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    METHOD FOR THE REESTERIFICATION OR ESTERIFICATION OF SIDE CHAINS IN POLYMERS
    1.
    发明申请
    METHOD FOR THE REESTERIFICATION OR ESTERIFICATION OF SIDE CHAINS IN POLYMERS 审中-公开
    在聚合物中重新涂覆或超过侧链的方法

    公开(公告)号：WO2007063037A2

    公开(公告)日：2007-06-07

    申请号：PCT/EP2006068882

    申请日：2006-11-24

    Applicant: BASF AG ,  HAERING DIETMAR ,  HERRERA TABOADA LIDCAY ,  HAUER BERNHARD ,  FRIEDRICH THOMAS ,  GOETHLICH ALEXANDER

    Inventor： HAERING DIETMAR ,  HERRERA TABOADA LIDCAY ,  HAUER BERNHARD ,  FRIEDRICH THOMAS ,  GOETHLICH ALEXANDER

    CPC classification number: C08F220/18 ,  C08F8/14 ,  C08F220/62 ,  C08F220/00

    Abstract: The invention relates to a method for reesterifying or esterifying side chains in polymers. Said method comprises the following steps: a) a copolymer is produced which is obtained by polymerizing aa) at least one (meth)acrylate of general formula (I) as component A, wherein R 1 represents H or CH 3 while R 2 represents H or an alkyl radical that can be optionally substituted with functional groups such as acryl groups, ether groups, amino groups, epoxy groups, halogen groups, or sulfonic acid groups, and ab) at least one monomer of general formula (II) as component B, wherein R 3 has the same meaning as R 1 , R 4 has the same meaning as R 2 , and n = 1 to 40, and b) reesterifying or esterifying the carboxyl group containing the radical R 4 with an alcohol in the presence of an enzyme catalyzing the reesterification or esterification process. The invention also relates to said polymers and the use thereof.

    Abstract translation: 本发明涉及一种用于酯化或酯交换中的聚合物侧链，其包括以下步骤：a）制备由氨基酸的聚合而得到的共聚物）的通式（I）作为组分A的至少一种（甲基）丙烯酸酯，其中R H或CH 3和R 2是H或任选被官能团取代的烷基，所述官能团如丙烯酸，醚，氨基 - ，通式（II）作为组分B，其中R 3 的含义与R相同 1

    ENZYMATIC ACRYLATION OF ARYL KETONES
    3.
    发明申请
    ENZYMATIC ACRYLATION OF ARYL KETONES 审中-公开
    芳基酮的酶法丙烯酸酯

    公开(公告)号：WO2005059151A3

    公开(公告)日：2005-09-22

    申请号：PCT/EP2004014344

    申请日：2004-12-16

    Applicant: BASF AG ,  HAERING DIETMAR ,  SCHOEPKE HOLGER ,  HAUER BERNHARD ,  HAREMZA SYLKE ,  WINTER DOMINIK

    Inventor： HAERING DIETMAR ,  SCHOEPKE HOLGER ,  HAUER BERNHARD ,  HAREMZA SYLKE ,  WINTER DOMINIK

    IPC: C12P7/26 ,  C12P7/62

    CPC classification number: C12P7/26 ,  C12P7/62

    Abstract: Disclosed is a method for the enzyme-catalyzed production of (alk)acrylates of general formula (I) by esterifying or transesterifying aryl ketones of general formula (II) with (alk)acrylic acid, an (alk)acrylic acid ester of general formula (III), or an (alk)acrylic acid anhydride of general formula (IIIa) in the presence of an enzyme which catalyzes esterification or transesterification.

    Abstract translation: 一种用于酶催化生产过程（烷基））通过酯化或通式（II）与（烷基）丙烯酸，（烷基）通式（III）或（烷基丙烯酸酯的芳基酮的酯基转移反应的通式（I）的丙烯酸酯） 通式（IIIa）的丙烯酸酐在酯化或酯交换催化酶的存在下反应。

    Production of (meth)acrylates of cyclic or open-chain N-hydroxyalkylated amides, used as (co)monomer in poly(meth)acrylates or in radiation cure, uses inorganic salt or enzyme as heterogeneous catalyst for esterification or ester exchange
    9.
    发明专利
    Production of (meth)acrylates of cyclic or open-chain N-hydroxyalkylated amides, used as (co)monomer in poly(meth)acrylates or in radiation cure, uses inorganic salt or enzyme as heterogeneous catalyst for esterification or ester exchange 未知

    公开(公告)号：DE102004036930A1

    公开(公告)日：2006-03-23

    申请号：DE102004036930

    申请日：2004-07-29

    Applicant: BASF AG

    Inventor： HOEFER FRANK ,  HAERING DIETMAR

    IPC: C12P7/62 ,  C08F2/46 ,  C08F20/10 ,  C08J3/28

    Abstract: Production of (meth)acrylates (I) of cyclic or open-chain N-hydroxyalkylated amides (II) involves esterification of (II) with (meth)acrylic acid or ester exchange with (meth)acrylic ester(s) in the presence of heterogeneous catalyst(s) selected from inorganic salts (III) and enzymes (IV). Production of (meth)acrylates (I) of cyclic or open-chain N-hydroxyalkylated amides (II) of formulae (IIA) and (IIB) respectively involves esterification of (II) with (meth)acrylic acid or ester exchange with (meth)acrylic ester(s) in the presence of heterogeneous catalyst(s) selected from inorganic salts (III) and enzymes (IV). Z 1>oxygen (O), sulfur (S), (un)substituted phosphorus (P) or mono- or un-substituted nitrogen (N-R 3>); R 1>, R 3>2-20 C alkylene, 5-12 C cycloalkylene, 6-12 C arylene or a 2-20 C alkylene group with 1 or more O and/or S atoms, (un)substituted imino groups and/or cycloalkyl, -(CO)-, -O(CO)O-, -(NH)(CO)O-, -O(CO)(NH)-, -O(CO)- or -(CO)O- groups in the chain, where any of these groups may be substituted by R; R : aryl, alkyl, aryloxy, alkoxy, heteroatoms and/or heterocycles; or R 2>-OH : -[X i] k-H; R 3>, R 4>, R 5>H, 1-18 C alkyl, 2-18 C alkyl, optionally with O and/or S atoms and/or (un)substituted imino groups in the chain, 2-18 C alkenyl, 6-12 C aryl, 5-12 C cycloalkyl or a 5-7-membered heterocycle containing O, N and/or S atom(s), where any of these groups may be substituted R; or R 3>R 6>a group forming 5-12-membered ring; k : 1-50; X i-CH 2-CH 2-O-, -CH 2-CH 2-N(H)-, -CH 2-CH 2-CH 2-N(H)-, -CH 2-CH(NH 2)-, -CH 2-CH(NHCHO)-, -CH 2-CH(CH 3)-O-, -CH(CH 3)-CH 2-O-, -CH 2-C(CH 3) 2-O-, -C(CH 3) 2-CH 2-O-, -CH 2-CH 2-CH 2-O-, -CH 2-CH 2-CH 2-CH 2-O-, -CH 2-CHVin-O-, -CHVin-CH 2-O-, -CH 2-CHPh-O- or -CHPh-CH 2-O-; Ph : phenyl; Vin : vinyl; i : 1-k; and R 5>unsubstituted 1-18 C alkyl, 6-12 C aryl or 5-12 C cycloalkyl if Z 1> = O. [Image].

    10.
    发明专利
    未知

    公开(公告)号：DE10163163A1

    公开(公告)日：2003-07-03

    申请号：DE10163163

    申请日：2001-12-20

    Applicant: BASF AG

    Inventor： WAGNER EVA ,  BRUCHMANN BERND ,  HAERING DIETMAR ,  KELLER PETER ,  POUHE THOMAS

    IPC: C08G63/06 ,  C08G63/12 ,  C08G63/60 ,  C08G83/00 ,  C12P7/62 ,  C12R1/72 ,  C08G63/78 ,  C08G63/91 ,  C09D135/02 ,  C09J135/02

    Abstract: The invention relates to a method for producing highly functional, hyper branched polyester, characterised by the reaction of a reaction solution containing solvent and (a) one or more dicarboxylic acids or one or more derivatives thereof with one or more at least trifunctional alcohols, (b) or one or more tricarboxylic acids or high polycarboxylic acids or one or more derivatives thereof with one or more dioles, (c) or one or more tricarboxylic acids or higher polycarboxylic acids or one or more derivatives thereof with one or more trifunctional alcohols, (d) or one or more di- or polyhydroxycarboxylic acids, (e) or one or more hydroxydicarboxylic acids or hydroxypolycarboxylic acids, or a mixture of at least two of the above-mentioned reaction solutions in the presence of an enzyme at temperatures greater than 60 DEG C and at a pressure which is greater than 500mbar.

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