公开(公告)号：DE2428688A1

公开(公告)日：1976-01-15

申请号：DE2428688

申请日：1974-06-14

Applicant: BASF AG

Inventor： GREIF NORBERT DIPL CHEM DR ,  GERENDAS JOZSEF DIPL CHEM DR ,  ROKOHL RUDOLF DIPL CHEM DR ,  SCHARPENBERG HANS-GEORG DIPL C

IPC: D06P1/66 ,  D06P3/76 ,  C07C93/04

Abstract: Quaternary NH4 salts have general formula (where Ris m-valent 3-7 C alkyl; R1 is mono-valent 1-4 C alkyl; R2 is mono-valent 8-22 C alkyl; X- is Cl or Br anion, 1 is 0 to 6, m is 3 to 7, n is 1 to 7 and 1 + n max. = m). Pref. as retarders in dyeing anionic polyacrylonitrile fibres with basic dyes. W.r.t. standard retarders, (I) have higher activity and can be used in smaller quantities to achieve same levelling effect; (ii) fibre-blocking risk is overcome. (I) are pref. pred. by reacting an alcohol having formula R(OH)m (II) with (m-1) mol. epihalohydrin in presence of a Lewis acid and then with at least one tert. fatty amine of formula NR12R2.

公开(公告)号：DE2404511A1

公开(公告)日：1975-08-14

申请号：DE2404511

申请日：1974-01-31

Applicant: BASF AG

Inventor： FUERST ERNST DIPL CHEM DR ,  GERENDAS JOZSEF DIPL CHEM DR ,  ROKOHL RUDOLF DIPL CHEM DR ,  FIKENTSCHER ROLF DIPL CHEM DR ,  HELFERT HERBERT DIPL CHEM DR

IPC: D06P1/66 ,  D06P3/76 ,  C07D251/04

Abstract: Title cpds. of formula (I): (where R1 is opt. branched 1-6C alkyl opt. substd. by OH gps, or two R1 gps. together with the N atom form a 4-7C heterocycle; R2-R4 are each a cyclic, linear or branched, satd. or contg. an olefinic link 1-30C alkyl, opt. substd. by OH gps. and opt. interrupted by ether bridges, or a phenyl or benzyl gp. opt. substd. by Cl or 1-12C alkyl; R3 and R4 may also represent H or a pair of free electrons; R5 is H or 1-4C alkyl; Z is 2-6C alkylene, opt. substd. esp. by OH gps. or interrupted by either or ester gps; X- is an (in)organice anion; and these various anions may be the same or different; n is a whole no. 1-3), are prepd. by quaternising the corresp. unguaternised cpd. They are effective in amts. of 0.003-1.5 wt. % w.r.t. anionic polyacrylonitrile fibres.

公开(公告)号：DE2361949A1

公开(公告)日：1975-06-26

申请号：DE2361949

申请日：1973-12-13

Applicant: BASF AG

Inventor： GERENDAS JOZSEF DIPL CHEM DR ,  FLEISCHER HERBERT DIPL ING ,  FIKENTSCHER ROLF DIPL CHEM DR ,  HELFERT HERBERT DIPL CHEM DR

IPC: C07D251/34 ,  C07D251/54 ,  C07D251/70 ,  D06P1/66 ,  D06P3/76

Abstract: Special quaternary ammonium salts of 2,4,6-tris-( omega -dialkylamino-alkyleneamino)-triazines and 2,4,6-tris-( omega -dialkylaminoalkoxy)-triazines and their use in dyeing anionic polyacrylonitrile fibers with basic dyes; these special derivatives of triazine are particularly effective retarders.

公开(公告)号：DE2444823A1

公开(公告)日：1976-04-08

申请号：DE2444823

申请日：1974-09-19

Applicant: BASF AG

Inventor： WOLF HANS DIPL CHEM DR ,  GERENDAS JOZSEF DIPL CHEM DR ,  WILHELM ERNST

IPC: D06P1/52 ,  D06P3/60 ,  D06P3/82

Abstract: A process for dyeing cellulose fibers and mixtures of the same with synthetic fibers in an aqueous liquor by the exhaustion method in the presence of a water-soluble polymer of acrylic acid or an alkali metal salt or ammonium salt thereof, an alkali metal or ammonium salt of a copolymer of maleic acid and styrene, maleic acid and a vinyl ester or maleic acid and a vinyl ether as a dyeing assistant in an amount of from 0.05 to 2% by weight based on the material being dyed. Level dyeings are obtained and mixtures of fibers can be dyed in a single liquor.

公开(公告)号：DE2316725A1

公开(公告)日：1974-11-07

申请号：DE2316725

申请日：1973-04-04

Applicant: BASF AG

Inventor： FUERST ERNST DR ,  GERENDAS JOZSEF DIPL CHEM DR ,  ROKOHL RUDOLF DIPL CHEM DR ,  FIKENTSCHER ROLF DIPL CHEM DR ,  HELFERT HERBERT DIPL CHEM DR

IPC: D06P1/66 ,  D06P3/76 ,  C07D55/14 ,  D06P1/88

Abstract: Title cpds. of formula (I): (where R1 is opt. branched 1-6C alkyl opt. substd. by OH gps, or two R1 gps. together with the N atom form a 4-7C heterocycle; R2-R4 are each a cyclic, linear or branched, satd. or contg. an olefinic link 1-30C alkyl, opt. substd. by OH gps. and opt. interrupted by ether bridges, or a phenyl or benzyl gp. opt. substd. by Cl or 1-12C alkyl; R3 and R4 may also represent H or a pair of free electrons; R5 is H or 1-4C alkyl; Z is 2-6C alkylene, opt. substd. esp. by OH gps. or interrupted by either or ester gps; X- is an (in)organice anion; and these various anions may be the same or different; n is a whole no. 1-3), are prepd. by quaternising the corresp. unguaternised cpd. They are effective in amts. of 0.003-1.5 wt. % w.r.t. anionic polyacrylonitrile fibres.