被C1至在酰亚胺氮，或它们的混合物C4烷基取代的马来酰亚胺; 和c）0至20重量含有丙烯酸或甲基丙烯酸衍生物的一个或多个羟基的％; D）重量具有两个或更多个可自由基聚合的官能团的作为交联剂的预聚物A，其中（在不存在单体成分）的羟基基团通过使用含羟基的调节Ç并入A中的单体的0001-20％; 和2）从5至95重量多元醇，聚酯或聚酰胺或它们的混合物，和γ）％的阿尔法的混合物的缩聚％）重量％的预聚物A的.-％，β）从0至95：5〜95重量。 - ％进行至少一种脂肪族或在分子中具有至少两个羧基基团或C 1的酯至C20 Kohlenwasserstoffalkoholaten芳族羧酸或至少一种酐或它们的混合物。

公开(公告)号：WO0074844A8

公开(公告)日：2001-03-29

申请号：PCT/EP0004572

申请日：2000-05-19

Applicant: BASF AG ,  GROSCH GEORG HEINRICH ,  HARRE KATHRIN ,  ERBES JOERG ,  LORENZ REINHARD ,  BAUER STEPHAN ,  OSTROWSKI THOMAS ,  BAUM EVA ,  JUNGE DIETER

Inventor： GROSCH GEORG HEINRICH ,  HARRE KATHRIN ,  ERBES JOERG ,  LORENZ REINHARD ,  BAUER STEPHAN ,  OSTROWSKI THOMAS ,  BAUM EVA ,  JUNGE DIETER

IPC: B01J27/26 ,  C08G65/26 ,  C08G65/10

CPC classification number: C08G65/2663 ,  B01J27/26

Abstract: The invention relates to multi-metal cyanide compounds of the general formula (I). In said formula: M represents at least one metal ion, selected from the group containing Zn , Fe , Co , Ni , Mn , Pb , Fe , Mo , Mo , Al , V , Sr , W , W , Cu , Cr , Cr , Cd , Hg , Pd , Pt , V , Mg , Ca , Ba ; M represents at least one metal ion, selected from the group containing Fe , Fe , Co , Cr , Mn , Mn , Rh , Ru , Ru , V , V , Co , Ir and Cr and M is different from M ; X represents at least one anion, selected from the group containing halide, hydroxide, sulphate, carbonate, cyanide, thiocyanate, isocyanate, carboxylate, in particular, formiate, acetate, propionate, oxalate, nitrate; A represents at least one anion, selected from the group containing halide, hydroxide, sulphate, carbonate, cyanate, thiocyanate, isocyanate, carboxylate or nitrate, in particular, cyanide; a, b, c and d are whole or fractional numbers which are selected in such a way, that the electroneutrality of the cyanide compound is guaranteed, whereby a, b and d are greater than zero and c is greater than or equal to zero; e is a whole or fractional number greater than zero and h is a whole or fractional number greater than or equal to zero; and f and g are whole or fractional numbers which are selected in such a way that the electroneutrality of M fXg is guaranteed.

Abstract translation: 涉及多金属的式（I）的氰化：M <1> [M <2>（CN）BAC] D * E中号<1> FXG * H 2 O，其中M <1>，选自Zn <中选择的至少一种金属离子2+ >，铁<2+>，钴<3+>，镍<2+>，锰<2+>，钴<2+>，锡<2+>，铅<2+>，铁<3+> 沫<4+>，莫<6+>，铝<3+>，V <5+>，SR <2+>，W <4+>，W <6+>，铜<2+>，铬< 2+>，铬<3+>，镉<2+>，汞<2+>，钯<2+>，铂<2+>，V <2+>，镁<2+>，钙<2+ >，钡<2+>; 中号<2>的至少一种金属选自Fe <2+>，铁<3+>，钴<3+>，铬<3+>，锰<2+>，锰<3+>，铑<3+ >，茹<2+>，钌<3+>，V <4+>，V <5+>，钴<2+>，IR <3+>和Cr <2+>和M <2>不同 是M <1>的; X是至少一种阴离子选自卤化物，氢氧化物，硫酸盐，碳酸盐，氰化物，硫氰酸盐，异氰酸酯，羧酸盐中，特别是甲酸盐，乙酸盐，丙酸盐，草酸盐，硝酸盐; 甲至少一个阴离子选择卤化物，氢氧化物，硫酸盐，碳酸盐，氰酸盐，硫氰酸盐，异氰酸酯，羧酸盐，或硝酸盐，特别是氰化装置; 并且a，b，c和d是被选择的整数或分数，使得氰化物化合物的电中性保证，其中a，b和d是大于零，而c是大于或等于零，并且f和g是整数或分数 是被选择使得M <1> FXG的Elektoneutralität保证数字。

公开(公告)号：WO9919917A3

公开(公告)日：1999-06-24

申请号：PCT/EP9806394

申请日：1998-10-08

Applicant: BASF AG ,  GS JAPAN STORAGE ,  BAUER STEPHAN ,  BRONSTERT BERND ,  MOEHWALD HELMUT ,  STEPHAN OSKAR ,  TUKAMOTO HISASHI

Inventor： BAUER STEPHAN ,  BRONSTERT BERND ,  MOEHWALD HELMUT ,  STEPHAN OSKAR ,  TUKAMOTO HISASHI

IPC: H01G9/155 ,  C09K9/02 ,  H01B5/14 ,  H01G9/02 ,  H01G9/04 ,  H01M2/16 ,  H01M4/13 ,  H01M4/48 ,  H01M4/485 ,  H01M4/62 ,  H01M6/18 ,  H01M6/40 ,  H01M10/0525 ,  H01M10/0565 ,  H01M10/0569 ,  H01M10/36 ,  H01M10/40 ,  H01M10/04

CPC classification number: H01M4/13 ,  C09K9/02 ,  H01G9/02 ,  H01G9/04 ,  H01M2/164 ,  H01M2/1673 ,  H01M4/0435 ,  H01M4/485 ,  H01M4/62 ,  H01M4/622 ,  H01M6/188 ,  H01M6/40 ,  H01M10/0525 ,  H01M10/0565 ,  H01M10/0569 ,  H01M2300/0085

Abstract: A composite comprises Aa) at least one first layer which comprises a mixture Ia, comprising a mix IIa consisting of a) from 1 to 95 % by weight of a solid III, preferably a basic solid III, having a primary particle size of from 5 nm to 20 mu m and b) from 5 to 99 % by weight of a polymeric composition IV obtainable by polymerization of b1) from 5 to 100 % by weight, based on the composition IV, of a condensation product V of alpha ) at least one compound VI which is able to react with a carboxylic acid or a sulfonic acid or a derivative or a mixture of two or more thereof, and beta ) at least 1 mol per mol of the compound VI of a carboxylic acid or sulfonic acid VII which contains at least one free-radically polymerizable functional group, or a derivative thereof or a mixture of two or more thereof, and b2) from 0 to 95 % by weight, based on the composition IV, of a further compound VIII having a mean molecular weight (number average) of at least 5000 and polyether segments in the main chain or a side chain, where the proportion by weight of the mix IIa in the mixture Ia is from 1 to 100 % by weight, and the layer is free of an electron-conducting, electrochemically active compound, and B) at least one second layer which comprises an electron-conducting, electrochemically active compound, wherein the first layer or layers and the second layer or layers are joined to one another by one of the two methods V1 or V2: V1) Lamination of the first layer or layers with the second layer or layers under the action of heat or pressure or under the action of heat and pressure, or V2 Corona treatment of the first layer or layers, the second layer or layers or the first layer or layers and the second layer or layers and subsequent bringing together of the corona-treated first layer or layers with the corona-treated or untreated second layer or layers.

Abstract translation: 复合材料包括Aa）至少一个包含混合物Ia的第一层，其包含混合物IIa，混合物IIa由以下组分组成：a）1至95重量％的固体III，优选碱性固体III，其初级粒度为5 nm至20μm，和b）5至99重量％的聚合物组合物IV，其可通过以b1）5至100重量％（基于组合物IV）将α缩合产物V至少 一种化合物VI，其能够与羧酸或磺酸或其两种或多种的衍生物或其混合物反应，并且β）每摩尔化合物VI至少1摩尔的羧酸或磺酸VII，其中 含有至少一个可自由基聚合的官能团，或其衍生物或其两种或多种的混合物，和b2）0至95重量％（基于组合物IV）的另一种化合物VIII具有平均分子量 重量（数均）至少5000和聚醚片段在。 n链或侧链，其中混合物Ia中混合物IIa的重量比例为1至100重量％，并且该层不含电子传导的电化学活性化合物，和B）至少一个 第二层，其包括电子传导的电化学活性化合物，其中第一层或第二层或第二层或两层通过两种方法V1或V2之一彼此连接：V1）第一层或第二层与第 在热或压力作用下或在热和压力的作用下的第二层或第二层，或V2电晕处理第一层或第二层或第二层或第一层或第二层或第二层或第二层或 随后将电晕处理的第一层或多层与电晕处理或未经处理的第二层或多层组合在一起。

公开(公告)号：PL205216B1

公开(公告)日：2010-03-31

申请号：PL35321300

申请日：2000-08-23

Applicant: BASF AG

Inventor： HARRE KATHRIN ,  LORENZ REINHARD ,  GROSCH GEORG HEINRICH ,  ERBES JOERG ,  JUNGE DIETER ,  BAUER STEPHAN ,  BAUM EVA ,  OSTROWSKI THOMAS

IPC: C08G65/10 ,  C08G18/48 ,  C08G65/26 ,  C08G65/28

公开(公告)号：MXPA06014496A

公开(公告)日：2007-03-23

申请号：MXPA06014496

申请日：2005-06-22

Applicant: BASF AG

Inventor： BAUER STEPHAN ,  OSTROWSKI THOMAS ,  WINKLER JURGEN ,  LOFFLER ACHIM

IPC: C08G65/00

Abstract: La invencion proporciona un proceso para la preparacion continua de alcoholes de polieter mediante la adicion de oxidos de alquileno a sustancias iniciadoras funcionales de H usando un catalizador de DMC, que comprende las etapas de: a) preparar un precursor por la dosificacion continua de una sustancia iniciadora, funcional de H, un oxido de alquileno o una mezcla de al menos dos oxidos de alquileno y la cantidad requerida del catalizador de DMC en un reactor continuo, b) extraer continuamente el precursor de la etapa a) del reactor, c) dosificar continuamente el producto de la etapa a) , un oxido de alquileno diferente de aquel en la etapa a) o una mezcla de al menos dos oxidos de alquileno diferentes de aquel en la etapa a) y, si es apropiado, la cantidad requerida del catalizador de DMC en un reactor continuo adicional.

公开(公告)号：CA2394091C

公开(公告)日：2007-01-30

申请号：CA2394091

申请日：2000-12-06

Applicant: BASF AG

Inventor： GROSCH GEORG HEINRICH ,  HARRE KATHRIN ,  LORENZ REINHARD ,  WINKLER JURGEN ,  PAREDIS ELS ,  BAUER STEPHAN ,  HOPPNER GERD ,  ROTERMUND INGE

IPC: C08G65/20 ,  C08G65/26 ,  C08G18/48

Abstract: The invention relates to a method for the production of polyether alcohols b y catalytic addition of at least two alkylene oxides to H-functional starting materials. Said method is characterised in that at least one multi-metal cyanide compound is used as catalyst and in the course of the addition to the starting material at least one oxyalykylene unit is incorporated, during which a common dosing of at least two alkylene oxides occurs, whereby during said common dosing the ratio of the amounts of alkylene oxides to each other is varied.

公开(公告)号：ES2244446T3

公开(公告)日：2005-12-16

申请号：ES00935078

申请日：2000-05-19

Applicant: BASF AG

Inventor： GROSCH GEORG HEINRICH ,  HARRE KATHRIN ,  ERBES JORG ,  LORENZ REINHARD ,  BAUER STEPHAN ,  OSTROWSKI THOMAS

IPC: B01J27/26 ,  C08G65/26 ,  C08G65/10

Abstract: Procedimiento para la obtención de poliéteralcoholes con un peso molecular desde 500 hasta 50.000 Dalton y una funcionalidad desde 1 hasta 8 mediante polimerización con apertura del anillo de óxidos de alquileno, caracterizado porque se emplea, a modo de catalizador, al menos un compuesto de cianuro multimetálico con una constitución cristalina, de la fórmula general (I) M1a[M2(CN)bAc]d * e M1fXg * h H2 O (I) en la que M1 significa, al menos, un ión metálico elegido del grupo que contiene Zn2+, Fe2+, Co3+, Ni2+, Mn2+, Co2+, Sn2+, Pb2+, Fe3+, Mo4+, Mo6+, Al3+, V5+, Sr2+, W4+, W6+, Cu2+, Cr2+, Cr3+, Cd2+, Hg2+, Pd2+, Pt2+, V2+, Mg2+, Ca2+, Ba2+ y mezclas de los mismos, M2 significa, al menos, un ión metálico, elegido del grupo constituido por Fe2+, Fe3+, Co3+, Cr3+, Mn2+, Mn3+, Rh3+, Ru2+, Ru3+, V4+, V5+, Co2+, Ir3+ y Cr2+ y siendo M2 diferente de M1, X significa, al menos, un anión elegido del grupo constituido por halogenuro, hidróxido, sulfato, carbonato, cianuro, tiocianato, isocianato, carboxilato, especialmente formiato, acetato, propionato, oxalato, nitrato, A significa, al menos, un anión elegido del grupo formado por halogenuro, hidróxido, sulfato, carbonato, cianuro, tiocianato, isocianato, carboxilato o nitrato, especialmente cianuro, pudiendo ser A igual que o diferente de X, y a, b, c y d significan números enteros o fraccionarios, que se eligen de tal manera que se garantice la neutralidad electrónica del compuesto de cianuro, siendo a, b y d mayor que cero y siendo c mayor o igual que cero, e significa un número entero o fraccionario mayor que cero, así como f y g significan números enteros o fraccionarios, que se eligen de tal manera que se garantice la neutralidad electrónica de M1fXg, h significa un número entero o fraccionario mayor o igual que cero, que se ha fabricado mediante el empleo de un ácido hexacianocobáltico.

公开(公告)号：DE50007641D1

公开(公告)日：2004-10-07

申请号：DE50007641

申请日：2000-12-06

Applicant: BASF AG

Inventor： HARRE KATHRIN ,  HOEPPNER GERD ,  GROSCH HEINRICH ,  BAUER STEPHAN ,  WINKLER JUERGEN ,  PAREDIS ELS ,  LORENZ REINHARD ,  ROTERMUND INGE

IPC: C08G65/20 ,  C08G18/48 ,  C08G65/26

Abstract: In a process for preparing polyether alcohols by catalytic addition of at least two alkylene oxides onto H-functional initiator substances, at least one multimetal cyanide compound is used as catalyst and the addition of the alkylene oxides onto the initiator substance includes incorporation of at least one oxyalkylene block during whose formation at least two alkylene oxides are metered in together and the ratio of the alkylene oxides to one another in the mixture is changed during the joint introduction.