公开(公告)号：JPH10110116A

公开(公告)日：1998-04-28

申请号：JP26604997

申请日：1997-09-30

Applicant: BASF AG

Inventor： KALIBA CLAUS DR ,  KELLER HARALD DR ,  GONZALEZ GOMEZ JUAN ANTONIO DR ,  BIDLINGMAIER HERMANN ,  ELLINGHOVEN RAYMOND ,  SCHMID RAIMUND DR

IPC: C09C1/28 ,  A61K8/11 ,  A61K8/29 ,  A61K8/58 ,  A61Q1/02 ,  A61Q19/00 ,  C03C1/10 ,  C03C4/02 ,  C04B33/14 ,  C08J3/20 ,  C08K9/02 ,  C08K9/06 ,  C09C1/00 ,  C09C1/36 ,  C09C3/12 ,  C09D5/36 ,  C09D7/12 ,  C09D11/00 ,  C09D11/02 ,  C09D11/16 ,  C09D17/00

Abstract: PROBLEM TO BE SOLVED: To obtain a pale blue gloss pigment having high perspiration resistance useful as a coating material especially a coloring coating material, etc., of a lacquer for an automobile by reacting a silicate platelet coated with reduced titania with a specific silane. SOLUTION: This pale blue gloss pigment is produced by using a silicate platelet coated with reduced titania as a base and reacting the silicate platelet with a silane of the formula Ra SiXb [R is a 1-10C alkyl substituted by glycidoxy, amino, etc., at μ-position; X is a 1-4C alkoxy; (a) is 1 or 2; (b) is 2 or 3 with the proviso that (a)+(b)=4] (preferably, 3-aminopropyltriethoxysilane, etc.) by heating in a reductive atmosphere. The reaction is preferably per-formed by fluidizing the reduced platelets in a fluidizing reaction vessel by nitrogen, heating to 150-300 deg.C and further introducing the gasified silane and water vapor to the vessel. Moreover, muscovite flakes obtained by wet milling is preferably used as the silicate platelet. The reduction of the silicate platelet coated by the titania is preferably performed by ammonia gas.

公开(公告)号：DE19640188A1

公开(公告)日：1998-07-02

申请号：DE19640188

申请日：1996-09-30

Applicant: BASF AG

Inventor： KALIBA CLAUS DR ,  KELLER HARALD DR ,  GONZALEZ GOMEZ JUAN ANTONIO DR ,  BIDLINGMAIER HERMANN ,  ELLINGHOVEN RAYMOND ,  SCHMID RAIMUND DR

IPC: C09C1/28 ,  A61K8/11 ,  A61K8/29 ,  A61K8/58 ,  A61Q1/02 ,  A61Q19/00 ,  C03C1/10 ,  C03C4/02 ,  C04B33/14 ,  C08J3/20 ,  C08K9/02 ,  C08K9/06 ,  C09C1/00 ,  C09C1/36 ,  C09C3/12 ,  C09D5/36 ,  C09D7/12 ,  C09D11/00 ,  C09D11/02 ,  C09D11/16 ,  C09D17/00

公开(公告)号：ES2155149T3

公开(公告)日：2001-05-01

申请号：ES96104563

申请日：1996-03-22

Applicant: BASF AG

Inventor： SCHMIDT HELMUT ,  OSTERTAG WERNER DR ,  BIDLINGMAIER HERMANN ,  MRONGA NORBERT DR ,  GONZALEZ GOMEZ JUAN ANTONIO DR ,  KALIBA CLAUS DR

IPC: C09C1/30 ,  A61K8/11 ,  A61K8/25 ,  A61Q1/02 ,  C03C1/10 ,  C03C4/02 ,  C04B33/14 ,  C08K9/02 ,  C09C1/00 ,  C09C1/28 ,  C09C1/36 ,  C09C3/08 ,  C09D5/36 ,  C09D7/12 ,  C09D11/00 ,  A61K7/00

Abstract: (A) Prepn. of blue-shade gloss pigments is obtd. by treatment of silicatic flakes which are coated with titanium dioxide (the titanium dioxide coating having a geometric layer thickness of 10-60 nm) with a reducing gas mixt. (which contains a vaporised organic cpd. and ammonia) at 800-900 degrees C. (B) Blue-shade gloss pigment is based on silicatic flakes which comprise a reduced titanium dioxide and has a geometric layer thickness of 10-60 nm and a CIELAB colour value -2 ≤ a* ≤ b* ≤ -20 (measurement angle 20 degrees ,'standard light type'D65).

公开(公告)号：DE19511697A1

公开(公告)日：1996-10-02

申请号：DE19511697

申请日：1995-03-30

Applicant: BASF AG

Inventor： OSTERTAG WERNER DR ,  BIDLINGMAIER HERMANN ,  MRONGA NORBERT DR ,  GONZALEZ GOMEZ JUAN ANTONIO DR ,  KALIBA CLAUS DR ,  SCHMID RAIMUND DR ,  ELLINGHOVEN RAYMOND ,  SCHMIDT HELMUT

IPC: C09C1/30 ,  A61K8/11 ,  A61K8/25 ,  A61Q1/02 ,  C03C1/10 ,  C03C4/02 ,  C04B33/14 ,  C08K9/02 ,  C09C1/00 ,  C09C1/28 ,  C09C1/36 ,  C09C3/08 ,  C09D5/36 ,  C09D7/12 ,  C09D11/00 ,  C09D17/00 ,  C09D11/02 ,  C09D11/16 ,  A61K7/021

Abstract: (A) Prepn. of blue-shade gloss pigments is obtd. by treatment of silicatic flakes which are coated with titanium dioxide (the titanium dioxide coating having a geometric layer thickness of 10-60 nm) with a reducing gas mixt. (which contains a vaporised organic cpd. and ammonia) at 800-900 degrees C. (B) Blue-shade gloss pigment is based on silicatic flakes which comprise a reduced titanium dioxide and has a geometric layer thickness of 10-60 nm and a CIELAB colour value -2 ≤ a* ≤ b* ≤ -20 (measurement angle 20 degrees ,'standard light type'D65).

公开(公告)号：ES2154751T3

公开(公告)日：2001-04-16

申请号：ES96104562

申请日：1996-03-22

Applicant: BASF AG

Inventor： SCHMID RAIMUND DR ,  KALIBA CLAUS DR ,  MRONGA NORBERT DR ,  OSTERTAG WERNER DR ,  SCHMIDT HELMUT ,  GONZALEZ GOMEZ JUAN ANTONIO DR

IPC: C09C1/30 ,  A61K8/11 ,  A61Q1/02 ,  C03C1/04 ,  C03C4/02 ,  C04B33/14 ,  C08K9/02 ,  C09C1/00 ,  C09C1/28 ,  C09C3/08 ,  C09D5/36 ,  C09D7/12 ,  C09D11/00 ,  A61K7/00

Abstract: Gloss pigment is obtd. by treatment of silicatic flakes which are coated with titanium dioxide with a gas mixt. (which contains a vapourised organic cpd. and ammonia) at 400-900 degrees C.

公开(公告)号：DE19725519A1

公开(公告)日：1998-12-24

申请号：DE19725519

申请日：1997-06-17

Applicant: BASF AG

Inventor： SUTORIS HEINZ FRIEDRICH DR ,  MITULLA KONRAD DR ,  DUPUIS JACQUES DR ,  KALIBA CLAUS DR

IPC: C07B63/04 ,  C07C7/20 ,  C07C15/46 ,  C09K15/20 ,  C09K15/30 ,  C09K15/32 ,  C07C15/44 ,  C07C211/45 ,  C07C205/06 ,  C07D211/92

Abstract: The invention relates to a mixture of substances containing one or several compounds with vinyl groups as constituent (A) and a stabilizer (B) as another constituent containing one or several easily volatile nitroxyl compounds as constituent (b1), one or several non-easily volatile nitroxyl compounds as constituent (b2), optionally one or several aromatic nitro compounds as constituent (b3) and optionally one or several iron compounds as constituent (b4). The invention also relates to stabilizers (B) containing constituents (b1) and (b2), (b1) and (b2) and (b3), (b1) and (b2) and (b4), in addition to (b1), (b2), (b3) and (b4). The invention further relates to a method for inhibiting premature polymerization of compounds with vinyl groups during the cleaning thereof or distillation by adding a stabilizer (B), or by adding the constituents of stabilizer (B) as individual substances or in at least two groups of constituents.

公开(公告)号：DE59503574D1

公开(公告)日：1998-10-22

申请号：DE59503574

申请日：1995-04-22

Applicant: BASF AG

Inventor： SCHMID RAIMUND DR ,  MRONGA NORBERT DR ,  KALIBA CLAUS DR ,  OSTERTAG WERNER DR ,  SCHMIDT HELMUT

IPC: B41M3/14 ,  B44F1/12 ,  C09C1/00 ,  C09D11/00 ,  C09D11/037

公开(公告)号：DE19511696A1

公开(公告)日：1996-10-02

申请号：DE19511696

申请日：1995-03-30

Applicant: BASF AG

Inventor： SCHMIDT RAIMUND DR ,  KALIBA CLAUS DR ,  MRONGA NORBERT DR ,  OSTERTAG WERNER DR ,  SCHMIDT HELMUT ,  GONZALEZ GOMEZ JUAN ANTONIO DR ,  BIDLINGMAIER HERMANN ,  ELLINGHOVEN RAYMOND

IPC: C09C1/30 ,  A61K8/11 ,  A61Q1/02 ,  C03C1/04 ,  C03C4/02 ,  C04B33/14 ,  C08K9/02 ,  C09C1/00 ,  C09C1/28 ,  C09C3/08 ,  C09D5/36 ,  C09D7/12 ,  C09D11/00 ,  C09D17/00 ,  C09D11/02 ,  C09D11/16 ,  A61K7/021

Abstract: Gloss pigment is obtd. by treatment of silicatic flakes which are coated with titanium dioxide with a gas mixt. (which contains a vapourised organic cpd. and ammonia) at 400-900 degrees C.

公开(公告)号：DE4419089A1

公开(公告)日：1995-12-07

申请号：DE4419089

申请日：1994-06-01

Applicant: BASF AG

Inventor： SCHMID RAIMUND DR ,  MRONGA NORBERT DR ,  KALIBA CLAUS DR ,  OSTERTAG WERNER DR ,  SCHMIDT HELMUT

IPC: B41M3/14 ,  B44F1/12 ,  C09C1/00 ,  C09C1/28 ,  C09D7/12 ,  C09D11/00 ,  D21H21/40 ,  G07D7/00 ,  B41F11/02

Abstract: Interference pigments based on silicate laminae that are coated with titanium dioxide and heated in a reduced atmosphere are used to produce forgery-proof security documents and packaging.

公开(公告)号：DE4415357A1

公开(公告)日：1995-11-09

申请号：DE4415357

申请日：1994-05-02

Applicant: BASF AG

Inventor： SCHMID RAIMUND DR ,  MRONGA NORBERT DR ,  KALIBA CLAUS DR ,  OSTERTAG WERNER DR ,  SCHMIDT HELMUT

IPC: B41M3/14 ,  B44F1/12 ,  C09C1/00 ,  C09D11/00 ,  C09D11/037 ,  C09C3/06 ,  C09D5/36 ,  C09D11/02 ,  C09D17/00 ,  G06K19/14 ,  G07D7/00