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公开(公告)号:CA2466292C
公开(公告)日:2010-09-14
申请号:CA2466292
申请日:2002-11-19
Applicant: BASF AG
Inventor: ETTL ROLAND , WINTER MANFRED , FREUND TORSTEN , KESSLER THOMAS , GRIMM GUNTHER
IPC: C07D305/10 , C07D315/00
Abstract: The invention relates to a method for producing alkyl ketene dimers by reacting carboxylic acid chlorides with tertiary amines in a molar ratio of between 1: 1 and 1: 1.6 at temperatures of between 65 and 150 ~C and with a residence time of between 1 and 30 mins in the absence of solvents. Said reaction partners are intensively mixed and the alkyl ketene dimers are separated from the reaction mixture.
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公开(公告)号:CA2485113A1
公开(公告)日:2003-12-04
申请号:CA2485113
申请日:2003-05-19
Applicant: BASF AG
Inventor: GRIMM GUNTHER , BRAIG VOLKER , MAHR NORBERT , CHAMP SIMON
Abstract: The invention relates to hydrophobically modified polymers, which contain vinylamine units or ethylenimine units and can be obtained by reacting: (a) polymers containing vinylamine units or ethylenimine units with; (b) compoun ds of formula (I) R - A - (EO, PO, BuO)n - X, in which: R represents C4 to C26 alkyl or C4 to C26 alkenyl; A represents O, NH, COO; EO represents an ethyle ne oxide unit; PO represents a propylene oxide unit, BuO represents a butylene oxide unit, n ranges from 1 to 250, and; X represents a functional group tha t can be covalently bonded to an OH group. The invention also relates to a method for producing hydrophobically modified polymers, which contain vinylamine units or ethylenimine units, by reacting polymers containing vinylamine units or ethylenimine units with at least one hydrophobing agent of formula (I), and to the use of polymers obtained in this manner as an additi ve to paper pulp during the production of paper.
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公开(公告)号:AU2003251464A1
公开(公告)日:2004-03-29
申请号:AU2003251464
申请日:2003-07-24
Applicant: BASF AG
Inventor: CHAMP SIMON , GRIMM GUNTHER , ETTL ROLAND , DYLLICK-BRENZINGER RAINER
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公开(公告)号:AU2003232798A1
公开(公告)日:2003-12-12
申请号:AU2003232798
申请日:2003-05-19
Applicant: BASF AG
Inventor: CHAMP SIMON , MAHR NORBERT , GRIMM GUNTHER , BRAIG VOLKER
Abstract: Hydrophobically modified polymers containing vinylamine or ethylenimine units and obtainable by reacting (a) polymers containing vinylamine or ethylenimine units with (b) compounds of the formula R-A-(EO, PO, BuO)n-X (I), where R is C4- to C26-alkyl or C4- to C26-alkenyl, A is O, NH or COO, EO is an ethylene oxide unit, PO is a propylene oxide unit, BuO is a butylene oxide unit, n is from 1 to 250 and X is a functional group which can be covalently bonded to an OH group, process for the preparation of hydrophobically modified polymers containing vinylamine or ethylenimine units by reacting polymers containing vinylamine or ethylenimine units with a water repellent of the formula I and use of the polymers thus obtainable as an additive to paperstock in papermaking.
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公开(公告)号:AU1051502A
公开(公告)日:2002-04-08
申请号:AU1051502
申请日:2001-09-25
Applicant: BASF AG
Inventor: SCHAFER MARTIN , SLANY MICHAEL , ZELLER EDGAR , ROPER MICHAEL , SCHULZ MICHAEL , GRIMM GUNTHER
Abstract: The invention relates to a catalyst system for carbonylating olefinically or acetylenically unsaturated compounds with carbon monoxide and a nucleophile compound, containing (a) palladium; (b) a phosphine and (c) a polymer containing nitrogen which is soluble in the reaction mixture, with the exception of polyvinyl polymers with aromatic radicals containing nitrogen on the polymer chain. The invention also relates to a method for carbonylation in the presence of one such catalyst system.
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公开(公告)号:CA2485113C
公开(公告)日:2011-04-26
申请号:CA2485113
申请日:2003-05-19
Applicant: BASF AG
Inventor: GRIMM GUNTHER , BRAIG VOLKER , CHAMP SIMON , MAHR NORBERT
Abstract: The invention relates to hydrophobically modified polymers, which contain vinylamine units or ethylenimine units and can be obtained by reacting: (a) polymers containing vinylamine units or ethylenimine units with; (b) compounds of formula (I) R - A - (EO, PO, BuO)n - X, in which: R represents C4 to C26 alkyl or C4 to C26 alkenyl; A represents O, NH, COO; EO represents an ethylene oxide unit; PO represents a propylene oxide unit, BuO represents a butylene oxide unit, n ranges from 1 to 250, and; X represents a functional group that can be covalently bonded to an OH group. The invention also relates to a method for producing hydrophobically modified polymers, which contain vinylamine units or ethylenimine units, by reacting polymers containing vinylamine units or ethylenimine units with at least one hydrophobing agent of formula (I), and to the use of polymers obtained in this manner as an additive to paper pulp during the production of paper.
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公开(公告)号:ES2261484T3
公开(公告)日:2006-11-16
申请号:ES01978386
申请日:2001-09-25
Applicant: BASF AG
Inventor: SCHAFER MARTIN , SLANY MICHAEL , ZELLER EDGAR , ROPER MICHAEL , SCHULZ MICHAEL , GRIMM GUNTHER
Abstract: Sistema catalizador para el carbonilado de compuestos con insaturación olefínica o acetilénica con monóxido de carbono y un compuesto nucleófilo, que contiene (a) paladio; (b) una fosfina; y (c) una polietilenimina acilada disuelta de manera homogénea o al menos en distribución coloidal en la mezcla de reacción, que presenta unidades de la fórmula general (I) o isómeros ramificados de las mismas (Ver fórmula) en la que la suma de m+n asciende al menos a 10, y R, independientemente entre sí, significa hidrógeno, restos alquilo, cicloalquilo, arilo, aralquilo, acilo con hasta 30 átomos de carbono o restos hidroxialquil(poli)oxialquileno con hasta 500 unidades alquilenoxi, presentando la polietilenimina (I) los siguientes elementos estructurales (II) o isómeros ramificados de los mismos (Ver fórmulas) en las que R¿ significa, independientemente entre sí, alquilo con 1 a 29 átomos de carbono, y cuyo grado de amidación asciende a un 1 hasta casi un 100%, referido a los grupos amino amidables.
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