5.
    发明专利
    未知

    公开(公告)号:DE2158609A1

    公开(公告)日:1973-06-20

    申请号:DE2158609

    申请日:1971-11-26

    Applicant: BASF AG

    Abstract: 1401875 Extracting C 4 or C 5 conjugated diolefins BADISCHE ANILIN-& SODAFABRIK AG 24 Nov 1972 [26 Nov 1971] 54360/72 Heading C5E Pure C 4 or C 5 conjugated diolefins are separated from hydrocarbon mixtures by countercurrent gas scrubbing liquid-liquid extraction, extractive distillation and/or countercurrent distribution using as selective solvent a mixture of:- (a) 5-95 wt. per cent of an N-alkylpyrrolidone which may contain an inert substituent; and (b) 5-95 wt. per cent of an N-hydroxyalkyl compound of the general formula in which Y is C 2 or C 3 alkylene or alkenylene, or o-phenylene which may be wholly or partly hydrogenated R is a linear or branched alkylene and Z is oxygen or two hydrogens. The solvent mixture may contain up to 25 wt. per cent water. Preferred solvent components are (a) N-methylpyrrolidone; (b) N-hydroxyethylphthalimide, N-hydroxyethylsuccinimide and N-hydroxyethylpyrrolidone. The diolefins which may be separated by the process of the invention are butadiene, isoprene, 1,3-pentadiene and cyclopentadiene.

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